Provided herein is a method of preparing carbon-graphene-lead composite particles, comprising the steps of forming a dispersion of lead particles, graphene particles and cellulose in an aqueous solution, spray drying the dispersion to aggregate the lead particles, graphene particles and cellulose to form cellulose-graphene-lead composite particles, and heating the cellulose-graphene-lead composite particles, to carbonize the cellulose to result in the formation of the carbon-graphene-lead composite particles.

The organic expander in a negative electrode material of a lead-acid battery contains an S polymer having an aromatic ring and an L polymer having an aromatic ring, and a mass MS1 of the S polymer and a mass ML1 of the L polymer satisfy 0.05≤ML1/(ML1+MS1)≤0.15.

Embodiments related to electrodes comprising composite mixtures and related devices (e.g., convection batteries), systems, and methods are disclosed.

An accumulator having a plurality of electrode plates which are adjacently arranged and form at least one electrode plate stack in the form of a block, wherein each electrode plate comprises a frame having a grid arranged therein and wherein at least the grid is filled with an active mass, and wherein each electrode plate comprises at least one connecting lug protruding beyond the frame, wherein the connecting lugs of same-polarity electrode plates are arranged adjacent to one another in a row, wherein the connecting lugs adjacently arranged in a row are materially bonded together electrically and mechanically into a connecting lug block by at least one weld or solder point arranged between the connecting lugs. Further described is a method for manufacturing an accumulator.

An accumulator having a plurality of electrode plates which are adjacently arranged and form at least one electrode plate stack in the form of a block, wherein each electrode plate comprises a frame having a grid arranged therein and wherein at least the grid is filled with an active mass, and wherein each electrode plate comprises at least one connecting lug protruding beyond the frame, wherein the connecting lugs of same-polarity electrode plates are arranged adjacent to one another in a row, wherein the connecting lugs adjacently arranged in a row are materially bonded together electrically and mechanically into a connecting lug block by at least one weld or solder point arranged between the connecting lugs. Further described is a method for manufacturing an accumulator.

A lead-acid battery is disclosed. The lead-acid storage battery has a container with a cover, the container including one or more compartments. One or more cell elements are provided in the one or more compartments. The one or more cell elements include a positive plate, the positive plate having a positive grid and a positive electrochemically active material on the positive grid; a negative plate, the negative plate having a negative grid and a negative electrochemically active material on the negative grid, wherein the negative electrochemically active material comprises barium sulfate and an organic expander; and a separator between the positive plate and the negative plate. Electrolyte is provided within the container. One or more terminal posts extend from the cover and are electrically coupled to the one or more cell elements.

A machine and process for making a composite battery electrode with a conductive lead cast ribbon extending along and attached to a portion of a carbon fiber material. A lead ribbon may be continuously cast along a longitudinally elongate strip of carbon fiber material. The ribbon may be cast along an edge or edges of a longitudinally elongate strip of carbon fiber material.

A shoe for dispensing a molten metal such as lead into a mold cavity of a rotating dmm to continuously cast a web of a plurality of serially connected grids or battery composite electrodes of a carbon fiber material with a cast metal conductor. The shoe may have at least one elongate orifice slot in a face confronting the drum, a molten metal supply passage communicating with the Norifice slot and an excess molten metal return slot opening into the confronting face downstream of the supply slot relative generally to the direction of rotation of the dmm.

A method for forming a connection such as an electrical connection, to a fibre material electrode element comprises moving a length of the fibre material relative to a pressure injection stage and pressure impregnating by a series of pressure injection pulses a lug material into a lug zone part of the fibre material to surround and/or penetrate fibres of the fibre material and form a lug strip in the lug zone. The fibre material may be a carbon fibre material and the lug material a metal such as Pb or a Pb alloy. Apparatus for forming an electrical connection to a fibre material electrode element is also disclosed.

A method for forming a connection such as an electrical connection, to a fibre material electrode element comprises moving a length of the fibre material relative to a pressure injection stage and pressure impregnating by a series of pressure injection pulses a lug material into a lug zone part of the fibre material to surround and/or penetrate fibres of the fibre material and form a lug strip in the lug zone. The fibre material may be a carbon fibre material and the lug material a metal such as Pb or a Pb alloy. Apparatus for forming an electrical connection to a fibre material electrode element is also disclosed.