The invention relates to flow batteries having improved crossover resistance to electroactive species, excellent coulombic and voltage efficiency and durability, which batteries comprise a separator membrane comprising an ionomer having a high equivalent weight, EW, to achieve these performance benefits. The ionomer has an EW of 1150 to 2000. Preferably, the ionomer is a perfluorosulfonic acid ionomer which has substantially all of the functional groups being represented by the formula SO.sub.3X wherein X is H, Li, Na, K or N(R.sup.1)(R.sup.2)(R.sup.3)(R.sup.4) and R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are the same or different and are H, CH.sub.3 or C.sub.2H.sub.5. Preferably, substantially all of the functional groups are represented by the formula SO.sub.3X wherein X is H.

A system and method for preparing a vanadium battery high-purity electrolyte, comprising preparing a low-valence vanadium oxide with a valence of 3.5 with liquid phase hydrolysis and fluidization reduction with vanadium oxytrichloride, adding clean water and sulfuric acid for dissolution, and further performing ultraviolet activation to obtain the vanadium electrolyte, for use in an all-vanadium redox flow battery stack. The high-temperature tail gas in the reduction fluidized bed is combusted for preheating the vanadium powder material, to recover the sensible heat and latent heat of the high-temperature tail gas, and the sensible heat of the reduction product is recovered through heat transfer between the reduction product and the fluidized nitrogen gas. An internal member is arranged in the reduction fluidized bed to realize the precise regulation of the valence state of the reduction product, and ultraviolet is used to activate the vanadium ions, improving the activity of the electrolyte.

The present invention is characterized by comprising: an acid leaching step for obtaining a leach liquid by causing leaching of, by means of an acid, a metal mixture at least containing vanadium and at least one type of a divalent or trivalent metal selected from nickel, cobalt, manganese, palladium, platinum, copper, and zinc; a complex generation step for adding an ammoniacal alkaline aqueous solution to the leach liquid for adjusting the pH to 10-12 and generating, in the alkaline aqueous solution, an ammine complex of a divalent or trivalent metal ion and an anion complex of a tetravalent and/or pentavalent vanadium ion; a divalent or trivalent metal recovery step for adding a carrier having a carboxyl group to the alkaline aqueous solution in which the ammine complex and the anion complex are generated, causing the divalent or trivalent metal ion in the ammine complex to be selectively adsorbed onto the carrier, and recovering the divalent or trivalent metal ion; and a vanadium recovery step for recovering vanadium from the anion complex contained in the alkaline aqueous solution after the divalent or trivalent metal ion is recovered.

Disclosed herein are exemplary embodiments of improved separators for lead acid batteries, improved lead acid batteries incorporating the improved separators, and systems incorporating the same. A lead acid battery separator is provided with a porous membrane with a plurality of ribs extending from a surface thereon. The ribs are provided with a plurality of discontinuous peaks arranged such as to provide resilient support for the porous membrane in order to resist forces exerted by swelling NAM and thus mitigate the effects of acid starvation associated with NAM swelling. The separator is also provided to be capable utilizing any motion experienced by the battery housing such a separator in order to mitigate the effects of acid stratification by facilitating acid mixing. A lead acid battery is further provided that incorporates the provided separator. Such a lead acid battery may be a flooded lead acid battery, an enhanced flooded lead acid battery, and may be provided as operating in a partial state of charge. Systems incorporating such a lead acid battery are also provided, such as a vehicle or any other energy storage system, such as solar or wind energy collection. Other exemplary embodiments are provided such as to have any one or more of the following: a lowered electrical resistance; increased puncture resistance; increased oxidation resistance; increased ability to mitigate the effects of dendrite growth, and/or other improvements.

A lead-acid battery is disclosed. The lead-acid storage battery has a container with a cover, the container including one or more compartments. One or more cell elements are provided in the one or more compartments. The one or more cell elements include a positive plate, the positive plate having a positive grid and a positive electrochemically active material on the positive grid; a negative plate, the negative plate having a negative grid and a negative electrochemically active material on the negative grid, wherein the negative electrochemically active material comprises barium sulfate and an organic expander; and a separator between the positive plate and the negative plate. Electrolyte is provided within the container. One or more terminal posts extend, from the cover and are electrically coupled to the one or more cell elements.

A raw material of an electrolyte solution that is to be dissolved in a solvent to form an electrolyte solution, and the raw material of an electrolyte solution is a raw material of an electrolyte solution that is a solid or semisolid that contains Ti in an amount of 2 mass % to 83 mass % inclusive, Mn in an amount of 3 mass % to 86 mass % inclusive, and S in an amount of 6 mass % to 91 mass % inclusive.

Described are aqueous rechargeable hydrogen batteries operating in the full pH range (e.g., pH: 1 to 15) with potential for electrical grid storage. The pH-universal hydrogen batteries operate with different redox chemistry on the cathodes and reversible hydrogen evolution/oxidation reactions (HER/HOR) on the anode. The reactions can be catalyzed by a highly active ruthenium-based electrocatalyst. The ruthenium-based catalysts exhibit comparable specific activity and superior long-term stability of HER/HOR to that of state-of-the-art Pt/C electrocatalyst in the full pH range. New chemistries for aqueous rechargeable hydrogen batteries are also provided.

An electrochemical device has an electrochemical cell provided with an electrolyte having proton conductivity, an anode provided on one side of the electrolyte, and a cathode provided on the other side of the electrolyte. The electrochemical device is configured so that a solution containing water, an artificial synthetic resin, and an acid is supplied to the anode. The electrochemical device is configured so that an oxygen-containing gas is supplied to the cathode and connecting a load between the anode and the cathode. The electrochemical device is configured so that the inert gas is supplied to the cathode and connecting the voltage application unit between the anode and the cathode.

A positive electrode active material includes a nickel-containing lithium transition metal oxide containing nickel in an amount of 60 mol % or more based on a total number of moles of transition metals excluding lithium, and a lithium-containing inorganic compound layer formed on a surface of the nickel-containing lithium transition metal oxide, wherein the positive electrode active material has a first peak in a range of 5 eV or less, a second peak in a range of 7 eV to 13 eV, and a third peak in a range of 20 eV to 30 eV when intensity is measured by X-ray photoelectron spectroscopy, and the first peak has a maximum value of 80% to 120% with respect to the third peak. A method of preparing the positive electrode active material, and a positive electrode and a lithium secondary battery are also provided.

Disclosed is a lead acid battery including: a positive electrode; a negative electrode; a separator interposed between the positive electrode and the negative electrode; and an electrolyte containing sulfuric acid. The negative electrode includes a negative electrode active material, and a negative electrode grid that supports the negative electrode active material. The negative electrode grid contains tin in an amount of 0.1 mass % or more and 0.8 mass % or less. The electrolyte contains aluminum ions at a concentration of 1 mmol/L or more and less than 10 mmol L, and sodium ions at a concentration of 15 mmol/L or less.