Disclosed are an anodeless all-solid-state battery including a protective layer formed on an anode current collector and a method for manufacturing the same. The anodeless all-solid-state battery may be capable of inhibiting the growth of lithium dendrites formed therein.

Articles and methods related to electrochemical cells and/or electrochemical cell components (such as electrodes) comprising species comprising a conjugated, negatively-charged ring comprising a nitrogen atom and/or reaction products of such species are generally provided. The electrochemical cell may comprise an electrode (e.g., a cathode) comprising a protective layer comprising a species comprising a conjugated, negatively-charged ring comprising a nitrogen atom and/or a reaction product thereof.

Manufacturing a lithium-ion battery includes assembling the lithium-ion battery; and performing an initial charging on the lithium-ion battery. The lithium-ion battery includes a positive electrode, a negative electrode, and an electrolyte; the negative electrode contains a negative electrode active material containing a precursor of a silicon material, the precursor having a composition represented by SiO.sub.x where a relationship of 0<x<2 is satisfied. The initial charging includes a first step where the charging is performed to an intermediate voltage at a first current rate, and a second step where the charging is performed from the intermediate voltage to a maximum voltage at a second current rate. The first current rate is lower than 0.5 C; the second current rate is higher than the first current rate; and the intermediate voltage is 3.75 V or higher.

The present invention relates to a positive electrode plate and an electrochemical device. The positive electrode plate comprises a current collector, a positive active material layer and a safety coating disposed between the current collector and the positive active material layer, and wherein the safety coating comprises a polymer matrix, a conductive material and an inorganic filler and wherein when the safety coating and the positive active material layer are collectively referred as a film layer, the film layer has an elongation of 30% or more and wherein the polymer matrix of the safety coating is fluorinated polyolefin and/or chlorinated polyolefin having a crosslinked structure. The positive electrode plate may improve the safety performance during nail penetration of the electrochemical device such as capacitor, primary battery or secondary battery and the like.

An anode for a magnesium battery, including a core element made from a core material, wherein a magnesium coating is at least partially arranged on a surface of the core element, a protective layer being arranged on a surface of the magnesium coating. A method for producing such an anode and a magnesium battery having at least one such anode are also provided.

Articles and methods including composite layers for protection of electrodes in electrochemical cells are provided. In some embodiments, the composite layers comprise a polymeric material and a plurality of particles.

Provided are an electrode plate and a lithium-ion battery, the electrode plate includes a current collector layer, a semiconductor layer and an alkali metal replenishing layer. The semiconductor layer is disposed on at least one surface of the current collector layer. The alkali metal replenishing layer is a lithium-replenishing agent layer or a sodium-replenishing agent layer. The alkali metal replenishing layer is arranged on a side of the semiconductor layer far away from the current collector layer.

Embodiments of the present application provide a lithium metal negative electrode, a preparation method therefor and related lithium metal battery and device. The lithium metal negative electrode may comprise: a negative electrode current collector; at least one lithium-based metal layer provided on at least one surface of the negative electrode current collector; and an ion-conducting polymer modification layer, which is located on the surface of one of the at least one lithium-based metal layer and comprises at least catalytic amount of a Lewis acid, the Lewis acid containing cations of a metal capable of forming an alloy-type active material with lithium.

A cathode slurry for a lithium secondary battery according to exemplary embodiments may include a cathode active material including lithium metal oxide particles, a binder, a dispersion medium, and at least one of a multivalent carboxylic acid compound and a salt of the multivalent carboxylic acid compound. A total amount of the multivalent carboxylic acid compound and the salt of the multivalent carboxylic acid compound in the cathode slurry may be 0.01 to 0.05 wt. parts based on 100 wt. parts of the lithium metal oxide particles.

There is provided a method for producing an anode for lithium batteries. The method comprises: providing a current collector, forming a layer of protective material thereon, depositing a lithiophilic material on the layer of protective material, and depositing a molten lithium material on the layer of lithiophilic material. The lithiophilic material and the molten lithium material subsequently react to form the anode active material. The current collector and/or at least one other layer of the anode may comprise a continuous 3D structure on a surface thereof. The protective material deposited on the current collector constitutes a barrier between the current collector and lithium in the anode active material, therefore formation of cracks in the current collector is avoided.