It is a CNT device (1) (carbon-metal structure) equipped with a carbon nanotube layer (2) (CNT layer 2; same hereafter) on a metal pedestal (4). The metal pedestal (4) is brazed to the CNT layer (2) with a brazing material layer (3) interposed therebetween. When manufacturing the CNT device (1), firstly, the CNT layer (2) is formed on a heat-resistant textured substrate (6). Next, the metal pedestal (4) is brazed to the CNT layer (2) that is on the heat-resistant textured substrate (6) with the brazing material layer (3) interposed therebetween. Then, the metal pedestal (4) (and the CNT layer 2) is peeled off the heat-resistant textured substrate (6) to transfer the CNT layer (2) from the heat-resistant textured substrate (6) to the metal pedestal (4).

A capacitor electrode including a first carbon, and at least one of a second carbon and a metal porous body. The first carbon includes a graphene, and the second carbon includes short carbon fibers having an average length of 10 μm or less and/or carbon particles having an average diameter of 0.1 μm or less. The graphene is layered via the second carbon.

A capacitor electrode including a first carbon, and at least one of a second carbon and a metal porous body. The first carbon includes a graphene, and the second carbon includes short carbon fibers having an average length of 10 μm or less and/or carbon particles having an average diameter of 0.1 μm or less. The graphene is layered via the second carbon.

Energized composites include vertically aligned graphene on carbon fibers (VGCF). The VGCF enhances surface area available for charge storage, acts as templates for depositing other charge storing materials and provides stability for a minimum of 100,000 discharge cycles. The final storage device is in the order of high strength carbon fiber matrix with active material, glass fiber separator with polymer electrolyte and another carbon fiber matrix with active material. To achieve higher voltage or current, devices can be connected in series or parallel, respectively. The whole structure is made into a structural component by infusing epoxy resin. An alternating pattern of energy storage devices allows for the epoxy resin to seep through the whole structure and strongly bind them to make a monolith multifunctional composite. The high strength energized composites can power any electrical devices including electric vehicles, portable electronics, and space vehicles without any tradeoff between energy and structural integrity.

Energized composites include vertically aligned graphene on carbon fibers (VGCF). The VGCF enhances surface area available for charge storage, acts as templates for depositing other charge storing materials and provides stability for a minimum of 100,000 discharge cycles. The final storage device is in the order of high strength carbon fiber matrix with active material, glass fiber separator with polymer electrolyte and another carbon fiber matrix with active material. To achieve higher voltage or current, devices can be connected in series or parallel, respectively. The whole structure is made into a structural component by infusing epoxy resin. An alternating pattern of energy storage devices allows for the epoxy resin to seep through the whole structure and strongly bind them to make a monolith multifunctional composite. The high strength energized composites can power any electrical devices including electric vehicles, portable electronics, and space vehicles without any tradeoff between energy and structural integrity.

An electrical storage device includes high surface area fibers (e.g., shaped fibers and/or microfibers) coated with carbon (graphite, expanded graphite, activated carbon, carbon black, carbon nanofibers, CNT, or graphite coated CNT), electrolyte, and/or electrode active material (e.g., lead oxide) in electrodes. The electrodes are used to form electrical storage devices such as electrochemical batteries, electrochemical double layer capacitors, and asymmetrical capacitors.

An electrical storage device includes high surface area fibers (e.g., shaped fibers and/or microfibers) coated with carbon (graphite, expanded graphite, activated carbon, carbon black, carbon nanofibers, CNT, or graphite coated CNT), electrolyte, and/or electrode active material (e.g., lead oxide) in electrodes. The electrodes are used to form electrical storage devices such as electrochemical batteries, electrochemical double layer capacitors, and asymmetrical capacitors.

Porous carbon fiber electrode materials are provided having fast electron and ion transport. The porous carbon fiber electrodes include uniform mesoscale pores that are partially filled with a metal oxide layer. With large mass loadings of metal oxide, porous carbon fiber electrodes described herein can outperform conventional metal oxide electrodes at similar loadings. In various aspects, electrode materials are provided having (i) a porous carbon fiber support with a plurality of mesoscale pores having an internal surface and an average pore width of about 2 mm to about 200 mm; and (ii) a metal oxide layer on at least the internal surface of the mesoscale pores. Methods of making the porous carbon fiber electrode materials are also provided. Using a microphase-separation of block copolymers, the methods can provide porous carbon fiber supports with interconnected and uniform mesoscale pores that can be deposited with a metal oxide layer.

Porous carbon fiber electrode materials are provided having fast electron and ion transport. The porous carbon fiber electrodes include uniform mesoscale pores that are partially filled with a metal oxide layer. With large mass loadings of metal oxide, porous carbon fiber electrodes described herein can outperform conventional metal oxide electrodes at similar loadings. In various aspects, electrode materials are provided having (i) a porous carbon fiber support with a plurality of mesoscale pores having an internal surface and an average pore width of about 2 mm to about 200 mm; and (ii) a metal oxide layer on at least the internal surface of the mesoscale pores. Methods of making the porous carbon fiber electrode materials are also provided. Using a microphase-separation of block copolymers, the methods can provide porous carbon fiber supports with interconnected and uniform mesoscale pores that can be deposited with a metal oxide layer.

Provided herein is a battery and an electrode. The battery may include two electrodes; and an electrolyte, wherein at least one electrode further includes: a nano-scale coated network, which includes one or more first carbon nanotubes electrically connected to one or more second carbon nanotubes to form a nano-scale network, wherein at least one of the one or more second carbon nanotubes is in electrical contact with another of the one or more second carbon nanotubes. The battery may further include an active material coating distributed to cover portions of the one or more first carbon nanotubes and portions of the one or more second carbon nanotubes, wherein a plurality of the one or more second carbon nanotubes are in electrical communication with other second carbon nanotubes under the active material coating. Also provided herein is a method of making a battery and an electrode.