A process and system for creating a lithium ion anolyte from lithium alloys. Metal and lithium alloys are processed to remove the metal with lithium from the alloy remaining. A lithium ion anolyte formed may be used in a process to form lithium metal. Alternatively, a process and system for recovering lithium from sources such as lithium alloys and lithium metal oxides and other feedstock such as recycled batteries into a thin lithium metal film via electrodeposition in an organic electrolyte contacting both anode (holder for lithium source) and cathode (substrate for lithium deposition) in a single-compartment electrolysis cell.

To provide a fabricating method and a fabricating apparatus for a lithium-ion secondary battery having stable charge characteristics and lifetime characteristics. A positive electrode is subjected to an electrochemical reaction in a large amount of electrolytic solution in advance before a secondary battery is completed. In this manner, the positive electrode can have stability. The use of the positive electrode enables fabrication of a highly reliable secondary battery. Similarly, a negative electrode is subjected to an electrochemical reaction in a large amount of electrolytic solution in advance. The use of the negative electrode enables fabrication of a highly reliable secondary battery.

The formation method of graphene includes the steps of forming a layer including graphene oxide over a first conductive layer; and supplying a potential at which the reduction reaction of the graphene oxide occurs to the first conductive layer in an electrolyte where the first conductive layer as a working electrode and a second conductive layer with a as a counter electrode are immersed. A manufacturing method of a power storage device including at least a positive electrode, a negative electrode, an electrolyte, and a separator includes a step of forming graphene for an active material layer of one of or both the positive electrode and the negative electrode by the formation method.

A lithium electrode includes a first lithium layer made of lithium or a lithium alloy, a current collector situated on a first side of the lithium layer, and a lithium-ion-conducting protective layer situated on a second side of the lithium layer opposite the first side. An intermediate layer completely covers the second side of the lithium layer and is situated between the lithium layer and the protective layer. The protective and intermediate layers have an electrical conductivity of less than 10.sup.10 S/cm. The lithium electrode may be used as the anode of a rechargeable lithium-ion battery. A lithium layer is applied to a current collector, an intermediate layer is applied to the lithium layer so that the intermediate layer completely covers the lithium layer, and a lithium-ion-conducting protective layer is applied to the intermediate layer.

An electrolytic copper foil capable of improving a capacity retention rate of a secondary battery, an electrode including the same, a secondary battery including the same, and a method of manufacturing the same. The electrolytic copper foil, which includes a first surface and a second surface opposite the first surface, includes a copper layer including a matte surface facing the first surface and a shiny surface facing the second surface, and a first protective layer on the matte surface of the copper layer, wherein the first surface has a peak density (PD) of 3 to 110, a texture coefficient [TC(220)] of a (220) plane of 1.32 or less, and a surface roughness (Rz) of 0.5 to 2.7 m.

A method (10) for the processing of lithium containing brines, the method comprising the method steps of: (i) Passing a lithium containing brine (12) to a filtration step (14) to remove sulphates; (ii) Passing a product (16) of step (i) to a first ion exchange step (18) to remove divalent impurities; (iii) Passing a product (20) of step (ii) to a second ion exchange step (22) to remove boron impurities; (iv) Passing a product (24) of step (iii) to an electrolysis step (26) to produce lithium hydroxide (28); and (v) Passing a product (30) of step (iv) to a crystallisation step (32) that in turn provides a lithium hydroxide monohydrate product (34).

A method (10) for the processing of lithium containing brines, the method comprising the method steps of: (i) Passing a lithium containing brine (12) to a filtration step (14) to remove sulphates; (ii) Passing a product (16) of step (i) to a first ion exchange step (18) to remove divalent impurities; (iii) Passing a product (20) of step (ii) to a second ion exchange step (22) to remove boron impurities; (iv) Passing a product (24) of step (iii) to an electrolysis step (26) to produce lithium hydroxide (28); and (v) Passing a product (30) of step (iv) to a crystallisation step (32) that in turn provides a lithium hydroxide monohydrate product (34).

The present invention relates to a copper foil current collector having superior adhesion to an active material of a Li secondary battery. The electrolytic copper foil of the present invention having a first surface and a second surface comprises: a first protective layer at the first surface; a second protective layer at the second surface; and a copper film between the first and second protective layers, wherein an oxygen-containing part at the second surface has a thickness (OT) of not less than 1.5 nm. According to the present invention, an electrolytic copper foil current collector for a Li secondary battery, which has low electric resistance and high adhesion to an active material, can be provided.

The present invention relates to nanostructured materials for use in rechargeable energy storage devices such as lithium batteries, particularly rechargeable secondary lithium batteries, or lithium-ion batteries (LIBs). The present invention includes materials, components, and devices, including nanostructured materials for use as battery active materials, and lithium ion battery (LIB) electrodes comprising such nanostructured materials, as well as manufacturing methods related thereto. Exemplary nanostructured materials include silicon-based nanostructures such as silicon nanowires and coated silicon nanowires, nanostructures disposed on substrates comprising active materials or current collectors such as silicon nanowires disposed on graphite particles or copper electrode plates, and LIB anode composites comprising high-capacity active material nanostructures formed on a porous copper and/or graphite powder substrate.

A film and a manufacturing process thereof, including a base layer, where each of front and back sides of the base layer is provided with a bonding layer, a functional layer, and a protective layer in sequence; the functional layer is composed of a first composite copper layer and/or a second composite copper layer; the first composite copper layer is formed by repeating copper coating on a surface of the bonding layer 2 to 500 times; and the second composite copper layer is formed by repeating copper coating on a surface of the bonding layer 2 to 500 times. The film has low cost, simple process, and prominent appearance performance, and the present disclosure belongs to the technical field of energy storage unit materials.