H01M4/0402

METHOD FOR MANUFACTURING DENSE LAYERS THAT CAN BE USED AS ELECTRODES AND/OR ELECTROLYTES FOR LITHIUM ION BATTERIES, AND LITHIUM ION MICROBATTERIES OBTAINED IN THIS WAY
20230148309 · 2023-05-11 ·

A method for manufacturing a dense layer that includes: supplying a substrate and a suspension of non-agglomerated nanoparticles of a material P; depositing a layer on the substrate using the suspension; drying the layer thus obtained; and densifying the dried layer by mechanical compression and/or heat treatment. The method is characterised in that the suspension of non-agglomerated nanoparticles of material P includes nanoparticles of material P having a size distribution having a value of D50. The distribution includes nanoparticles of material P of a first size D1 between 20 nm and 50 nm, and nanoparticles of material P of a second size D2 characterised by the value D50 being at least five times less than that of D1, or the distribution has a mean size of nanoparticles of material P less than 50 nm, and a standard deviation to mean size ratio greater than 0.6.

ALL-SOLID-STATE BATTERY INCLUDING OXIDE-BASED SOLID ELECTROLYTE FOR LOW-TEMPERATURE SINTERING PROCESS AND METHOD OF MANUFACTURING THE SAME
20230143908 · 2023-05-11 ·

The present disclosure relates to an oxide-based solid electrolyte for low-temperature sintering process and a method of manufacturing the same, and more particularly to a low-temperature sintering process having no problem of side reaction between a positive electrode active material and an oxide-based solid electrolyte through use of a low-melting point dissimilar oxide and a method of manufacturing an all-solid-state battery including a positive electrode manufactured thereby.

Printable ultra-violet light emitting diode curable electrolyte for thin-film batteries

An example composition is disclosed. For example, the composition includes a ultra-violet (UV) curable mixture of water, an acid, a phosphine oxide with one or more photoinitiators, a water miscible polymer, a salt, and a neutralizing agent. The composition can be used to form an electrolyte layer that can be cured in the presence of air when printing the thin-film battery.

METHOD OF INSULATING LITHIUM ION ELECTROCHEMICAL CELL COMPONENTS WITH METAL OXIDE COATINGS
20230207774 · 2023-06-29 · ·

Disclosed is a method for making a lithium-ion cell by depositing from an atmospheric plasma deposition device inorganic oxide particles produced from a precursor in an atmospheric plasma as a coating on a surface of a lithium-ion electrochemical cell component. The coating formed by the inorganic oxide particles may be an insulating coating or may provide dimensional stability during a thermal runaway.

METHOD OF PREPARING SLURRY WITH ANTI-DENDRITIC LITHIUM FOR COATING DRIED ON ANODE AND BATTERY SO MADE
20230207773 · 2023-06-29 ·

An anode passivation slurry of anti-dendritic lithium and a method of preparation are provided. The method comprises the steps of dissolving a divalent copper metal compound and a non-ionic polymer to obtain a first solution, dissolving trimesic acid to obtain a second solution, and mixing the first and second solutions to obtain a copper-based metal-organic framework. The dried precursor are mixed with ionic liquid, which has contained a first lithium salt, and then dried to obtain an anion impregnated copper-based metal-organic framework. Thereafter, an anion impregnated copper-based metal-organic framework, a second lithium salt, polymer materials, and a second solvent are mixed to obtain the anode passivation slurry. The anode passivation slurry homogenizes the concentration of conduction of lithium ions and improves ionic conductivity, reducing the formation of lithium dendrites, and improving the cycle life of batteries. A battery with the anode passivation slurry dried on an anode is also disclosed.

Method to Improve Sodium Electrochemical Interfaces of Sodium Ion-Conducting Ceramics

The present invention is directed to the modification of sodium electrochemical interfaces to improve performance of sodium ion-conducting ceramics in a variety of electrochemical applications. Enhanced mating of the separator-sodium interface by means of engineered coatings or other surface modifications results in lower interfacial resistance and higher performance at increased current densities, enabling the effective operation of molten sodium batteries and other electrochemical technologies at low and high temperatures.

Process for the solvent-free coating of foils for electrochemical applications

The present invention provides a solvent-free process for producing foil with a functional coating containing an active material and a meltable polymer, the foil with a functional coating and its use as an electrode foil, electrolyte in solid-state batteries or separator for electrochemical storage. The process comprises scattering a dry powder mixture onto a foil, melting the dry powder mixture, and calendering the foil covered with the molten powder.

Lithium nickel cobalt manganese oxide positive active material having concentration gradient of nickel, cobalt, and manganese and precursor thereof and preparation methods

A precursor of a modified ternary material for a lithium ion battery positive material belongs to the technical field of application of lithium ion battery positive materials. A molecular formula of the precursor is: (Ni.sub.1/3Co.sub.1/3Mn.sub.1/3)(OH).sub.2, and the precursor consists of three layers. An inner layer of the precursor is a ternary material with the Co content of more than ⅓ and equal Ni and Mn content, and the molecular formula of the inner layer of the precursor is: (Ni.sub.1/3−xCol/.sub.3+2xMn.sub.1/3−x(OH).sub.2, where 0<x<⅓. An outer layer of the precursor is a ternary material with the Co content of greater than 0 to ⅓ and equal Ni and Mn content, and the molecular formula of the outer layer of the precursor is: (Ni.sub.0.5−yCo.sub.2yMn.sub.0.5−y)(OH).sub.2, where 0<y<⅙. An intermediate layer of the precursor is a concentration gradient composite material of the two materials of the inner layer and the outer layer of the precursor. The modified ternary material containing the precursor has the chemical formula of Li(Ni.sub.1/3Co.sub.1/3Mn.sub.1/3)O.sub.2. The inside of each microscopic particle of the ternary material consists of three parts, namely, an inner layer, an intermediate layer and an outer layer. The present invention effectively improves the cyclic stability, thermal stability and compacted density, and has a high cost-performance advantage.

ELECTRONIC CIRCUITS WITH DIRECTLY INTEGRATED ELECTROCHEMICAL CELLS

Provided are electronic circuits, comprising electrochemical cells directly integrated with other devices of the circuits, and methods of manufacturing these circuits. The direct integration occurs during cell manufacturing, which allows sharing components, reducing operation steps and failure points, and reducing cost and size of the circuits. For example, a portion of a cell enclosure may be formed by a circuit board, providing direct mechanical integration. More specifically, the cell is fabricated right on the circuit board. In the same or other examples, one or both cell current collectors extend outside of the cell boundary and used by other devices, providing direct electrical integration without a need for intermediate connections and eliminating additional failure points. Furthermore, printing one or more components of electrochemical cells, such as electrolytes and current collectors, allows achieving higher levels of mechanical and electrical integration that are generally not available in conventional cells.

CAPACITANCE-BASED QUALITY MONITORING AND CONTROL IN BATTERY MANUFACTURING

A quality control system in a battery manufacturing process includes two or more capacitive measurement apparatuses to obtain a capacitance measurement from two or more intermediate products generated during the battery manufacturing process. The system also includes processing circuitry to obtain the capacitive measurement from the two or more capacitive measurement apparatuses, to determine a characteristic of the corresponding intermediate product, and to control at least one process of the battery manufacturing process that produced at least one of the two or more intermediate products based on the characteristic.