A flame-resistant polymer composite separator for use in a lithium battery, wherein the polymer composite separator comprises (a) a binder or matrix polymer; (b) 0.1% to 50% by weight of a lithium salt dispersed in the polymer; and (c) from 30% to 99% by weight of particles or fibers of an inorganic material or polymer fibers that are dispersed in or bonded by the polymer, wherein the polymer is a polymerization or crosslinking product of a reactive additive comprising (i) a first liquid solvent that is polymerizable, (ii) an initiator or crosslinking agent, and (iii) the lithium salt and wherein the polymer composite separator has a thickness from 50 nm to 100 μm and a lithium ion conductivity from 10.sup.−8 S/cm to 5×10.sup.−2 S/cm at room temperature.

A separator in which at least one surface of a porous base is coated with a coating layer including partially-reduced graphene oxide and a lithium ion conducting polymer, and thereby capable of resolving problems caused by lithium polysulfide occurring in a lithium secondary battery, and a lithium secondary battery including the same.

An electrode assembly and related battery, device, manufacturing method, and manufacturing device are provided. In some embodiments, the electrode assembly includes: a first electrode plate and a second electrode plate that are of opposite polarities, where an active material region of the first electrode plate and an active material region of the second electrode plate are wound to form a body portion, a non-active material region of the first electrode plate or a non-active material region of the second electrode plate is wound to form a tab, and the tab includes a bend portion bent against the body portion; and a guide piece. At least a part of the guide piece is located in the bend portion, and the guide piece is configured to guide an electrolytic solution into an interior of the body portion.

A lithium secondary battery comprising a cathode, an anode, and a thermally stable polymer composite separator disposed between said cathode and said anode, wherein said composite separator comprises a thermally stable polymer, comprising a phosphorous-containing polymer, and from 30% to 99% by weight of particles of an inorganic material electrolyte and the particles are dispersed in or bonded by the thermally stable polymer, wherein the composite separator has a thickness from 50 nm to 100 μm and a lithium ion conductivity from 10.sup.−8 S/cm to 5×10.sup.−2 S/cm at room temperature.

A lithium secondary battery comprising a cathode, an anode, and a thermally stable polymer composite separator disposed between said cathode and said anode, wherein said composite separator comprises a thermally stable polymer, comprising a phosphorous-containing polymer, and from 30% to 99% by weight of particles of an inorganic material electrolyte and the particles are dispersed in or bonded by the thermally stable polymer, wherein the composite separator has a thickness from 50 nm to 100 μm and a lithium ion conductivity from 10.sup.−8 S/cm to 5×10.sup.−2 S/cm at room temperature.

In one embodiment of the present invention, it is provided a method of manufacturing a separator comprising:

preparing expansion graphite; pulverizing the expansion graphite; mixing the expansion graphite and polymer; and forming a separator by molding the mixture.

In one embodiment of the present invention, it is provided a method of manufacturing a separator comprising:

preparing expansion graphite; pulverizing the expansion graphite; mixing the expansion graphite and polymer; and forming a separator by molding the mixture.

A low cost, sandwich-structured thin film composite (TFC) anion exchange membrane for redox flow batteries, fuel cells, electrolysis, and other electrochemical reaction applications is described. The sandwich-structured TFC anion exchange membrane comprises a microporous substrate membrane, a first hydrophilic ionomeric polymer coating layer on the surface of the microporous substrate layer, a cross-linked protonated polyamine anion exchange polymer coating layer on top of the first hydrophilic ionomeric polymer coating layer, and a second hydrophilic ionomeric polymer protective layer on top of the cross-linked protonated polyamine anion exchange polymer coating layer. Methods of making the TFC anion exchange membrane comprises a microporous substrate membrane and redox flow battery system incorporating the TFC anion exchange membrane comprises a microporous substrate membrane are also described.

A low cost, sandwich-structured thin film composite (TFC) anion exchange membrane for redox flow batteries, fuel cells, electrolysis, and other electrochemical reaction applications is described. The sandwich-structured TFC anion exchange membrane comprises a microporous substrate membrane, a first hydrophilic ionomeric polymer coating layer on the surface of the microporous substrate layer, a cross-linked protonated polyamine anion exchange polymer coating layer on top of the first hydrophilic ionomeric polymer coating layer, and a second hydrophilic ionomeric polymer protective layer on top of the cross-linked protonated polyamine anion exchange polymer coating layer. Methods of making the TFC anion exchange membrane comprises a microporous substrate membrane and redox flow battery system incorporating the TFC anion exchange membrane comprises a microporous substrate membrane are also described.

Provided is a laminated body in which a short circuit caused by the formation of a dendrite is prevented and which achieves stable voltage output. A laminated body (50) in accordance with an aspect of the present invention includes a solid electrolyte layer (20) and a layer (30) that contains a heat-resistant resin and an ion-conductive material. The solid electrolyte layer (20) and the layer (30) containing the heat-resistant resin and the ion-conductive material are adjacent to each other.