H01M50/491

Printable ionic gel separation layer for energy storage devices

Representative embodiments provide a liquid or gel separator utilized to separate and space apart first and second conductors or electrodes of an energy storage device, such as a battery or a supercapacitor. A representative liquid or gel separator comprises a plurality of particles, typically having a size (in any dimension) between about 0.5 to about 50 microns; a first, ionic liquid electrolyte; and a polymer. In another representative embodiment, the plurality of particles comprise diatoms, diatomaceous frustules, and/or diatomaceous fragments or remains. Another representative embodiment further comprises a second electrolyte different from the first electrolyte; the plurality of particles are comprised of silicate glass; the first and second electrolytes comprise zinc tetrafluoroborate salt in 1-ethyl-3-methylimidalzolium tetrafluoroborate ionic liquid; and the polymer comprises polyvinyl alcohol (“PVA”) or polyvinylidene fluoride (“PVFD”). Additional components, such as additional electrolytes and solvents, may also be included.

SEPARATOR FOR NON-AQUEOUS SECONDARY BATTERY AND NON-AQUEOUS SECONDARY BATTERY
20230216143 · 2023-07-06 · ·

A separator for a non-aqueous secondary battery contains: a porous substrate and a heat-resistant porous layer that is provided on one side or on both sides of the porous substrate, and that contains a resin and inorganic particles, in which (A) the resin contains a copolymer having a vinylidene fluoride unit and a hexafluoropropylene unit satisfying particular requirements, a content of the inorganic particles in the heat-resistant porous layer is from 50% by mass to 90% by mass, and the inorganic particles contain first inorganic particles and second inorganic particles satisfying particular size requirements, or (B) a content of the inorganic particles in the heat-resistant porous layer is from 50% by mass to 90% by mass, and the inorganic particles contain first inorganic particles that are metal sulfate (or metal hydroxide) particles and second inorganic particles that are inorganic particles other than metal sulfate (or metal hydroxide) particles.

SEPARATOR FOR NON-AQUEOUS SECONDARY BATTERY AND NON-AQUEOUS SECONDARY BATTERY
20230216143 · 2023-07-06 · ·

A separator for a non-aqueous secondary battery contains: a porous substrate and a heat-resistant porous layer that is provided on one side or on both sides of the porous substrate, and that contains a resin and inorganic particles, in which (A) the resin contains a copolymer having a vinylidene fluoride unit and a hexafluoropropylene unit satisfying particular requirements, a content of the inorganic particles in the heat-resistant porous layer is from 50% by mass to 90% by mass, and the inorganic particles contain first inorganic particles and second inorganic particles satisfying particular size requirements, or (B) a content of the inorganic particles in the heat-resistant porous layer is from 50% by mass to 90% by mass, and the inorganic particles contain first inorganic particles that are metal sulfate (or metal hydroxide) particles and second inorganic particles that are inorganic particles other than metal sulfate (or metal hydroxide) particles.

ANODE PIECE FOR LITHIUM BATTERY HAVING BOTH HIGH SAFETY AND HIGH CAPACITY, AND PREPARATION METHOD AND USE THEREFOR

An anode piece for a lithium battery having both high safety and high capacity, and a preparation method and a use therefor, the anode piece being mixed with a lithium-rich compound, the lithium-rich compound being at least one selected from lithium-rich manganese-based solid solution, a lithium-rich solid electrolyte or a lithium-separated silicon oxide. Li ions can be pulled away from the lithium-rich compound in extreme conditions such as overcharging, internal short circuiting, external short circuiting, thermal abuse, piercing, compressing or overheating, thereby filling in lithium vacancies in the anode material, stabilizing the crystal lattice structure of the anode material, improving safety performance in a battery manufactured by using the material, and allowing the anode piece to maintain excellent cycle performance at higher area capacities.

