A system including biogas purification and provides biogas as feedstock to a solid oxide fuel cell. The biogas purification treatment process provides a polished biogas that is substantially free of carbonyl sulfides and hydrogen sulfide. The system uses a biogas treatment apparatus, that includes apparatus such as a packed columns, comprising copper oxide or potassium permanganate packing material, and an activated carbon component configured to treat the biogas by polishing it to remove carbonyl sulfides and deleterious trace residues, such as hydrogen sulfide, that were not removed by any prior bulk H2S removal steps. In addition, an oil removal device is used to remove any entrained fine oil droplets in the biogas. A polished biogas having in the range of 60% methane is charged to the fuel cell. Electricity generated may be fed into a grid or used directly as energy to charge electrical-powered vehicles, for example. Energy credits are tracked in real time and are appropriately assigned.

A sorbent bed assembly of a fuel cell system, including a first sorbent bed, a second sorbent bed and at least one third sorbent bed, the second sorbent bed disposed between the first sorbent bed and the at least one third sorbent bed, a cover plate on the plurality of sorbent beds and configured to connect the sorbent beds to one another, a fuel inlet connector on the cover plate and configured to receive a fuel, a manifold having a first fluid conduit configured to transport fuel between the first sorbent bed and at least one third sorbent bed, and a second fluid conduit configured to transport fuel between at least one third sorbent bed and the second sorbent bed, and a fuel outlet connector on the cover plate and configured to receive fuel that has passed through each of the sorbent beds.

A power producing system adapted to be integrated with a flue gas generating assembly, the flue gas generating assembly including one or more of a fossil fueled installation, a fossil fueled facility, a fossil fueled device, a fossil fueled power plant, a boiler, a combustor, a furnace and a kiln in a cement factory, and the power producing system utilizing flue gas containing carbon dioxide and oxygen output by the flue gas generating assembly and comprising: a fuel cell comprising an anode section and a cathode section, wherein inlet oxidant gas to the cathode section of the fuel cell contains the flue gas output from the flue gas generating assembly; and a gas separation assembly receiving anode exhaust output from the anode section of the fuel cell and including a chiller assembly for cooling the anode exhaust to a predetermined temperature so as to liquefy carbon dioxide in the anode exhaust, wherein waste heat produced by the fuel cell is utilized to drive the chiller assembly.

A SOFC system for producing a refined carbon dioxide product, electrical power, and a compressed hydrogen product is presented. The system can include a hydrodesulfurization system, a steam reformer, a water-gas shift reactor system, a hydrogen purification system, a hydrogen compression and storage system, a pre-reformer, and a CO2 purification and liquidification system.

A fuel cell system including a hydrocarbon fuel stream including a sulfur compound; a passive sorbent bed including a selective sulfur sorbent configured to remove the sulfur compound from the hydrocarbon fuel stream; a SCSO reactor, and an active sorbent bed comprising a sulfur oxide sorbent, wherein the active sorbet bed is configured to receive an effluent stream from the SCSO reactor and remove at least a portion of the sulfur oxides via the sulfur oxide sorbent. During start-up of the fuel cell system, the hydrocarbon fuel stream may be directed along a first flow pathway through the passive sorbent bed to remove the sulfur compound from the fuel stream during a first time period and then directed along a second flow pathway during a second time period that does not pass through the passive sorbent bed, e.g., once the SCSO reactor/active sorbent bed have reached operating temperature.

A fuel cell system includes: a fuel cell; a reformer to generate a hydrogen-containing gas; an electric power generation raw material supply unit; a reforming material supply unit configured to supply at least one of reforming water and reforming air, to the reformer; an oxidizing gas supply unit to supply an oxidizing gas to a cathode of the fuel cell; a combustor to ignite an exhaust gas discharged from the fuel cell; and a controller. In an operation stop process of the fuel cell system, the controller causes the oxidizing gas supply unit to supply the oxidizing gas, causes the electric power generation raw material supply unit and the reforming material supply unit to intermittently supply the electric power generation raw material and at least one of the water and the air to the reformer, and causes the ignitor to perform an ignition operation.

The present invention concerns a process for removing carbon monoxide and/or gaseous sulphur compounds from hydrogen gas and/or aliphatic hydrocarbons, preferably at low temperatures, with the aid of complex metal aluminium hydrides.

This invention relates to a method for preparing a bimetallic titania-based catalyst for use in hydrodesulfurization reactions.

Problem to be Solved

A catalyst for obtaining hydrogen gas by steam reforming of a hydrocarbon-containing gas in the presence of steam active metals supported on an α-alumina carrier.

The active metals include 0.1 to 0.3 parts by weight of rhodium (Rh) based on the content of the metal, relative to 100 parts by weight of the α-alumina carrier, and 0.01 to 0.3 parts by weight of platinum (Pt) based on the content of the metal, relative to 100 parts by weight of the α-alumina carrier.

The α-alumina carrier is a carrier modified with a promoter including 1 to 10 parts by weight of cerium (Ce) based on the content of the metal, relative to 100 parts by weight of the α-alumina carrier.

A system including biogas purification and provides biogas as feedstock to a solid oxide fuel cell. The biogas purification treatment process provides a polished biogas that is substantially free of carbonyl sulfides and hydrogen sulfide. The system uses a biogas treatment apparatus, that includes apparatus such as a packed columns, comprising copper oxide or potassium permanganate packing material, and an activated carbon component configured to treat the biogas by polishing it to remove carbonyl sulfides and deleterious trace residues, such as hydrogen sulfide, that were not removed by any prior bulk H2S removal steps. In addition, an oil removal device is used to remove any entrained fine oil droplets in the biogas. A polished biogas having in the range of 60% methane is charged to the fuel cell. Electricity generated may be fed into a grid or used directly as energy to charge electrical-powered vehicles, for example. Energy credits are tracked in real time and are appropriately assigned.