The disclosure relates to a complexed iodine-based electrolyte, a redox flow battery comprising the complexed iodine-based electrolyte, and a method for producing the redox flow battery.

The present disclosure is directed to triblock copolymer based anion exchange membranes (AEMs) and methods for making same. The membranes are useful as separators in electrochemical devices, such as fuel cells, electrolyzers, water desalination systems, and redox flow batteries.

The invention discloses a zinc organic battery having a container. The container contains a positive electrode active material, a positive electrode current collector, an organic solvent, a zinc negative electrode, and an aqueous electrolyte. The organic solvent and the aqueous electrolyte are not miscible and are layered due to different densities. The positive electrode active material has a redox activity, and has the two forms of an oxidized state and a reduced state. If the positive electrode active material itself is a liquid and is difficult to be dissolved in the aqueous electrolyte, then the organic solvent may be omitted. The positive electrode active material itself doubles as the organic solvent and is layered with the aqueous electrolyte. The zinc negative electrode is immersed in the aqueous electrolyte and is not in contact with the organic solvent. The aqueous electrolyte is an aqueous solution containing a zinc salt.

A primary electrochemical cell including a cell housing, an anode including metallic lithium, a liquid SOCl.sub.2 cathode and a separator separating the anode from the cathode. The liquid SOCl.sub.2 cathode material includes a salt of a Lewis base with a Lewis acid dissolved in the SOCl.sub.2 to form an electrolyte solution and an amount of SnCl.sub.2 dissolved in the electrolyte solution. The cell has a higher TMV and lower cell impedance after extended periods of cell storage at room or higher temperatures as compared to similar prior art primary Li/SOCl.sub.2 cells that do not include the SnCl.sub.2 additive.

The present disclosure relates to a negative electrode for a non-aqueous electrolyte secondary battery, the negative electrode comprising an active material layer, wherein the active material layer contains graphite particles, fibrous carbon, silicon-containing particles, and a binder, a BET specific surface area of the graphite particles is 3.5 m.sup.2/g or less, the fibrous carbon includes a carbon nanotube, each of the silicon-containing particles includes a domain composed of carbon and a domain composed of silicon and having a size of 50 nm or less, and an oxygen content ratio in each of the silicon-containing particles is 7 wt % or less. According to the present disclosure, a negative electrode and a non-aqueous electrolyte secondary battery are provided to suppress decrease in initial capacity and cycling performance.

Systems and methods for managing flow batteries utilize a battery management controller (BMC) coupled between a flow battery and a DC/DC converter, which is coupled to an electrical grid or a photovoltaic device via an inverter. The inverter converts an AC voltage to a first DC voltage and the DC/DC converter steps down the first DC voltage to a second DC voltage. The BMC includes a first power route, a second power route, and a current source converter coupled to the second power route. The BMC initializes the flow battery with a third DC voltage using the current source converter until a sensing circuit senses that the voltage of the flow battery has reached a predetermined voltage. The sensing circuit may include a capacitor, which has a small capacitance and is coupled across each cell of the flow battery, coupled in series between two resistors having very large resistances.

Methods and systems are provided for a redox flow battery system. In one example, the redox flow battery is adapted with an additive included in a battery electrolyte and an anion exchange membrane separator dividing positive electrolyte from negative electrolyte. An overall system cost of the battery system may be reduced while a storage capacity, energy density and performance may be increased.

Flow batteries can include a first half-cell containing a first aqueous electrolyte solution. a second half-cell containing a second aqueous electrolyte solution, and a separator disposed between the first half-cell and the second half-cell. The first aqueous electrolyte solution contains a first redox-active material, and the second aqueous electrolyte solution contains a second redox-active material. At least one of the first redox-active material and the second redox-active material is a nitroxide compound or a salt thereof. Particular nitroxide compounds can include a doubly bonded oxygen contained in a ring bearing the nitroxide group, a doubly bonded oxygen appended to a ring bearing the nitroxide group, sulfate or phosphate groups appended to a ring bearing the nitroxide group, various heterocyclic rings bearing the nitroxide group, or acyclic nitroxide compounds.

A novel wound electrode assembly for a lithium oxyhalide electrochemical cell is described. The electrode assembly comprises an elongate cathode of an electrochemically non-active but electrically conductive carbonaceous material disposed between an inner elongate portion and an outer elongate portion of a unitary lithium anode. That way, lithium faces the entire length of the opposed major sides of the cathode. This inner anode portion/cathode/outer anode portion configuration is rolled into a wound-shaped electrode assembly that is housed inside a cylindrically-shaped casing. A cylindrically-shaped sheet-type spring centered in the electrode assembly presses outwardly to limit axial movement of the electrode assembly. In one embodiment, all the non-active components, except for the cathode current collector, which is nickel, are made of stainless-steel. This provides the cell with a low magnetic signature without adversely affecting the cell's high-rate capability.

The present invention relates to novel combinations of redox active compounds for use as redox flow battery electrolytes. The invention further provides kits comprising these combinations, redox flow batteries, and method using the combinations, kits and redox flow batteries of the invention.