The present invention is directed to a method for pre-lithiation of negative electrodes during lithium loaded electrode manufacturing for use in lithium-ion capacitors. There is provided a system and method of manufacture of LIC electrodes using thin lithium film having holes therein, and in particular, to the process of manufacturing lithium loaded negative electrodes for lithium-ion capacitors by pre-lithiating electrodes with thin lithium metal films, wherein the thin lithium metal films include holes therein, and the lithium loaded negative electrodes are manufactured using a roll-to-roll lamination manufacturing process.

An energy storage device includes: a positive electrode plate containing a positive composite layer including a positive active material capable of occluding and releasing a lithium ion; and a negative electrode plate containing a negative composite layer including a negative active material capable of occluding and releasing a lithium ion. A peak pore diameter Rp of the positive composite layer in a pore distribution measured by a mercury penetration method is 0.5 μm or less, and a peak pore diameter Rn of the negative composite layer in a pore distribution measured by a mercury penetration method is 0.5 μm or less. A ratio Rp/Rn of the peak pore diameter of the positive composite layer to the peak pore diameter of the negative composite layer is 0.60 or more and 1.70 or less.

An energy storage device includes: a positive electrode plate containing a positive composite layer including a positive active material capable of occluding and releasing a lithium ion; and a negative electrode plate containing a negative composite layer including a negative active material capable of occluding and releasing a lithium ion. A peak pore diameter Rp of the positive composite layer in a pore distribution measured by a mercury penetration method is 0.5 μm or less, and a peak pore diameter Rn of the negative composite layer in a pore distribution measured by a mercury penetration method is 0.5 μm or less. A ratio Rp/Rn of the peak pore diameter of the positive composite layer to the peak pore diameter of the negative composite layer is 0.60 or more and 1.70 or less.

Provided herein is a negative active material including an ordered porous manganese oxide, wherein pores of the ordered porous manganese oxide have a bimodal size distribution. Provided herein is a method of preparing a negative active material that includes the ordered porous manganese oxide. The invention also includes a negative electrode which includes the negative active material and a lithium battery which includes the negative electrode.

Provided herein is a negative active material including an ordered porous manganese oxide, wherein pores of the ordered porous manganese oxide have a bimodal size distribution. Provided herein is a method of preparing a negative active material that includes the ordered porous manganese oxide. The invention also includes a negative electrode which includes the negative active material and a lithium battery which includes the negative electrode.

An electrolytic solution for lithium ion secondary batteries contains: a lithium salt electrolyte; an organic solvent; and an aliphatic compound having three or more carboxylic acid groups in a molecule. A lithium ion secondary battery includes: a cathode including a cathode active material that is capable of absorbing and releasing lithium and contains manganese (Mn) as a major transit metal species; an anode; and a non-aqueous electrolytic solution. The electrolytic solution is the above-described solution. The aliphatic compound has a molecular weight within the range from 50,000 to 500,000.

An electrolytic solution for lithium ion secondary batteries contains: a lithium salt electrolyte; an organic solvent; and an aliphatic compound having three or more carboxylic acid groups in a molecule. A lithium ion secondary battery includes: a cathode including a cathode active material that is capable of absorbing and releasing lithium and contains manganese (Mn) as a major transit metal species; an anode; and a non-aqueous electrolytic solution. The electrolytic solution is the above-described solution. The aliphatic compound has a molecular weight within the range from 50,000 to 500,000.

Provided is a capacitor in which, even in the case of a high maximum charging voltage, decomposition of the electrolyte can be suppressed and charging and discharging can be performed with stability. The capacitor includes a positive electrode containing a positive-electrode active material, a negative electrode containing a negative-electrode active material, a separator disposed between the positive electrode and the negative electrode, and an electrolyte, wherein the positive-electrode active material contains a porous carbon material, in a volume-based pore size distribution of the porous carbon material, a cumulative volume of pores having a pore size of 1 nm or less accounts for 85% or more of a total pore volume, the porous carbon material has a crystallite size of 1 to 10 nm, the porous carbon material contains an oxygen-containing functional group, and a content of the oxygen-containing functional group is 3.3 mol % or less.

Provided is a capacitor in which, even in the case of a high maximum charging voltage, decomposition of the electrolyte can be suppressed and charging and discharging can be performed with stability. The capacitor includes a positive electrode containing a positive-electrode active material, a negative electrode containing a negative-electrode active material, a separator disposed between the positive electrode and the negative electrode, and an electrolyte, wherein the positive-electrode active material contains a porous carbon material, in a volume-based pore size distribution of the porous carbon material, a cumulative volume of pores having a pore size of 1 nm or less accounts for 85% or more of a total pore volume, the porous carbon material has a crystallite size of 1 to 10 nm, the porous carbon material contains an oxygen-containing functional group, and a content of the oxygen-containing functional group is 3.3 mol % or less.

The present disclosure provides a prelithiated negative electrode, a preparation method thereof, and a lithium ion battery and a supercapacitor comprising the same. The prelithiated negative electrode comprises: an electrode film which is a solvent-free film-like negative electrode material composed of a negative electrode active material, a lithium-skeleton carbon composite material, a binder and optionally a conductive additive; and a metal current collector, wherein the electrode film is bonded on the metal current collector through a conductive adhesive. The present disclosure provides an effective method of prelithiating a negative electrode, and can effectively improve the first cycle efficiency of a lithium battery comprising a silicon-carbon negative electrode, contributing to increasing the specific capacity and cycle life of the battery. The present disclosure can also increase the energy density of a supercapacitor.