NON-WOVEN FABRIC AND PREPARATION METHOD THEREFOR, LITHIUM BATTERY DIAPHRAGM, AND LITHIUM BATTERY DIAPHRAGM BASE MEMBRANE
20230216142 · 2023-07-06 ·

---A non-woven fabric and a preparation method therefore, a lithium battery diaphragm and a lithium battery diaphragm base membrane, relating to the field of materials. Raw materials of the non-woven fabric include main fibers and bonding fibers, wherein the bonding fibers include first bonding fibers and second bonding fibers; the melting point or softening point of the first bonding fibers is 120-220° C., and the melting point or softening point of the second bonding fibers is 100-170° C., the melting point or softening point of the second bonding fibers is at least 15° C. lower than that of the first bonding fibers; and the melting point or softening point of the main fibers is at least 20° C. higher than that of the first bonding fibers.---

NON-WOVEN FABRIC AND PREPARATION METHOD THEREFOR, LITHIUM BATTERY DIAPHRAGM, AND LITHIUM BATTERY DIAPHRAGM BASE MEMBRANE
20230216142 · 2023-07-06 ·

---A non-woven fabric and a preparation method therefore, a lithium battery diaphragm and a lithium battery diaphragm base membrane, relating to the field of materials. Raw materials of the non-woven fabric include main fibers and bonding fibers, wherein the bonding fibers include first bonding fibers and second bonding fibers; the melting point or softening point of the first bonding fibers is 120-220° C., and the melting point or softening point of the second bonding fibers is 100-170° C., the melting point or softening point of the second bonding fibers is at least 15° C. lower than that of the first bonding fibers; and the melting point or softening point of the main fibers is at least 20° C. higher than that of the first bonding fibers.---

LITHIUM-ION BATTERY SEPARATOR, PREPARATION METHOD THEREOF, AND LITHIUM-ION BATTERY PREPARED THEREFROM

A lithium-ion battery separator with high-temperature resistance, a preparation method thereof and a lithium-ion battery prepared therefrom fall within the field of lithium-ion battery separators. The separator has a thickness of 3.5-30 μm, a porosity of 30-80%, an adjustable pore size of 20-2000 nm, a biaxial tensile strength of ≥50 MPa, an air permeability of ≤400 s/100 cc, and a breaking temperature of ≥160° C. The preparation method comprises the following steps: mixing, melting, and plasticizing 20%-60% of a polypropylene main material, 2%-10% of a solubilizer, 30%-80% of a solvent. 0.1%-5% of a nucleating aid and/or 0.1%-1% of an antioxidant, carrying out twin-screw extrusion, carrying out thermally induced phase separation to obtain a cast sheet, and carrying out cast sheet stretching, extraction, and post-treatment or directly carrying out extraction and post-treatment. The separator has the characteristics of high-temperature resistance, biaxial high strength, uniform pore size, high specific resistance.

SEPARATOR AND METHOD FOR PRODUCING THE SAME

Provided are a separator and a method for producing the same, and more particularly, a separator which may secure battery stability and has characteristics of significantly low heat shrinkage even at a high temperature and minimally increased resistance, and a method for producing the same. The separator according to the present disclosure includes: a porous substrate; and an inorganic particle layer positioned on one or both surfaces of the porous substrate, wherein the inorganic particle layer includes inorganic particles and a sheet-shaped inorganic binder.

SEPARATOR AND METHOD FOR PRODUCING THE SAME

Provided are a separator and a method for producing the same, and more particularly, a separator which may secure battery stability and has characteristics of significantly low heat shrinkage even at a high temperature and minimally increased resistance, and a method for producing the same. The separator according to the present disclosure includes: a porous substrate; and an inorganic particle layer positioned on one or both surfaces of the porous substrate, wherein the inorganic particle layer includes inorganic particles and a sheet-shaped inorganic binder.

SEPARATOR FOR A SECONDARY BATTERY AND METHOD FOR PRODUCING THE SAME

Provided are a separator and a method for producing the same, and more particularly, a separator which may secure battery stability and has characteristics of significantly low heat shrinkage even at a high temperature and minimally increased resistance, and a method for producing the same.

The separator according to the present disclosure includes: a porous substrate; and an inorganic particle layer positioned on one or both surfaces of the porous substrate, wherein the inorganic particle layer includes inorganic particles and a rod-shaped inorganic binder.