Performance of a thermal lithium battery is improved by improving the ion-transport characteristics of a solid lithium iodide electrolyte. The lithium iodide lattice of the solid electrolyte includes defects that improve the ion-transport characteristics of the solid lithium iodide electrolyte. In one example, the defects are due to the introduction of nanoparticles that result in grain boundary defects. The defects resulting at the grain boundaries with the nanoparticles improve the ion transport characteristics of the electrolyte. In another example, defects originating from the synthesis process are pinned by the presence of nanoparticles and/or the reinforcing structure. In another example, the defects are aliovalent substitution defects. A cation that is aliovalent to the lithium cation (Li.sup.+), such as a barium cation (Ba.sup.2+), creates an aliovalent substitution defect in the lithium iodide lattice. In order to maintain charge neutrality in the lattice, two lithium cations are replaced by a single barium cation creating the defect in the lattice.

Development of a flexible battery based on periodate/iodate-zinc system is disclosed. H.sub.3PO.sub.4—KCl dual quasi-solid electrolytes separated by an anion-exchange-membrane maintain the desired pH in electrodes and block unwanted ion movements. Poly(acrylic acid) fortifies the electrodes, enhances electrode flexibility, and avoids the free-flow of liquids. The NaMnIO.sub.6 shows a specific capacity of 650 mAg.sup.−1, approximately 81% of its theoretical capacity even when cells are bent. The overall technology is scalable by printing methods.

A lithium secondary battery comprising a cathode, an anode, and an elastic polymer protective layer disposed between the cathode and the anode, and a working electrolyte in ionic communication with the anode and the cathode, wherein the elastic polymer protective layer comprises a high-elasticity polymer having a thickness from 2 nm to 200 μm, a lithium ion conductivity from 10.sup.−8 S/cm to 5×10.sup.−2 S/cm at room temperature, and a fully recoverable tensile elastic strain of at least 5% when measured without any additive or filler dispersed therein and wherein the high-elasticity polymer comprises a crosslinked polymer network of chains derived from a phosphazene compound and wherein the crosslinked polymer network of chains is impregnated with from 0% to 90% by weight of a liquid electrolyte.

A sodium-ion conducting NaSICON ceramic can be densified via the addition of a solvent to a NaSICON powder and subsequent pressing under high pressure and mild heat. Densification to ˜90% relative density can be achieved, providing a path toward low-temperature fabrication of Na-ion conductors.

The present disclosure sets forth battery components for secondary and/or traction batteries. Described herein are new solid-state lithium (Li) conducting electrolytes including monolithic, single layer, and bi-layer solid-state sulfide-based lithium ion (Li.sup.+) conducting catholytes or electrolytes. These solid-state ion conductors have particular chemical compositions which are arranged and/or bonded through both crystalline and amorphous bonds. Also provided herein are methods of making these solid-state sulfide-based lithium ion conductors including new annealing methods. These ion conductors are useful, for example, as membrane separators in rechargeable batteries.

A polyoxymethylene-based all-solid-state polymer electrolyte prepared by in-situ ring-opening polymerization is used in forming an all-solid-state secondary lithium battery. A trioxymethylene monomer, an additive and lithium salt initiates in-situ ring-opening polymerization on a porous support material through a catalyst to form the all-solid-state polymer electrolyte, which has a thickness of 10 μm-800 μm, an ionic conductivity of 4×10.sup.−5 S/cm—8×10.sup.−3 S/cm at room temperature and an electrochemical window not lower than 4.2 V.

There is provided an inorganic solid electrolyte-containing composition containing an inorganic solid electrolyte and a polymer binder, in which the polymer binder contains a specific polymer, and the weight-average molecular weight and content of the polymer binder satisfy relationships represented by specific expressions. There are also provided a sheet for an all-solid state secondary battery and an all-solid state secondary battery, in which this inorganic solid electrolyte-containing composition is used, and manufacturing methods for a sheet for an all-solid state secondary battery, and an all-solid state secondary battery.

Disclosed are a hybrid solid electrolyte sheet and a method of manufacturing the same. The hybrid solid electrolyte sheet includes a hybrid solid electrolyte layer including a gel polymer electrolyte, thereby securing flexibility and alleviating brittleness. In addition, the hybrid solid electrolyte sheet includes a porous polymer film having a plurality of pores, thus minimizing the content of the acrylate monomer in the pores thereof and providing advantages of maintaining the continuity of the solid electrolyte while minimizing a decrease in ionic conductivity.

A composition of matter, has a solid foam, at least one ionic conductor in the foam, and an electronic conductor in the foam. A battery has an anode, comprising a metal electrode and a solid foam, a cathode, and a solid electrolyte between the anode and the cathode, the solid electrolyte in contact with the solid foam. A solid foam has an electronic conductor, a hard ionic conductor, and a soft ionic conductor.

Provided are a solid electrolyte composition containing an inorganic solid electrolyte having a conductivity of an ion of a metal belonging to Group I or II of the periodic table and a binder having a specific hydrocarbon polymer segment and a specific segment, a solid electrolyte-containing sheet in which the same solid electrolyte composition is used and a manufacturing method therefor, an all-solid state secondary battery and a manufacturing method therefor, a polymer having a specific hydrocarbon polymer segment and a specific segment, and a non-aqueous solvent dispersion thereof.