A secondary zinc-manganese dioxide secondary cell is disclosed. The cell includes a zinc gel anode, high manganese content cathode in either prismatic or jelly roll form. An aqueous based continuous reel to reel process for formulation and fabrication of the anode and cathode is provided. The cell is contained in a box assembly.

An electrical energy storage device and a method of forming such electrical energy storage device. The electrical energy storage device includes an electrolyte that is arranged to dissipate energy when subjected to external mechanical load applied to the electrical energy storage device. The electrolyte includes a polymer matrix of at least two crosslinked structures, including a first polymeric material and a second polymeric material; and an electrolytic solution retained by the polymer matrix.

There is provided a secondary zinc battery including: a unit cell including; a positive-electrode plate including a positive-electrode active material layer and a positive-electrode collector; a negative-electrode plate including a negative-electrode active material layer containing zinc and a negative-electrode collector; a layered double hydroxide (LDH) separator covering or wrapping around the entire negative-electrode active material layer; and an electrolytic solution. The positive-electrode collector has a positive-electrode collector tab extending from one edge of the positive-electrode active material layer, and the negative-electrode collector has a negative-electrode collector tab extending from the opposite edge of the negative-electrode active material layer and beyond a vertical edge of the LDH separator. The unit cell can thereby collects electricity from the positive-electrode collector tab and the negative-electrode collector tab. The LDH separator has at least two continuous closed edges, provided that an edge, adjacent to the negative-electrode collector tab, of the LDH separator is open.

The present invention provides an energy storage device having high discharge capacity and high cycling ability. More particularly, the present invention provides Zn/V.sub.2O.sub.5 battery having cation selective ionomer membrane and free-standing electrode.

Disclosed is an electrode for a rechargeable energy storage device, including several inner layers interposed between two outer layers, the inner layers including several electrode material layers ME composed of at least one electrode active material and several porous current collector layers CC composed of electrically-conductive material(s) whose electronic conductivity is greater than or equal to 102 S.Math.cm-1, the layers of electrode material ME and current collector CC being alternated. The outer layers do not consist of the porous current collector layers CC. Additionally, the electrode has a total thickness ranging from strictly more than 4 mm, preferably ranging from strictly more than 4 mm to 10 mm, in particular ranging from strictly more than 4 mm to 8 mm.

An alkaline electrochemical cell includes a cathode; a gelled anode having an anode active material and an electrolyte; and a separator disposed between the cathode and the anode; wherein the separator includes a non-conductive, porous material having a mean pore size of about 1 micron to about 5 microns, a maximum pore size of about 19 microns, and an air permeability of about 0.5 cc/cm.sup.2/s to about 3.8 cc/cm.sup.2/s at 125 Pa.

A system and a method for an energy harvesting and storage apparatus including a flexible substrate, an energy harvesting device disposed on the flexible substrate, the energy harvesting device is configured to convert mechanical energy into electrical energy, an energy storage device disposed on the flexible substrate and in electrical communication with the energy harvesting device and configured to receive and store the electrical energy from the energy harvesting device.

Provided is a negative electrode for use in a zinc secondary battery, including a negative electrode active material containing ZnO particles and Zn particles, and a nonionic water-absorbing polymer in an amount of 0.01 to 6.0 parts by weight on a solid basis, based on the content of the ZnO particles being 100 parts by weight.

Provided is an air electrode/LDH separator assembly including: a rigid porous layer having rigidity and air permeability, wherein the rigidity is defined as a proportion of displacement in a compression direction of less than 3% when pressurized at 0.1 MPa; an air electrode layer that covers both sides of the rigid porous layer, or both sides and end faces of the rigid porous layer provided that at least one end face is excluded; and a layered double hydroxide (LDH) separator that covers an outside of the air electrode layer; wherein i) the rigid porous layer is made of a metal or an electrically conductive ceramic, whereby the rigid porous layer itself functions as a positive electrode current collector, or ii) the rigid porous layer is made of an insulating material and is covered with a porous metal layer, whereby the porous metal layer functions as a positive electrode current collector.

Various embodiments are directed to an electrochemical cell having a non-homogeneous anode. The electrochemical cell includes a container, a cathode forming a hollow cylinder within the container, an anode positioned within the hollow cylinder of the cathode, and a separator between the cathode and the anode. The anode defines a characteristic gradient between an interior portion of the anode and the outermost surface of the anode adjacent the separator. The characteristic gradient may be defined as, for example, an average active material particle size within the anode that changes as a function of the radial location within the anode or a surfactant concentration gradient that changes as a function of the radial location within the anode.