A secondary battery with excellent cycle performance is provided. The secondary battery is an all-solid-state battery including a positive electrode current collector layer, a base film, a positive electrode active material layer, a buffer layer, and a solid electrolyte layer. The base film contains titanium nitride. The positive electrode active material layer contains lithium cobalt oxide. The buffer layer contains titanium oxide. The solid electrolyte layer contains a titanium compound. By using titanium oxide for the buffer layer, a side reaction between the positive electrode active material layer and the solid electrolyte layer can be suppressed, and cycle performance can be improved.

A first electrode current collector is joined to a multilayer of a positive electrode core in a part including no positive electrode active material layer of the first electrode core, by ultrasonic welding in a joint area. The joint area, at which the multilayers of the first electrode core where the first electrode cores are stacked is joined to the first electrode current collector by ultrasonic welding, includes a plurality of core recesses. A core projection is formed between each adjacent pair of the plurality of core recesses of the multilayer of the first electrode core with the first electrode core flexed in a convex shape. A gap in an arc shape is formed between the adjacent pair of the layers of the first electrode core forming the core projection. The gap has a length decreasing from an apex to a bottom of the core projection.

A negative electrode for lithium secondary batteries and a method of manufacturing the same are provided. The negative electrode includes a negative electrode current collector and a lithiophilic material formed on at least one surface of the negative electrode current collector, wherein the lithiophilic material is an oxidized product of a coating material coated on the negative electrode current collector and includes at least one of a metal or a metal oxide, and an oxide layer is formed on a surface of the negative electrode current collector having the lithiophilic material formed thereon.

A negative electrode for lithium secondary batteries and a method of manufacturing the same are provided. The negative electrode includes a negative electrode current collector and a lithiophilic material formed on at least one surface of the negative electrode current collector, wherein the lithiophilic material is an oxidized product of a coating material coated on the negative electrode current collector and includes at least one of a metal or a metal oxide, and an oxide layer is formed on a surface of the negative electrode current collector having the lithiophilic material formed thereon.

A negative electrode for lithium secondary batteries is provided. The negative electrode comprises a negative electrode current collector including a porous structure having an inner pore or a through-hole formed therethrough from an upper surface to a lower surface thereof, wherein a lithiophilic material is applied to a surface of the porous structure or the through-hole excluding a first surface of the negative electrode current collector that faces a positive electrode.

A negative electrode for lithium secondary batteries is provided. The negative electrode comprises a negative electrode current collector including a porous structure having an inner pore or a through-hole formed therethrough from an upper surface to a lower surface thereof, wherein a lithiophilic material is applied to a surface of the porous structure or the through-hole excluding a first surface of the negative electrode current collector that faces a positive electrode.

An electrochemical device includes a negative electrode plate including a negative current collector provided with a negative active material layer and a positive electrode plate including a positive current collector provided with a positive active material layer. The positive active material layer includes a first region. The first region includes a second region and a third region that does not overlap the second region by any area. A first insulation layer is disposed on a surface of the second region. The negative active material layer includes a fourth region facing towards the third region. An area S2 mm.sup.2 of the second region and an area S1 mm.sup.2 of the first region satisfy: S2<S1≤1.5S2, and a ratio CB of a unit-area capacity of the fourth region to a unit-area capacity of the third region is greater than or equal to 1.1.

The present disclosure provides a porous electrode for a flow-through rechargeable electrochemical cell including a high-porosity metal current collector, an active material surrounding the metal current collector, and a self-supporting synthetic membrane material surrounding the active material. The present disclosure further includes a flow-through rechargeable battery including multiple electrochemical cells, a closed loop, and a pump.

According to the present disclosure, it is possible to inhibit the electrically conductive foreign substance from falling off and being peeled off from the electrode plate that has been already manufactured, so as to contribute in improving the safety property of the secondary battery. The manufacturing method of the electrode plate herein disclosed includes a precursor preparing step for preparing an electrode precursor 20A including an active material provided area A1 in which an electrode active material layer 24 is provided on a surface of the electrode core 22 and including a core exposed area A2 in which the electrode active material layer 24 is not provided and the electrode core 22 is exposed, and an active material provided area cutting step for cutting the active material provided area A1 by a pulse laser, and a core exposed area cutting step for cutting the core exposed area A2 by the pulse laser. Then, in the case where the pulse width (ns) of the pulse laser is represented by X and the lap rate (%) is represented by Y for the core exposed area cutting step, a condition represented by Y≥−3log X+106 is satisfied. According to the manufacturing method of the electrode plate as described above, it is possible to inhibit the electrically conductive foreign substance from falling off and being peeled off from the electrode plate that has been already manufactured, and thus it is possible to contribute in improving the safety property of the secondary battery.

A lithium-sulfur battery includes a casing having a length and a width, the casing including at least an anode and a cathode wound into a jelly roll oriented parallel to the length of the casing, an electrolyte disposed in the lithium-sulfur battery, a negative terminal extending along the length of the casing, and a positive terminal extending along the length of the casing, the positive terminal and the negative terminal parallel to one another.