Core-shell particles may be based on red lead coated with pyrogenically produced titanium dioxide and/or a pyrogenically produced aluminum oxide, and a process may prepare such core-shell particles which may be used in lead-acid batteries. The red lead may include PbO.sub.2 in a range of from 25 to 32 wt. %.

A lead-acid battery is disclosed. The lead-acid storage battery has a container with a cover, the container including one or more compartments. One or more cell elements are provided in the one or more compartments. The one or more cell elements include a positive plate, the positive plate having a positive grid and a positive electrochemically active material on the positive grid; a negative plate, the negative plate having a negative grid and a negative electrochemically active material on the negative grid, wherein the negative electrochemically active material comprises barium sulfate and an organic expander; and a separator between the positive plate and the negative plate. Electrolyte is provided within the container. One or more terminal posts extend from the cover and are electrically coupled to the one or more cell elements.

A lead-acid battery is disclosed. The lead-acid battery has a container with a cover and includes one or more compartments. One or more cell elements are provided in the one or more compartments. The one or more cell elements comprise a positive electrode, the positive electrode having a positive substrate and a positive electrochemically active material on the positive substrate; a negative electrode, the negative electrode having a negative substrate and a negative active mass on the negative substrate, wherein the negative active mass comprises a leady oxide, a synthetic organic expander, a very fine particle barium sulfate, and plurality of conductive carbons; and an absorbent glass mat separator between the positive plate and the negative plate. Electrolyte is provided within the container. A negative electrode for a lead-acid battery and a battery having improved performance are also disclosed.

To provide a convenient and effective method for suppressing the penetration of dendrite over the microporous film mainly containing the base portion, which occupies the most part of the entire separator (total area), rather than the peculiar concept (resulting in a difficult measure), in which only the pore structure of the rib portion is densified or contracted for suppressing dendrite from penetrating through the rib portion. A separator for a lead-acid battery, containing a microporous film obtained in such a manner that a raw material composition mainly containing a polyolefin resin, silica powder, and a plasticizer is melt-kneaded and formed into a film, from which the plasticizer is entirely or partially removed, the raw material composition containing glass flakes having an average particle diameter of from 20 to 800 m and an average thickness of 0.2 to 8 m and having no self-film formability in an amount of from 2 to 15% by weight based on a total amount of the silica powder and the glass flakes, the glass flakes in the microporous film being disposed in such a manner that a plane direction thereof is substantially oriented in a plane direction of the microporous film, a value of (the content of the glass flakes in the microporous film)/(the average thickness of the glass flakes in the microporous film) being 1 or more.

To increase the conductivity and electric capacity of an electrode which includes active material particles and the like and is used in a battery, a graphene net including 1 to 100 graphene sheets is used instead of a conventionally used conduction auxiliary agent and binder. The graphene net which has a two-dimensional expansion and a three-dimensional structure is more likely to touch active material particles or another conduction auxiliary agent, thereby increasing the conductivity and the bonding strength between active material particles. This graphene net is obtained by mixing graphene oxide and active material particles and then heating the mixture in a vacuum or a reducing atmosphere.

Lead-acid batteries with low water consumption and hydrogen gassing, comprise electrodes of a carbon fibre material having a surface area of less than 50 m.sup.2/g. The carbon fibre material may also comprise non-carbon functional groups less than 22% by mass in the bulk fibre, and at least 78% carbon by mass in the bulk fibre. The carbon fibre material may be heated to a temperature of at least 1000 C. and cooled in an inert atmosphere to prevent non-carbon functional groups reforming on the carbonised carbon fibre material. The batteries are suitable for use in hybrid vehicles.

An Advanced Graphite, with a lower degree of ordered carbon domains and a surface area greater than ten times that of typical battery grade graphites, is used in negative active material (NAM) of valve-regulated lead-acid (VRLA) type Spiral wound 6V/25 Ah lead-acid batteries. A significant and unexpected cycle life was achieved for the Advanced Graphite mix, where the battery was able to cycle beyond 145,000 cycles above the failure voltage of 9V, in a non-stop, power-assist, cycle-life test. Batteries with Advanced Graphite also showed increased charge acceptance power and discharge power compared to control groups.

The present invention deals with employing Heteroatoms namely Nitrogen, Sulphur intrinsic embedded carbon nanotubes (H-CNT) as multifunctional additive for preparing lead acid battery electrodes to substitute the expander chemicals namely, Vanisperse, Dinel Fibre, Barium sulphate and carbon black. Further the invention provides H-CNT in-situ produced from Crude oil or its products.

The present disclosure relates to surface-modified carbon hybrid particles in agglomerated form, methods for making such surface-modified carbon hybrid particles and their use, for example as conductive additives. The surface-modified carbon hybrid particles are characterized by a high surface area and a high mesopore content. The disclosure also pertains to methods for making dispersions of such compounds in a liquid medium in the presence of a surfactant and their use as conductive coatings. Polymer compounds filled with the surface-modified carbon hybrid particles are also disclosed. A further disclosure relates to the use of surface-modified carbon hybrid particles as carbon supports.

Carbon materials having low gassing properties and electrodes and electrical energy storage devices, especially lead-acid batteries, comprising the same are provided.