The invention discloses a perovskite solar cell and a method of fabrication thereof. The perovskite solar cell sequentially comprises a transparent electrode, a mesoporous P-I-N framework and a counter electrode from the bottom to top; the mesoporous P-I-N framework is composed of an n-type semiconductor layer, an insulating layer, and a p-type semiconductor layer in a sequentially stacked mode, and the n-type semiconductor layer, the insulating layer and the p-type semiconductor layer all comprise mesopores filled with a perovskite material. The preparation method sequentially includes preparing the mesoporous P-I-N framework on a transparent conductive substrate through a spin-coating method or a screen printing method, filling with the perovskite material and preparing the counter electrode layer.

A method of disinfection of a surface of a subject of harmful microorganisms including pathogenic bacteria and viruses upon visible light irradiation using a hybridized fluorescent silk is provided. The method includes placing a predetermined quantity of the hybridized fluorescent silk i) directly on to a skin surface of a subject; or ii) on a medium and then placing the medium on the skin surface of the subject. The method further includes applying light in the visible spectrum for a predetermined amount of time to the placed quantity of hybridized fluorescent silk, wherein the hybridized fluorescent silk is one of KillerRed, SuperNova, KillerOrange, Dronpa, TurboGFP, mCherry, or any combination thereof.

A method of inactivating harmful microorganisms of a filtration medium including pathogenic bacteria and viruses is disclosed which includes placing a predetermined quantity of a hybridized fluorescent silk on to a filtration medium, applying light for a predetermined amount of time to the placed quantity of the hybridized fluorescent silk, and passing a fluid through the medium, wherein the fluid is one of substantially air or substantially water, wherein the hybridized fluorescent silk is one of KillerRed, SuperNova, KillerOrange, Dronpa, TurboGFP, mCherry, or any combination thereof.

The present invention relates to a semiconductor device comprising a semiconducting material, wherein the semiconducting material comprises a compound comprising: (i) one or more first monocations [A]; (ii) one or more second monocations [B.sup.I]; (iii) one or more trications [B.sup.III]; and (iv) one or more halide anions [X]. The invention also relates to a process for producing a semiconductor device comprising said semiconducting material. Also described is a compound comprising: (i) one or more first monocations [A]; (ii) one or more second monocations [B.sup.I] selected from Cu.sup.+, Ag.sup.+ and Au.sup.+; (iii) one or more trications [B.sup.III]; and (iv) one or more halide anions [X].

A method for producing a photoelectric conversion element includes forming a hole transport layer containing a hole transport material by causing the hole transport material to adhere to one of a light-absorbing layer and a conductive layer; melting the hole transport layer by heating the hole transport layer to a temperature that is higher than or equal to a melting point of the hole transport material and is in a range of 120 C. or higher and 170 C. or lower; and bonding the light-absorbing layer and the conductive layer with the hole transport layer disposed therebetween by performing cooling while bringing the other of the light-absorbing layer and the conductive layer into contact with the melted hole transport layer under pressure. The light-absorbing layer contains a compound represented by general formula (1), where A represents an organic molecule, B represents a metal atom, and X represents a halogen atom.

ABX.sub.3(1)

The invention provides an all-day solar cell system that is capable of simultaneously generating and storing electricity, which allows efficient photocharge during the day and discharge at night.

The present invention relates to a photovoltaic element comprising one front electrode and one further electrode comprising respectively one glass substrate and one electrically conductive electrode layer which is disposed on the glass substrate, at least two porous carrier layers which are disposed between the two electrodes, the two electrodes being connected to the adjacent porous carrier layers without a spatial interval, a plurality of glass solder webs disposed between the two electrodes for fixing the at least two porous carrier layers, and at least one photovoltaically active material which is introduced into the at least two porous carrier layers and has a concentration gradient.

A perovskite composite structure is provided. The perovskite composite structure includes a light absorption layer and a sterically-hindered layer disposed in the periphery of the light absorption layer. The light absorption layer includes a perovskite material. The sterically-hindered layer includes a two-dimensional material.

Provided is a photoelectric conversion element including a first electrode, an electron-transporting layer, a hole-transporting layer, and a second electrode, wherein the hole-transporting layer and the second electrode are in contact with each other, and the hole-transporting layer satisfies the following formula:

0%<Rc(50)0.75%

where an average thickness of the hole-transporting layer is determined as X (nm), and Rc(50) is a ratio of an area of projected parts that are projected from a standard line towards the second electrode, where the standard line is present at a position that is away, by X+50 (nm), from an opposite surface of the hole-transporting layer to a surface of the hole-transporting layer in contact with the second electrode.

Disclosed herein are novel hole transporting materials comprising polycyclic heteroaromatic hydrocarbon compounds that are easy to synthesize and inexpensive. The hole transporting materials of the present disclosure have high hole mobility and thus do not require any doping. The hole transporting materials of the present disclosure also have matching frontier orbitals when used in devices with the perovskite and cathodes, facilitating hole migration across perovskite/hole transporting layers and hole transporting layer/cathode interfaces. The hole transporting materials of the present disclosure can further be hydrophobic with no moisture attracting atoms. The hole transporting materials can be used to form dense and uniform films on perovskite, and combined with hydrophobicity, form an excellent moisture barrier for the perovskite. With the present disclosure compound as the hole transporting layer in a perovskite solar cell, highly stable and highly efficient and inexpensive solar cells can be achieved.