An electrode for use in a device configured to remove ions from a solution. The electrode includes an intercalation material including a binary transition metal Prussian blue analogue compound, a ternary transition metal Prussian blue analogue compound, or a combination thereof. The binary compound may have a general formula: A.sub.xB.sub.yC.sub.z[Fe(CN).sub.6], where A=Li, Na, or K; B=Mn, Fe, Ni, Cu, or Zn; C=Mn, Fe, Ni, Cu, or Zn; 0≤x≤1; 0≤y≤1; and 0≤z≤1. The ternary compound may have the general formula: A.sub.xB.sub.yC.sub.zD.sub.w[Fe(CN).sub.6], where A=Li, Na, or K; B=Mn, Fe, Ni, Cu, or Zn; C=Mn, Fe, Ni, Cu, or Zn; D=Mn, Fe, Ni, Cu, or Zn; 0≤x≤1; 0≤y≤1; 0≤z≤1; 0≤w≤1.

An electrode for use in a device configured to remove ions from a solution. The electrode includes an intercalation material including a binary transition metal Prussian blue analogue compound, a ternary transition metal Prussian blue analogue compound, or a combination thereof. The binary compound may have a general formula: A.sub.xB.sub.yC.sub.z[Fe(CN).sub.6], where A=Li, Na, or K; B=Mn, Fe, Ni, Cu, or Zn; C=Mn, Fe, Ni, Cu, or Zn; 0≤x≤1; 0≤y≤1; and 0≤z≤1. The ternary compound may have the general formula: A.sub.xB.sub.yC.sub.zD.sub.w[Fe(CN).sub.6], where A=Li, Na, or K; B=Mn, Fe, Ni, Cu, or Zn; C=Mn, Fe, Ni, Cu, or Zn; D=Mn, Fe, Ni, Cu, or Zn; 0≤x≤1; 0≤y≤1; 0≤z≤1; 0≤w≤1.

Disclosed herein are membrane-electrode assemblies and fuel cells comprising an anode comprising a first catalyst; a cathode comprising a second catalyst; and a proton exchange membrane between the anode and cathode; wherein at least one of the proton exchange membrane, anode, and cathode comprise an antioxidant comprising yttrium doped cerium oxide and a metal doped cerium oxide that has a faster release time of cerium ions compared to yttrium doped cerium oxide.

Disclosed herein are membrane-electrode assemblies and fuel cells comprising an anode comprising a first catalyst; a cathode comprising a second catalyst; and a proton exchange membrane between the anode and cathode; wherein at least one of the proton exchange membrane, anode, and cathode comprise an antioxidant comprising yttrium doped cerium oxide and a metal doped cerium oxide that has a faster release time of cerium ions compared to yttrium doped cerium oxide.

Separators, high performance electrochemical devices, such as, batteries and capacitors, including the aforementioned separators, systems and methods for fabricating the same. In one implementation, a separator is provided. The separator comprises a polymer substrate (131), capable of conducting ions, having a first surface and a second surface opposing the first surface. The separator further comprises a first ceramic-containing layer (136), capable of conducting ions, formed on the first surface. The first ceramic-containing layer (136) has a thickness in arrange from about 1,000 nanometers to about 5000 nanometers. The separator further comprises a second ceramic-containing layer (138), capable of conducting ions, formed on the second surface. The second ceramic-containing layer (138) is a binder-free ceramic-containing layer and has a thickness in arrange from about 1 nanometer to about 1,000 nanometers.

A lithium metal electrode has no more than five ppm of non-metallic elements by mass, and is bonded to a conductive substrate. Optionally, the lithium metal electrode may be bonded on one side to a conductive substrate and on another side to a lithium ion selective membrane. The lithium metal electrode may be integrated into lithium metal batteries. The inventive lithium metal electrode may be manufactured by a process involving electrolysis of lithium ions from an aqueous lithium salt solution through an ion selective membrane, carried out under a blanketing atmosphere having no more than 10 ppm of non-metallic elements, the electrolysis being performed at a constant current between about 10 mA/cm.sup.2 and about 50 mA/cm.sup.2, and wherein the constant current is applied for a time between about 1 minute and about 60 minutes.

Electrolyte-infiltrated composite electrode includes an electrolyte component consisting of a polymer matrix with ceramic nanoparticles embedded in the matrix to form a networking structure of electrolyte. Suitable ceramic nanoparticles have the basic formula Li.sub.7La.sub.3Zr.sub.2O.sub.12 (LLZO) and its derivatives such as Al.sub.xLi.sub.7-xLa.sub.3Zr.sub.2-y-zTa.sub.yNb.sub.zO.sub.12 where x ranges from 0 to 0.85, y ranges from 0 to 0.50 and z ranges from 0 to 0.75, wherein at least one of x, y and z is not equal to 0. The networking structure of the electrolyte establishes an effective lithium-ion transport pathway in the electrode and strengthens the contact between electrode layer and solid-state electrolyte resulting in higher lithium-ion electrochemical cell's cycling stability and longer battery life. Sold-state electrolytes incorporating the ceramic particles demonstrate improved performance. Large dimensional electrolyte-infiltrated composite electrode sheets can be used in all solid-state lithium electrochemical pouch cells which can be assembled into battery packs.

A battery separator has performance enhancing additives or coatings, fillers with increased friability, increased ionic diffusion, decreased tortuosity, increased wettability, reduced oil content, reduced thickness, decreased electrical resistance, and/or increased porosity. The separator in a battery reduces the water loss, lowers acid stratification, lowers the voltage drop, and/or increases the CCA. The separators include or exhibit performance enhancing additives or coatings, increased porosity, increased void volume, amorphous silica, higher oil absorption silica, higher silanol group silica, reduced electrical resistance, a shish-kebab structure or morphology, a polyolefin microporous membrane containing particle-like filler in an amount of 40% or more by weight of the membrane and ultrahigh molecular weight polyethylene having shish-kebab formations and the average repetition periodicity of the kebab formation from 1 nm to 150 nm, decreased sheet thickness, decreased tortuosity, separators especially well-suited for enhanced flooded batteries.

In an aspect, a solid-state Li-ion battery (SSLB) cell, may comprise an anode electrode comprising an anode electrode surface and an anode active material, a cathode electrode comprising a cathode electrode surface and an cathode active material, and an inorganic, melt-infiltrated, solid state electrolyte (SSE) ionically coupling the anode electrode and the cathode electrode, wherein at least a portion of at least one of the electrode surfaces comprises an interphase layer separating the respective electrode active material from direct contact with the SSE, and wherein the interphase layer comprises two or more metals from the list of: Zr, Al, K, Cs, Fr, Be, Mg, Ca, Sr, Ba, Sc, Y, La or non-La lanthanoids, Ta, Zr, Hf, and Nb.

A coated hybrid electrode for a composite solid-state battery cell is disclosed. Systems and methods are further provided for forming an electrolyte coating including a solid ionically conductive polymer material in the coated hybrid electrode. In one example, the coated hybrid electrode can include an anode material coating, the solid polymer electrolyte coating, and a cathode material coating, such that the solid polymer electrolyte coating can function as a separator coating between the anode material coating and the cathode material coating, thus eliminating a need for a conventional battery separator. In some examples, a slurry-based coating process can be utilized for forming the solid polymer electrolyte coating. As such, the solid polymer electrolyte coating can be mechanically robust with uniform thickness. Further, a battery cell can be formed by utilizing a sub-assembly stacking technique to provide battery cell stiffness and increase precision and accuracy of coating.