Provided is a binder composition for a non-aqueous secondary battery electrode with which it is possible to form an electrode having excellent electrolyte solution injectability and process adhesiveness. The binder composition for a non-aqueous secondary battery electrode contains a particulate polymer formed by a polymer that includes a block region composed of an aromatic vinyl monomer unit and has a tetrahydrofuran-insoluble content of not less than 5 mass % and not more than 40 mass %. The binder composition for a non-aqueous secondary battery electrode preferably further contains a water-soluble polymer that includes a hydrophilic group and has a weight-average molecular weight of not less than 15,000 and not more than 500,000.

One of the objects of the present invention is to suppress mixing of a first layer and a second layer while forming the second layer before drying the first layer when manufacturing the electrode for the secondary battery in which the first layer and the second layer are laminated on the current collector. A method for manufacturing an electrode used as a positive electrode and a negative electrode of a secondary battery according to the present invention comprises applying a first layer slurry to a surface of a current collector, applying a second layer slurry on the first layer slurry before the first layer slurry is dried, and drying the first layer slurry and the second layer slurry after applying the first layer slurry and the second layer slurry to obtain a laminated structure in which a first layer and a second layer are laminated in this order on the current collector. A viscosity of the first layer slurry is 12000 mPa.Math.s or more, and/or a viscosity of the second layer slurry is 4000 mPa.Math.s or more when the viscosities of the first layer slurry and the second layer slurry are measured at 25° C. with a shear rate of 1/sec.

One of the objects of the present invention is to suppress mixing of a first layer and a second layer while forming the second layer before drying the first layer when manufacturing the electrode for the secondary battery in which the first layer and the second layer are laminated on the current collector. A method for manufacturing an electrode used as a positive electrode and a negative electrode of a secondary battery according to the present invention comprises applying a first layer slurry to a surface of a current collector, applying a second layer slurry on the first layer slurry before the first layer slurry is dried, and drying the first layer slurry and the second layer slurry after applying the first layer slurry and the second layer slurry to obtain a laminated structure in which a first layer and a second layer are laminated in this order on the current collector. A viscosity of the first layer slurry is 12000 mPa.Math.s or more, and/or a viscosity of the second layer slurry is 4000 mPa.Math.s or more when the viscosities of the first layer slurry and the second layer slurry are measured at 25° C. with a shear rate of 1/sec.

The present invention provides a vapour deposition method for preparing an amorphous lithium borosilicate or doped lithium borosilicate compound, the method comprising: providing a vapour source of each component element of the compound, wherein the vapour sources comprise at least a source of lithium, a source of oxygen, a source of boron, and a source of silicon, and, optionally, a source of at least one dopant element; delivering a flow of said lithium, said oxygen, said boron and said silicon, and, optionally, said dopant element; and co-depositing the component elements from the vapour sources onto a substrate wherein the component elements react on the substrate to form the amorphous compound; wherein the amorphous lithium borosilicate or doped lithium borosilicate ompound has a lithium content in the range 40-65 atomic %, based on the combined atomic percentages of lithium, boron and silicon.

A storage device having excellent cycle lifetime, an electrode used in this storage device, and a production method of the electrode are provided. An electrode comprising an active material and a conductive carbon including oxidized carbon. A surface of the active material is covered by the conductive carbon. A Raman spectrum of the active material covered by the conductive carbon includes a peak intensity (a) derived from the active material and a peak intensity (b) of D-band derived from the conductive carbon. A peak intensity ratio (b)/(a) between the peak intensity (a) and the peak intensity (b) is 0.25 or more.

A doped phosphorus-sulfur iodide solid electrolyte, a preparation method therefor, and use thereof. The chemical formula of said solid electrolyte is Li.sub.6-xM.sub.xP.sub.1-xS.sub.5I, in which 0<x<0.8, and M is tungsten and/or molybdenum. Said method comprises: 1) mixing a lithium source, a phosphorus source, an iodine source, a sulfur source, and an M source in an inert atmosphere, and then ball-milling same to obtain a solid electrolyte precursor; and 2) sintering the solid electrolyte precursor obtained in step 1) in an inert atmosphere or in vacuum to obtain the doped phosphorus-sulfur iodide solid electrolyte.

With respect to a secondary battery of one embodiment of the present invention, at least one of a positive electrode core body and a negative electrode core body is configured such that the tensile elongation in the central part in the width direction is higher than the tensile elongation in both end parts in the width direction. With respect to a secondary battery of another embodiment of the present invention, at least one of a positive electrode core body and a negative electrode core body is configured such that the number of crystal grains per unit area in the central part in the width direction is smaller than the number of crystal grains per unit area in both end parts in the width direction.

A doping system is configured to dope an active material included in an electrode with an alkali metal. The doping system includes a doping bath, a conveyor unit, a connection unit, and a drying unit. The doping bath is configured to store a solution containing alkali metal ion and a counter electrode unit. The conveyor unit is configured to convey the electrode along a path that passes through the doping bath. The connection unit includes an electrically conductive electric power supply roller that contacts the electrode, and is configured to couple the electrode to the counter electrode unit. The drying unit is configured to spray a gas onto the electrode that passes through the doping bath and is being conveyed to the electric power supply roller.

A negative electrode for lithium secondary batteries and a method of manufacturing the same are provided. The negative electrode includes a negative electrode current collector and a lithiophilic material formed on at least one surface of the negative electrode current collector, wherein the lithiophilic material is an oxidized product of a coating material coated on the negative electrode current collector and includes at least one of a metal or a metal oxide, and an oxide layer is formed on a surface of the negative electrode current collector having the lithiophilic material formed thereon.

A negative electrode for lithium secondary batteries is provided. The negative electrode comprises a negative electrode current collector including a porous structure having an inner pore or a through-hole formed therethrough from an upper surface to a lower surface thereof, wherein a lithiophilic material is applied to a surface of the porous structure or the through-hole excluding a first surface of the negative electrode current collector that faces a positive electrode.