The present invention relates to an electrode assembly. The electrode comprises: a plurality of unit electrodes formed by connecting a plurality of electrodes made of an electrode mixture having a solid shape to each other; a separator interposed between the plurality of unit electrodes; and an electrode tab attached to the unit electrode, wherein the electrode tab comprises first and second electrode tabs, which are respectively attached to the unit electrodes and have different specific resistance.

An aspect of the present disclosure is a system that includes a first deposition system that includes a first cylinder having a first outer surface configured to hold a first substrate, a first spray nozzle configured to receive at least a first fluid, and a first fiber nozzle configured to receive at least a second fluid, where the first spray nozzle is configured to operate at a first voltage, the first fiber nozzle is configured to operate at a second voltage, the first cylinder is configured to be electrically connected to ground, the first spray nozzle is configured to apply onto the substrate a first plurality of at least one of particles or droplets from the first fluid, the first fiber nozzle is configured to apply onto the substrate a first fiber from the second fluid, and the first plurality of particles or droplets and the first fiber combine to form a first composite layer on the substrate.

A method of manufacturing a free-standing electrode film includes preparing a mixture including an electrode active material, a binder, and an additive solution or conductive paste, the additive solution or conductive paste being in an amount less than 5% by weight of the mixture and including a polymer additive and a liquid carrier, as well as a conductive material in the case of a conductive paste. The mixture may have total solid contents greater than 95% by weight. Preparing the mixture may include mixing the additive solution or conductive paste with the electrode active material to lubricate the electrode active material and subsequently adding and mixing in the binder. The method may further include subjecting the mixture to a shear force and, after the mixture has been subjected to the shear force, pressing the mixture into a free-standing film.

An all-solid secondary battery, including: a cathode; an anode; and a solid electrolyte layer disposed between the cathode and the anode, wherein the anode comprises an anode current collector; a first anode active material layer in contact with the anode current collector and comprising a first metal; a second anode active material layer disposed between the first anode active material layer and the solid electrolyte layer and comprising a carbon-containing active material; and a contact layer between the second anode active material layer and the solid electrolyte layer, and disposed such that the contact layer prevents contact between the second anode active material layer and the solid electrolyte layer, wherein the contact layer comprises a second metal, and has a thickness less than a thickness of the first anode active material layer.

A method of manufacturing an all-solid-state battery cell includes depositing an interlayer directly onto an anode current collector; depositing a solid electrolyte onto the interlayer opposite the anode current collector; forming a cathode on the solid electrolyte opposite the interlayer, wherein the cathode contains one or more lithium-containing compounds; and applying pressure to achieve uniform contact between layers. The manufactured all-solid-state battery cell is anode-free prior to charging. The interlayer is configured such that lithium metal is deposited between the interlayer and the anode current collector during charging, the interlayer prevents contact between the lithium metal and the solid electrolyte, and the interlayer has a greater density than a density of the solid electrolyte.

An energy storage device can include a cathode, an anode, and a separator between the cathode and the anode, where the anode and/or electrode includes an electrode film having a super-fibrillized binder material and carbon. The electrode film can have a reduced quantity of the binder material while maintaining desired mechanical and/or electrical properties. A process for fabricating the electrode film may include a fibrillization process using reduced speed and/or increased process pressure such that fibrillization of the binder material can be increased. The electrode film may include an electrical conductivity promoting additive to facilitate decreased equivalent series resistance performance. Increasing fibrillization of the binder material may facilitate formation of thinner electrode films, such as dry electrode films.

A method of making a lithiated silicon-based precursor material for a negative electrode material of an electrochemical cell that cycles lithium ions is provided. An admixture comprising a plurality of lithium particles and a plurality of silicon particles is briquetted by applying pressure of greater than or equal to about 10 MPa and applying heat at a temperature of less than or equal to about 180° C. to form a precursor briquette. The briquette has lithium particles and silicon particles distributed in a matrix and has a porosity level of less than or equal to about 60% of the total volume of the precursor briquette. The briquetting is conducted in an environment having less than or equal to about 0.002% by weight of any oxygen-bearing species or nitrogen (N.sub.2).

Disclosed is a method of preparing a negative electrode which includes the steps of: forming a cell by sequentially stacking a preliminary negative electrode, a separator, and a lithium metal, immersing the cell in an electrolyte solution comprising a lithium salt and a solvent; applying a current after the cell is immersed in the electrolyte solution containing the lithium salt and the solvent, separating the preliminary negative electrode from the cell after removing the cell immersed in the electrolyte solution from the electrolyte solution, washing the separated preliminary negative electrode, performing a first drying on the washed preliminary negative electrode at room temperature, and performing a second drying on the first dried preliminary negative electrode at a temperature ranging from 30° C. to 70° C. in a vacuum state.

In solid-state lithium-ion battery cells, electrolyte-infiltrated composite electrode includes an electrolyte component consisting of polymer matrix with ceramic nanoparticles embedded in the matrix to form networking structure of electrolyte. The networking structure establishes effective lithium-ion transport pathway in the electrode. Electrolyte-infiltrated composite electrode sheets and solid electrolyte membranes can be used in all solid-state lithium electrochemical pouch and coin cells. Solid-state lithium-ion battery is fabricated by: (a) providing an anode layer; (b) providing a cathode layer; (c) positioning a ceramic-polymer composite electrolyte membrane between the anode layer and the cathode layer to form a laminar battery assembly; (d) applying pressure to the laminar battery assembly; and (e) heating the laminar battery assembly. Pressure-aided co-curing strengthens the contacts between the electrodes and the solid electrolyte membrane thus creating stable electrode-membrane interfaces with fewer porous regions. Lithium electrochemical cells and batteries exhibit excellent rate performance and outstanding stability over wide temperature range.

A method for preparing a solid electrolyte for an all-solid state battery, may include obtaining a slurry by dispersing a first raw material comprising lithium sulfide; and a second raw material selected from the group consisting of silicon sulfide, phosphorus sulfide, germanium sulfide, boron sulfide, and a combination thereof in a solvent; and drying the slurry.