A semiconductor device includes a diffusion barrier structure, a bottom electrode, a top electrode over the bottom electrode, a switching layer and a capping layer. The bottom electrode is over the diffusion barrier structure. The top electrode is over the bottom electrode. The switching layer is between the bottom electrode and the top electrode, and configured to store data. The capping layer is between the top electrode and the switching layer. A thermal conductivity of the diffusion barrier structure is greater than approximately 20 W/mK.

A semiconductor memory structure includes a memory cell, an encapsulation layer over a sidewall of the memory cell, and a nucleation layer between the sidewall of the memory cell and the encapsulation layer. The memory cell includes a top electrode, a bottom electrode and a data-storage element sandwiched between the bottom electrode and the top electrode. The nucleation layer includes metal oxide.

An resistive random-access memory (RRAM) device including an first crystalline semiconductor layer disposed adjacent to a crystalline semiconductor substrate, a crystal lattice edge-dislocation segment disposed at an interface of the first crystalline semiconductor layer and crystalline semiconductor substrate, the lattice edge-dislocation segment including first and second segment ends, a first ion-source electrode disposed upon the electrically isolating spacer, adjacent to the crystalline substrate and first crystalline semiconductor layer, and further disposed in contact with the first segment end of the lattice edge-dislocation segment, and a second electrode disposed upon the electrically isolating spacer, adjacent to the crystalline substrate and first crystalline semiconductor layer, and further disposed in contact with the second segment end of the lattice edge-dislocation segment.

Disclosed are electrochemically tunable metamaterials which are capable of complete reversibility such that the metamaterial itself can physically disappear (out of the active region) and reappear later, in a controllable manner. Some variations provide an electrochemically tunable, solid-state metamaterial-based device comprising a plurality of metamaterial unit cells, wherein each of the metamaterial unit cells comprises: an ion conductor containing mobile metal ions; a first electrode in contact with the ion conductor, wherein the first electrode is contained in a metasurface negative space disposed on the ion conductor; a second electrode in contact with the ion conductor, wherein the second electrode is electrically isolated from the first electrode; and a metal-containing region containing one or more metals, wherein the metal-containing region is contained within a metasurface positive space disposed on the ion conductor.

A semiconductor device includes a diffusion barrier structure, a bottom electrode, a top electrode, a switching layer and a capping layer. The bottom electrode is over the diffusion barrier structure. The top electrode is over the bottom electrode. The switching layer is between the bottom electrode and the top electrode, and configured to store data. The capping layer is between the switching layer and the top electrode. The diffusion barrier structure includes a multiple-layer structure. A thermal conductivity of the diffusion barrier structure is greater than approximately 20 W/mK.

The disclosed subject matter relates generally to structures, memory devices and a method of forming the same. More particularly, the present disclosure relates to resistive random-access (ReRAM) memory devices having a spacer element on a side of the electrode. The present disclosure provides a memory device including a first electrode having a side, the side has upper and lower portions, a spacer element on the lower portion of the side of the first electrode, a resistive layer on the upper portion of the side of the first electrode, and a second electrode laterally adjacent to the side of the first electrode. The second electrode has a top surface, in which the top surface has a concave profile.

A ferroelectric component includes a first electrode, a tunnel barrier layer disposed on the first electrode to include a ferroelectric material, a tunneling control layer disposed on the tunnel barrier layer to control a tunneling width of electric charges passing through the tunnel barrier layer, and a second electrode disposed on the tunneling control layer.

A memory structure is provided. The memory structure includes a top terminal, a multi-level nonvolatile electrochemical cell, a bottom terminal, a pedestal contact in the same metal level as the bottom terminal, and a vertical conductor fully self-aligned to the multi-level nonvolatile electrochemical cell and extending vertically from the pedestal contact.

A two-terminal atom-based switching device having a fast operating speed and high durability and a manufacturing method thereof are disclosed. It is possible to reduce a forming voltage during positive voltage forming by forming an oxygen vacancy percolation path through negative voltage forming, which is first forming, and forming high binding energy and low formation energy between oxygen vacancies and metal ions implanted through positive voltage forming which is second forming after the negative voltage forming. Further, since a significant amount of metal ions implanted into the insulating layer through negative voltage application switching after the positive voltage forming is removed, the volatility of the two-terminal atom-based switching device may be improved, and a stuck-on failure phenomenon in the durability may be prevented.

A memory cell and formation thereof. The memory cell including: a first dielectric material having a via; a dielectric spacer on a sidewall of the via, and a second dielectric material pinching off the via and forming a seam.