In one embodiment, a lead strip caster for battery grids includes a ladle, a nozzle, and a pair of rollers. The lead strip caster produces a continuous lead strip for use as battery positive plate grids. The ladle has an inlet to receive molten lead and has an outlet. The nozzle has at least one passage that communicates with the outlet of the ladle in order to receive molten lead from the ladle. The first roller is situated at a first exterior side of the nozzle. The first roller rotates via a first driver. The second roller is situated at a second exterior side of the nozzle. The second roller rotates via a second driver.

A method of prolonging service life of an energy storage device such as a lithium-ion battery includes temporarily operating the battery at an elevated current density. Cycling of lithium-ion batteries at regular current densities results in the generation of lithium-metal dendrites at the surface of the anode, particularly in batteries where the anode is lithium metal. The lithium metal dendrites pose a threat to damage other components of the battery, such as separators, as well as causing an electrical short. Operating the battery in bursts at the elevated current density results in self-heating at the anode surface that merges adjacent lithium-metal dendrites and an overall smoothing of the anode surface. This method is also applicable to other alkali-metal-based batteries and chemistries.

The present disclosure provides an electrolyte solution of a lead-crystal storage battery, a preparation method thereof, and a lead-crystal storage battery. The electrolyte solution comprises silica sol and precipitated silica in a mass ratio of 1:(0.005 to 0.05); a total content of silica in the electrolyte solution is from 1% to 4% as per a net content of the silica; the electrolyte solution further comprises 0.1% to 2% of lithium hydroxide based on a total amount of the electrolyte solution. Upon the completion of a formation step of the battery, the electrolyte solution changes from a flow dynamic state to a solidified electrolyte solution containing crystal particles. By using specific gelling agents in combination and adding a relatively large amount of lithium hydroxide in the electrolyte solution to facilitate the electrolyte solution becoming a solidified electrolyte solution containing crystal particles after a charge-discharge cycle, the present disclosure can have active materials of the electrode plates fixed firmly, and enhance the deep cycle capacity of the battery; a porous structure further provides enough space for ion motion to extend battery service life and improve low temperature performance and charge retention.

The present disclosure provides an electrolyte solution of a lead-crystal storage battery, a preparation method thereof, and a lead-crystal storage battery. The electrolyte solution comprises silica sol and precipitated silica in a mass ratio of 1:(0.005 to 0.05); a total content of silica in the electrolyte solution is from 1% to 4% as per a net content of the silica; the electrolyte solution further comprises 0.1% to 2% of lithium hydroxide based on a total amount of the electrolyte solution. Upon the completion of a formation step of the battery, the electrolyte solution changes from a flow dynamic state to a solidified electrolyte solution containing crystal particles. By using specific gelling agents in combination and adding a relatively large amount of lithium hydroxide in the electrolyte solution to facilitate the electrolyte solution becoming a solidified electrolyte solution containing crystal particles after a charge-discharge cycle, the present disclosure can have active materials of the electrode plates fixed firmly, and enhance the deep cycle capacity of the battery; a porous structure further provides enough space for ion motion to extend battery service life and improve low temperature performance and charge retention.

A machine and process for making a composite battery electrode with a conductive lead cast ribbon extending along and attached to a portion of a carbon fiber material. A lead ribbon may be continuously cast along a longitudinally elongate strip of carbon fiber material. The ribbon may be cast along an edge or edges of a longitudinally elongate strip of carbon fiber material.

The invention relates to a lead acid battery assembly comprising plurality of cells which are disposed within a housing and each cell having two electrodes namely positive plate and negative plate placed in a volume of an electrolyte in the housing. The cell formed comprises as per the invention at least one electrode plate prepared with a multilayered structure comprising a graphite composite material having higher electronic conductivity during charging and discharging of the battery assembly. The electrode plate structure formed is a three layered plate comprises a first base/substrate layer (100) made of electrically conductive material; a second transition layer (110) made of graphite composite material being adhered to the first base layer using an adhesive agent; and a third chemically active conductive layer (120) surrounding the second transition layer (110)

Provided herein is a method of preparing carbon-graphene-lead composite particles, comprising the steps of forming a dispersion of lead particles, graphene particles and cellulose in an aqueous solution, spray drying the dispersion to aggregate the lead particles, graphene particles and cellulose to form cellulose-graphene-lead composite particles, and heating the cellulose-graphene-lead composite particles, to carbonize the cellulose to result in the formation of the carbon-graphene-lead composite particles.

The present disclosure discloses a method for forming a lead-carbon compound interface layer on a lead-based substrate, wherein the lead-based substrate has a surface, and the method includes steps of: causing an acidic solution to contact with a carbon material and a lead-containing material to form a carbon-containing plumbate precursor having an ionic lead; and reducing the ionic lead in the carbon-containing plumbate precursor to form the lead-carbon compound interface layer on the surface.

A negative electrode of a secondary battery may include an electrode plate including lead; and an active material layer provided on the electrode plate and including composite particles having a core-shell structure, wherein a core of the composite particle includes lead; a shell of the composite particle includes carbon; and a specific surface area of the composite particles is 1 to 5,000 m.sup.2/g.

The inventive subject matter is directed to continuous electrochemical production of highly pure micro- or nanostructured lead that at least partially encloses the electroprocessing solvent and molecular hydrogen and optional guest compounds to form a mixed matrix. Such compositions are particularly suitable for cold forming of various structures and/or for alloy and composite material production.