The present invention relates to zinc electrode and to methods of producing zinc electrode and particularly to a method of producing zinc electrode providing dimensional/geometrical stability during a battery charge/discharge operation. The invention provides methods of use of batteries comprising the zinc electrode of this invention. Applications of batteries of this invention include electric vehicles, portable electronics and drones.

An article having a continuous network of zinc and a continuous network of void space interpenetrating the zinc network. The zinc network is a fused, monolithic structure. A method of: providing an emulsion having a zinc powder and a liquid phase; drying the emulsion to form a sponge; annealing and/or sintering the sponge to form an annealed and/or sintered sponge; heating the annealed and/or sintered sponge in an oxidizing atmosphere to form an oxidized sponge having zinc oxide on the surface of the oxidized sponge; and electrochemically reducing the zinc oxide to form a zinc metal sponge.

Provided is a secondary battery including a power generation unit including a positive electrode layer, a negative electrode layer, a porous separator, and an electrolytic solution. The negative electrode layer is a dissolution-deposition electrode. When viewed in plan view, a functional region, identified as a region where the positive electrode layer, the negative electrode layer, the electrolytic solution, and the porous separator overlap, is divided into power generation regions and a linear non-power generation region demarcating each power generation region. The power generation regions have a value α of 30 or less, the value α being defined by the equation: α=ΦP/wt, wherein Φ represents an area equivalent diameter (mm) per region of the power generation regions, P represents a thickness (mm) of the negative electrode layer, w represents a line width (mm) of the non-power generation region, and t represents a thickness (mm) of the porous separator.

An alkaline battery includes a negative electrode. The negative electrode includes a negative electrode active material particle. The negative electrode active material particle includes a center part, a covering layer, and island-form layers. The center part includes zinc as a constituent element. The covering layer covers a surface of the center part and includes gallium as a constituent element. The island-form layers are present on a surface of the covering layer and include indium as a constituent element.

An alkaline electrochemical cell includes a cathode, an anode which includes an anode active material, and a non-conductive separator disposed between the cathode and the anode, wherein from about 20% to about 50% by weight of the anode active material relative to a total amount of anode active material has a particle size of less than about 75 μm, and wherein the separator includes a unitary, cylindrical configuration having an open end, a side wall, and integrally formed closed end disposed distally to the open end.

A method of: providing an emulsion having a zinc powder and a liquid phase; drying the emulsion to form a sponge; sintering the sponge in an inert atmosphere to form a sintered sponge; heating the sintered sponge in an oxidizing atmosphere to form an oxidized sponge having zinc oxide on the surface of the oxidized sponge; and heating the oxidized sponge in an inert atmosphere at above the melting point of the zinc. A method of: providing an emulsion comprising a zinc powder and a liquid phase; placing the emulsion into a mold, wherein the emulsion is in contact with a metal substrate; and drying the emulsion to form a sponge.

The present invention provides novel cathodes having a reduced resistivity and other improved electrical properties. Furthermore, this invention also presents methods of manufacturing novel electrochemical cells and novel cathodes. These novel cathodes comprise a silver material that is doped with a silicate material.

A polymer electrolyte includes a polyethylene oxide matrix, a plasticizer additive, a solute, and a filler. The plasticizer additive includes an ionic liquid and the filler includes zinc oxide. An energy storage device includes an anode, a cathode and the polymer electrolyte. An energy storage device includes a zinc anode, a cathode and a polymer electrolyte, in which the polymer electrolyte includes a polyethylene oxide matrix and a plasticizer additive that includes an ionic liquid.

A secondary zinc-manganese dioxide secondary cell is disclosed. The cell includes a zinc gel anode, high manganese content cathode in either prismatic or jelly roll form. An aqueous based continuous reel to reel process for formulation and fabrication of the anode and cathode is provided. The cell is contained in a box assembly.

The invention is directed towards a battery. The battery includes a cathode, an anode, a separator between the cathode and the anode, and an electrolyte. The cathode includes a conductive additive and an electrochemically active cathode material. The electrochemically active cathode material includes a beta-delithiated layered nickel oxide. The beta-delithiated layered nickel oxide has a chemical formula. The chemical formula is Li.sub.xA.sub.yNi.sub.1+a−zM.sub.zO.sub.2.nH.sub.2O where x is from about 0.02 to about 0.20; y is from about 0.03 to about 0.20; a is from about 0 to about 0.2; z is from about 0 to about 0.2; and n is from about 0 to about 1. Within the chemical formula, A is an alkali metal. The alkali metal includes potassium, rubidium, cesium, and any combination thereof. Within the chemical formula, M comprises an alkaline earth metal, a transition metal, a non-transition metal, and any combination thereof. The anode includes an electrochemically active anode material. The electrochemically active anode material includes zinc, zinc alloy, and any combination thereof.