The present disclosure provides an electrolyte solution of a lead-crystal storage battery, a preparation method thereof, and a lead-crystal storage battery. The electrolyte solution comprises silica sol and precipitated silica in a mass ratio of 1:(0.005 to 0.05); a total content of silica in the electrolyte solution is from 1% to 4% as per a net content of the silica; the electrolyte solution further comprises 0.1% to 2% of lithium hydroxide based on a total amount of the electrolyte solution. Upon the completion of a formation step of the battery, the electrolyte solution changes from a flow dynamic state to a solidified electrolyte solution containing crystal particles. By using specific gelling agents in combination and adding a relatively large amount of lithium hydroxide in the electrolyte solution to facilitate the electrolyte solution becoming a solidified electrolyte solution containing crystal particles after a charge-discharge cycle, the present disclosure can have active materials of the electrode plates fixed firmly, and enhance the deep cycle capacity of the battery; a porous structure further provides enough space for ion motion to extend battery service life and improve low temperature performance and charge retention.

The present invention provides a porous body which contains sheath-core type binder fibers and a resin binder, and which is characterized in that: the resin binder (the solid content) is contained in an amount of more than 5.0 parts by mass but less than 50 parts by mass relative to 100 parts by mass of the porous body; and if P (N) is the penetration strength of the porous body and B (g/m.sup.2) is the weight per square meter of the porous body, P and B satisfy P/B>0.070.

A battery separator has performance enhancing additives or coatings, fillers with increased friability, increased ionic diffusion, decreased tortuosity, increased wettability, reduced oil content, reduced thickness, decreased electrical resistance, and/or increased porosity. The separator in a battery reduces the water loss, lowers acid stratification, lowers the voltage drop, and/or increases the CCA. The separators include or exhibit performance enhancing additives or coatings, increased porosity, increased void volume, amorphous silica, higher oil absorption silica, higher silanol group silica, reduced electrical resistance, a shish-kebab structure or morphology, a polyolefin microporous membrane containing particle-like filler in an amount of 40% or more by weight of the membrane and ultrahigh molecular weight polyethylene having shish-kebab formations and the average repetition periodicity of the kebab formation from 1 nm to 150 nm, decreased sheet thickness, decreased tortuosity, separators especially well-suited for enhanced flooded batteries.

Disclosed herein are exemplary embodiments of improved separators for lead acid batteries, improved lead acid batteries incorporating the improved separators, and systems incorporating the same. A lead acid battery separator is provided with a porous membrane with a plurality of ribs extending from a surface thereon. The ribs are provided with a plurality of discontinuous peaks arranged such as to provide resilient support for the porous membrane in order to resist forces exerted by swelling NAM and thus mitigate the effects of acid starvation associated with NAM swelling. The separator is also provided to be capable utilizing any motion experienced by the battery housing such a separator in order to mitigate the effects of acid stratification by facilitating acid mixing. A lead acid battery is further provided that incorporates the provided separator. Such a lead acid battery may be a flooded lead acid battery, an enhanced flooded lead acid battery, and may be provided as operating in a partial state of charge. Systems incorporating such a lead acid battery are also provided, such as a vehicle or any other energy storage system, such as solar or wind energy collection. Other exemplary embodiments are provided such as to have any one or more of the following: a lowered electrical resistance; increased puncture resistance; increased oxidation resistance; increased ability to mitigate the effects of dendrite growth, and/or other improvements.

Disclosed herein are exemplary embodiments of improved separators for lead acid batteries, improved lead acid batteries incorporating the improved separators, and systems incorporating the same. A lead acid battery separator is provided with a porous membrane with a plurality of ribs extending from a surface thereon. The ribs are provided with a plurality of discontinuous peaks arranged such as to provide resilient support for the porous membrane in order to resist forces exerted by swelling NAM and thus mitigate the effects of acid starvation associated with NAM swelling. The separator is also provided to be capable utilizing any motion experienced by the battery housing such a separator in order to mitigate the effects of acid stratification by facilitating acid mixing. A lead acid battery is further provided that incorporates the provided separator. Such a lead acid battery may be a flooded lead acid battery, an enhanced flooded lead acid battery, and may be provided as operating in a partial state of charge. Systems incorporating such a lead acid battery are also provided, such as a vehicle or any other energy storage system, such as solar or wind energy collection. Other exemplary embodiments are provided such as to have any one or more of the following: a lowered electrical resistance; increased puncture resistance; increased oxidation resistance; increased ability to mitigate the effects of dendrite growth, and/or other improvements.

A battery separator has performance enhancing additives or coatings, fillers with increased friability, increased ionic diffusion, decreased tortuosity, increased wettability, reduced oil content, reduced thickness, decreased electrical resistance, and/or increased porosity. The separator in a battery reduces the water loss, lowers acid stratification, lowers the voltage drop, and/or increases the CCA. The separators include or exhibit performance enhancing additives or coatings, increased porosity, increased void volume, amorphous silica, higher oil absorption silica, higher silanol group silica, reduced electrical resistance, a shish-kebab structure or morphology, a polyolefin microporous membrane containing particle-like filler in an amount of 40% or more by weight of the membrane and ultrahigh molecular weight polyethylene having shish-kebab formations and the average repetition periodicity of the kebab formation from 1 nm to 150 nm, decreased sheet thickness, decreased tortuosity, separators especially well-suited for enhanced flooded batteries.

A mandrel that can uniformly form a thickness of an electrode assembly and minimize deformation of an electrode plate upon swelling. The mandrel that is configured to wind an electrode of a rechargeable battery includes: a first reel and a second reel with a gap therebetween, wherein the first reel includes a gap surface facing the second reel, a first front surface and a second front surface that are connected by the gap surface, and a first inclined surface and a second inclined surface that connect the first front surface and the second front surface, wherein the first inclined surface is longer than the second inclined surface.

Disclosed is a lead acid battery having a negative electrode plate and a positive electrode plate, each plate formed of a lead-antimony grid coated with an active material. A separator is disposed between the first and second electrode plate faces and an electrolyte solution immersing the negative electrode plate, the positive electrode plate the separator. At least one of the lead-antimony electrode grids, the separator or the electrolyte solution contains TiO.sub.2, an amount sufficient to suppress the migration of antimony from the positive electrode plate to the negative electrode plate.

Disclosed is a lead acid battery having a negative electrode plate and a positive electrode plate, each plate formed of a lead-antimony grid coated with an active material. A separator is disposed between the first and second electrode plate faces and an electrolyte solution immersing the negative electrode plate, the positive electrode plate the separator. At least one of the lead-antimony electrode grids, the separator or the electrolyte solution contains TiO.sub.2, an amount sufficient to suppress the migration of antimony from the positive electrode plate to the negative electrode plate.

A bipolar lead acid battery with increased energy density is provided. The battery includes a number of lead acid wafer cell that each comprise a negative electrode having a negative electrode plate and a negative active material positioned on the negative electrode plate, as well as a positive electrode having a positive electrode plate and a positive active material positioned on the positive electrode plate. The positive electrode plate comprises a metal foil with a conductive film thereon, such as a titanium foil or substrate with a titanium silicide coating thereon. The lead acid wafer cell also includes a separator between the negative and positive electrodes, wherein the separator includes an electrolyte for transferring charge between the negative and positive electrodes.