The invention discloses a high voltage rechargeable Zn—MnO.sub.2 battery. The structure of the Zn—MnO.sub.2 battery includes zinc electrode/alkaline electrolyte/ion exchange membrane/acid electrolyte/MnO.sub.2 electrode. The ion exchange membrane comprises a cation exchange membrane, an anion exchange membrane or a proton exchange membrane. According to the invention, by using a composite electrolyte system (alkaline electrolyte/ion exchange membrane/acid electrolyte), a high voltage rechargeable Zn—MnO.sub.2 battery is obtained. According to the invention, an open circuit voltage of up to 2.7V is obtained, greatly improving the discharge voltage, and at the same time increasing the discharge capacity and enabling cyclic charge and discharge. The invention is of great importance in science research, beneficial to society and economics.

A secondary battery according to an embodiment includes a container, an electrolytic solution, a cathode and an anode, and a flow mechanism. The container includes an opening on a bottom surface thereof. The electrolytic solution is disposed in the container. The cathode and the anode are disposed in the electrolytic solution. The flow mechanism includes a generation part that is connected to the container via the opening and generates a gas bubble(s) in the container through the opening, and that causes the electrolytic solution to flow. A protrusion part that is positioned at an edge part of the opening and extends in upward and downward directions is disposed on the bottom surface.

An alkaline battery comprises an anode, a cathode, a separator disposed between the anode and the cathode, a barrier layer disposed between the anode and the cathode, and an electrolyte in fluid communication with the anode, the cathode, and the separator. The barrier layer is at least one of: an organic polymer film or a porous inorganic layer or combinations thereof.

In some embodiments, a battery comprises an anode, a cathode, a separator disposed between the anode and the cathode, and an electrolyte in fluid communication with the anode, the cathode, and the separator. The anode can be a porous metallic zinc anode. The porous metallic zinc anode comprises pure zinc electrode, a substrate coated with zinc, a zinc substrate with a coating layer, or combinations thereof.

In one embodiment, a battery cell can include a cathode including at least one of MnO or Mn(OH)2. The battery can also include an anode including at least one of ZnO or Zn(OH)2 and an electrolyte. The battery cell can be a rechargeable battery cell with total capacity before first charge or discharge of less than 30% of total capacity of this battery in a fully charged state.

A method for manufacturing zinc negative electrodes includes mixing a powder including zinc with polytetrafluoroethylene to form a homogenous blend, injecting a lubricant into the homogenous blend to form a dough, kneading the dough to form a fibrillated dough, and extruding the fibrillated dough through a die to form a ribbon. The method also includes calendering the ribbon to a target thickness to form a plaque, drying the plaque to form an active material sheet, laminating portions of the active material sheet to a current collector substrate such that the current collector substrate is sandwiched between the portions to form an electrode blank, and sectioning the electrode blank into zinc negative electrodes.

The invention relates to a starved metal hydride battery. The battery is characterized in that the battery further comprises adding of oxygen gas or hydrogen gas or hydrogen peroxide or a combination thereof in order to rebalance the electrodes and replenish the electrolyte by reactions with the electrode materials.

The present invention relates to a silicon-based particle-polymer composite, which includes silicon-based particles; and a polymer coating layer formed on the silicon-based particles, in which the polymer coating layer includes metal-substituted poly(acrylic acid) in which hydrogen atoms in carboxyl groups of the poly(acrylic acid) chain are substituted with one or more selected from the group consisting of K, Na and Li.

This disclosure provides novel batteries, e.g., redox flow batteries, and methods of making and operating batteries. Certain embodiments include redox flow battery comprising: a housing; a first electrode disposed in the housing; a second electrode disposed in the housing and facing the first electrode, the first electrode is spaced from the second electrode by a gap without an intervening ion selective membrane; and a fluid conveyance mechanism connected to the housing and configured to convey an electrolyte across the gap between the first electrode and the second electrode.

The present disclosure provides a separator for a zinc secondary battery that can inhibit short circuiting in a zinc secondary battery. The separator for a zinc secondary battery of the disclosure has a porous substrate layer and a titanium oxide-containing porous layer laminated onto the porous substrate layer, wherein the titanium oxide-containing porous layer comprises a titanium oxide represented by Ti.sub.xO.sub.y, where 0<x, 0<y, and y<2x. The titanium oxide may be TiO, Ti.sub.2O, Ti.sub.2O.sub.3, Ti.sub.3O, Ti.sub.3O.sub.5, Ti.sub.4O.sub.5, Ti.sub.4O.sub.7, Ti.sub.5O.sub.9, Ti.sub.6O, Ti.sub.6O.sub.11, T.sub.17O.sub.13, T.sub.18O.sub.15 or T.sub.19O.sub.17.