An apparatus for pre-lithiating a negative includes a pre-lithiation reactor sequentially divided into an impregnation section, a pre-lithiation section and an aging section, and accommodates a pre-lithiation solution in which a negative electrode structure is moved; a negative electrode roll arranged outside the pre-lithiation solution and on which the negative electrode structure before being moved is wound; a lithium metal counter electrode arranged in the pre-lithiation solution in the pre-lithiation section and is spaced apart from the negative electrode structure by a predetermined distance to face the negative electrode structure which is moved in the pre-lithiation solution; and a charge and discharge unit connected to the negative electrode structure and the lithium metal counter electrode, in which a separation distance between the lithium metal counter electrode and the negative electrode structure is in a range of 7 to 15 mm. A method for pre-lithiating the negative electrode is also provided.

A method for producing an all-solid multilayer battery, and an all-solid multilayer battery. The all-solid multilayer battery may be produced by depositing, by electrophoresis without any binder, at least one anode layer, at least one electrolyte layer, and at least one cathode layer. The at least one electrolyte layer, and the at least one cathode layer are obtained from a colloidal suspension containing nanoparticles that are not agglomerated with each other to create clusters and remain isolated from each other. A layer of Ms bonding material is then deposited on a surface of the at least one electrolyte layer. Next, two layers from the at least one dense anode layer, the at least one dense electrolyte layer, and the at least one dense cathode layer, are stacked face-to-face to obtain the all-solid multilayer battery having an assembly of a plurality of elementary cells connected with one another in parallel.

A method for producing an all-solid multilayer battery, and an all-solid multilayer battery. The all-solid multilayer battery may be produced by depositing, by electrophoresis without any binder, at least one anode layer, at least one electrolyte layer, and at least one cathode layer. The at least one electrolyte layer, and the at least one cathode layer are obtained from a colloidal suspension containing nanoparticles that are not agglomerated with each other to create clusters and remain isolated from each other. A layer of Ms bonding material is then deposited on a surface of the at least one electrolyte layer. Next, two layers from the at least one dense anode layer, the at least one dense electrolyte layer, and the at least one dense cathode layer, are stacked face-to-face to obtain the all-solid multilayer battery having an assembly of a plurality of elementary cells connected with one another in parallel.

A method of making a positive electrode includes forming a slurry of particles using an electrode formulation, a diluent, and oxalic acid, coating the slurry on a collector and drying the coating on the collector to form the positive electrode. The electrode formulation includes an electrode active material, a conductive carbon source, an organic polymeric binder, and a water soluble polymer. The diluent consists essentially of water.

A method of making a positive electrode includes forming a slurry of particles using an electrode formulation, a diluent, and oxalic acid, coating the slurry on a collector and drying the coating on the collector to form the positive electrode. The electrode formulation includes an electrode active material, a conductive carbon source, an organic polymeric binder, and a water soluble polymer. The diluent consists essentially of water.

Provided are various embodiments of a positive electrode for a secondary battery, which in one embodiment includes a first positive electrode material mixture layer formed on a positive electrode collector, and a second positive electrode material mixture layer formed on the first positive electrode material mixture layer, wherein the first positive electrode material mixture layer has an operating voltage of 4.25 V to 6.0 V and includes an active material for overcharge which generates lithium and gas during charge; a method of preparing such a positive electrode for a secondary battery; and a lithium secondary battery including such a positive electrode.

Provided is a technique relating to a slurry for a non-aqueous secondary battery that can stably be applied onto a battery member surface even in a situation in which an inkjet method is adopted. A method of producing the slurry for a non-aqueous secondary battery includes a degassing step of reducing the dissolved carbon dioxide gas concentration of a mixture containing a particulate polymer (A) and water.

Provided is a technique relating to a slurry for a non-aqueous secondary battery that can stably be applied onto a battery member surface even in a situation in which an inkjet method is adopted. A method of producing the slurry for a non-aqueous secondary battery includes a degassing step of reducing the dissolved carbon dioxide gas concentration of a mixture containing a particulate polymer (A) and water.

To detect the state of a slurry during stirring without exposure to the atmosphere and with high accuracy. A stirring tank stores a slurry for a battery without exposure to the atmosphere. A stirring device stirs the slurry in the stirring tank. An observation container is coupled to the stirring tank. A circulation device circulates the slurry between the stirring tank and the observation container without exposure to the atmosphere. A detection device detects the state of the slurry by irradiating the slurry in the observation container with X-rays and detecting the X-rays transmitted through the slurry.

To detect the state of a slurry during stirring without exposure to the atmosphere and with high accuracy. A stirring tank stores a slurry for a battery without exposure to the atmosphere. A stirring device stirs the slurry in the stirring tank. An observation container is coupled to the stirring tank. A circulation device circulates the slurry between the stirring tank and the observation container without exposure to the atmosphere. A detection device detects the state of the slurry by irradiating the slurry in the observation container with X-rays and detecting the X-rays transmitted through the slurry.