An anode-free solid-state battery includes a cathode layer having transient anode elements and a bare current collector devoid of non-transitory anode material and configured to accept thereon the transient anode elements. The battery also includes a solid-state electrolyte layer defining voids and arranged between the current collector and the cathode layer. The battery additionally includes a gel situated within the solid-state electrolyte and cathode layers, to permeate the electrolyte voids and form a gelled solid-state electrolyte layer, coat the cathode layer, and facilitate ionic conduction of the anode elements between the cathode layer, the solid-state electrolyte layer, and the current collector. Charging the battery diffuses the anode elements from the cathode layer, via the gelled solid-state electrolyte layer, onto the current collector. Discharging the battery returns the anode elements, via the gelled solid-state electrolyte layer, to the cathode layer. A particular method is used to fabricate the anode-free solid-state battery.

Provided is a battery in which the internal resistance is further decreased. The present disclosure provides a battery, comprising a positive electrode, a negative electrode, and an electrolyte layer provided between the positive electrode and the negative electrode. The electrolyte layer includes a first solid electrolyte material. The first solid electrolyte material includes Li, M, and X, and does not include sulfur. M is at least one selected from the group consisting of metalloid elements and metal elements other than Li. X is at least one selected from the group consisting of Cl, Br, and I. The negative electrode includes a negative electrode active material and a sulfide solid electrolyte.

In solid-state lithium-ion battery cells, electrolyte-infiltrated composite electrode includes an electrolyte component consisting of polymer matrix with ceramic nanoparticles embedded in the matrix to form networking structure of electrolyte. The networking structure establishes effective lithium-ion transport pathway in the electrode. Electrolyte-infiltrated composite electrode sheets and solid electrolyte membranes can be used in all solid-state lithium electrochemical pouch and coin cells. Solid-state lithium-ion battery is fabricated by: (a) providing an anode layer; (b) providing a cathode layer; (c) positioning a ceramic-polymer composite electrolyte membrane between the anode layer and the cathode layer to form a laminar battery assembly; (d) applying pressure to the laminar battery assembly; and (e) heating the laminar battery assembly. Pressure-aided co-curing strengthens the contacts between the electrodes and the solid electrolyte membrane thus creating stable electrode-membrane interfaces with fewer porous regions. Lithium electrochemical cells and batteries exhibit excellent rate performance and outstanding stability over wide temperature range.

A composite negative electrode structure includes a current collecting layer, a porous layer, a plurality of lithiophilic structures, and a solid-state electrolyte layer. The porous layer is located on a surface of the current collecting layer and includes a plurality of pores. The lithiophilic structures are located on the surface of the current collecting layer and accommodated in some of the pores. The solid-state electrolyte layer is located on the porous layer.

A solid-state electrolyte film includes a first lithium salt, a first polymer, a second polymer, and a solid-state electrolyte. The first polymer has a weight average molecular weight of between 60,000 g/mol and 1,800,000 g/mol. The second polymer has a granular shape. The solid-state electrolyte has a granular shape and a particle size (D50) of between 50 nm and 2 .Math.m.

Set forth herein are garnet material compositions, e.g., lithium-stuffed garnets and lithium-stuffed garnets doped with alumina, which are suitable for use as electrolytes and catholytes in solid state battery applications. Also set forth herein are lithium-stuffed garnet thin films having fine grains therein. Disclosed herein are novel and inventive methods of making and using lithium-stuffed garnets as catholytes, electrolytes and/or anolytes for all solid state lithium rechargeable batteries. Also disclosed herein are novel electrochemical devices which incorporate these garnet catholytes, electrolytes and/or anolytes. Also set forth herein are methods for preparing novel structures, including dense thin (<50 um) free standing membranes of an ionically conducting material for use as a catholyte, electrolyte, and, or, anolyte, in an electrochemical device, a battery component (positive or negative electrode materials), or a complete solid state electrochemical energy storage device. Also, the methods set forth herein disclose novel sintering techniques, e.g., for heating and/or field assisted (FAST) sintering, for solid state energy storage devices and the components thereof.

A method for producing a conductive composite material for a battery such as a solid-state battery includes providing an ion-conducting electrolyte matrix that can be plasticized and that includes an ion-conducting first substance a base substance that can be plasticized and/or a polyelectrolyte; providing a second ion-conducting substance in the form of ion-conducting particles; introducing the ion-conducting particles into the electrolyte matrix to produce a mixture consisting of the ion-conducting particles and the electrolyte matrix; and homogenizing the mixture.

A nanocomposite layer includes a carbon nanotube composite material and a lithium salt polymer composite. The carbon nanotube composite material includes a surface modified carbon nanotube with a positively charged group and a plurality of nanoparticles with a negatively charged group. The plurality of nanoparticles are attached to the surface modified carbon nanotube. The lithium salt polymer composite wraps the carbon nanotube composite material, and includes a first polymer, a second polymer, and a lithium salt.

A technique that can improve ionic conductivity is provided.

An electrolyte includes an inorganic composite particle that is a composite of an inorganic particle with a compound having a betaine structure and one or more functional groups selected from a (meth)acryloxy group, a Si(OR).sub.3 group (R is a hydrogen atom or an alkyl group having 1 to 3 carbon atoms), and an Al(OR).sub.2 group (R is a hydrogen atom or an alkyl group having 1 to 3 carbon atoms).

An aspect of the present invention provides a manufacturing method for an electrolyte sheet, the manufacturing method including a step of molding a composition containing a polymer, Li[TFSI], oxide particles, and a dispersion medium into a sheet shape and volatilizing the dispersion medium at 100° C. or higher.