The invention is a cathode arrangement comprising a cathode housing defining a space for cathode material and comprising a cathode housing wall being permeable to an electrolyte, and a collector member made of carbon, having a first end part extending into the space for cathode material and a second end part extending outside the space for cathode material, and cathode particles, having a cylindric shape with a diameter of 2-5 mm and being extruded from carbon, are arranged in the space for cathode material. The invention is, furthermore, an energy cell comprising the cathode arrangement, an arrangement for processing hydrogen gas comprising the cathode arrangement and use the energy cell applying seawater or salt water as an electrolyte. Furthermore, the invention is a method for manufacturing the cathode arrangement.

The invention is a cathode arrangement comprising a cathode housing defining a space for cathode material and comprising a cathode housing wall being permeable to an electrolyte, and a collector member made of carbon, having a first end part extending into the space for cathode material and a second end part extending outside the space for cathode material, and cathode particles, having a cylindric shape with a diameter of 2-5 mm and being extruded from carbon, are arranged in the space for cathode material. The invention is, furthermore, an energy cell comprising the cathode arrangement, an arrangement for processing hydrogen gas comprising the cathode arrangement and use the energy cell applying seawater or salt water as an electrolyte. Furthermore, the invention is a method for manufacturing the cathode arrangement.

An inventive, new system that measures gas composition and pressure in the headspace of an aqueous electrolyte battery is described. The system includes a microcontroller that can use the composition and pressure information to connect a third electrode to either the anode(s) or the cathode(s) in order to balance the state of charge between the two. Results have shown that such a system can control the gas pressure inside a sealed flooded aqueous electrolyte battery to remain below 20 kPa (3 psi) and greatly extend the useable life of the battery.

An inventive, new system that measures gas composition and pressure in the headspace of an aqueous electrolyte battery is described. The system includes a microcontroller that can use the composition and pressure information to connect a third electrode to either the anode(s) or the cathode(s) in order to balance the state of charge between the two. Results have shown that such a system can control the gas pressure inside a sealed flooded aqueous electrolyte battery to remain below 20 kPa (3 psi) and greatly extend the useable life of the battery.

An all solid battery includes an oxide-based solid electrolyte layer, a positive electrode layer that is provided on a first main face of the oxide-based solid electrolyte layer and includes a positive electrode active material, and a negative electrode layer that is provided on a second main face of the oxide-based solid electrolyte layer and includes a negative electrode active material. At least one of the positive electrode active material of the positive electrode layer and the negative electrode active material of the negative electrode layer includes a first electrode active material and a second electrode active material of which average operation potentials (vs Li/Li.sup.+) are different from each other.

An all solid battery includes an oxide-based solid electrolyte layer, a positive electrode layer that is provided on a first main face of the oxide-based solid electrolyte layer and includes a positive electrode active material, and a negative electrode layer that is provided on a second main face of the oxide-based solid electrolyte layer and includes a negative electrode active material. At least one of the positive electrode active material of the positive electrode layer and the negative electrode active material of the negative electrode layer includes a first electrode active material and a second electrode active material of which average operation potentials (vs Li/Li.sup.+) are different from each other.

An alkaline secondary battery having excellent charge-discharge cycle characteristics is provided. The alkaline secondary battery includes a positive electrode, a negative electrode, and a separator interposed between the positive electrode and the negative electrode. The positive electrode contains a silver oxide. The negative electrode contains zinc-based particles selected from the group consisting of zinc particles and zinc alloy particles. The separator holds an alkaline electrolyte solution. An anion conductive membrane is disposed between the negative electrode and the separator. The anion conductive membrane includes a polymer as a matrix and particles of at least one metal compound selected from the group consisting of metal oxides, metal hydroxides, metal carbonates, metal sulfates, metal phosphates, metal borates, and metal silicates, which are dispersed in the matrix.

This invention provides a rechargeable cell comprising an electrode including: a plurality of porous clusters of silver particles, wherein each cluster includes: (a) a plurality of silver particles, and (b) crystalline particles of zirconium oxide (ZrO.sub.2), wherein at least a portion of the crystalline particles of ZrO.sub.2 is located in pores formed by a surface of the plurality of silver particles. Electrodes of the present invention catalyze the reduction of oxygen in alkaline solution. When the cell is charged, the silver in the electrodes can be oxidized to Ag.sub.2O and further to AgO. Upon discharge, the reduction of the oxidized silver results in additional available energy. This invention provides electrodes for use in rechargeable cells or batteries and methods of making thereof.

This invention provides a rechargeable cell comprising an electrode including: a plurality of porous clusters of silver particles, wherein each cluster includes: (a) a plurality of silver particles, and (b) crystalline particles of zirconium oxide (ZrO.sub.2), wherein at least a portion of the crystalline particles of ZrO.sub.2 is located in pores formed by a surface of the plurality of silver particles. Electrodes of the present invention catalyze the reduction of oxygen in alkaline solution. When the cell is charged, the silver in the electrodes can be oxidized to Ag.sub.2O and further to AgO. Upon discharge, the reduction of the oxidized silver results in additional available energy. This invention provides electrodes for use in rechargeable cells or batteries and methods of making thereof.

Provided is a highly reliable button-shaped alkaline battery having excellent load characteristics. A button-shaped alkaline battery includes: a positive electrode having a positive electrode mixture layer containing a silver oxide and a conductive assistant; a negative electrode containing zinc particles; an alkaline electrolyte solution; and a battery container for accommodating the positive electrode, the negative electrode, and the alkaline electrolyte solution, the battery container including an outer can, a sealing plate, and a resin gasket. The positive electrode mixture layer contains carbon black and graphite particles as the conductive assistant, and an amount of water in the battery container is 0.63 to 1 g per 1 g of the zinc particles of the negative electrode.