The disclosure discloses electrode material, preparation methods thereof and supercapacitors based thereof. Raw material for preparing the electrode material include PVDF and an additive which can be reacted with the PVDF to generate conductive active substance, the amount of the PVDF is 50 to 99 mass percentage, and the amount of the additive is 1 to 50 mass percentage. A PVDF-based composite film can be prepared from the raw materials; and activating treatment is performed on the film by virtue of a physico-chemical process, so that PVDF can generate a conductive active substance, the contact resistance of the PVDF and the active substance is reduced, and the conductive active substance is distributed in the PVDF-based composite film more uniformly. Button and wound supercapacitor and flexible capacitor, which are prepared from the electrode material, are high in power density and energy density, long in cycle life.

Methods that expand the properties of laser-induced graphene (LIG) and the resulting LIG having the expanded properties. Methods of fabricating laser-induced graphene from materials, which range from natural, renewable precursors (such as cloth or paper) to high performance polymers (like Kevlar). With multiple lasing, however, highly conductive PEI-based LIG could be obtained using both multiple pass and defocus methods. The resulting laser-induced graphene can be used, inter alia, in electronic devices, as antifouling surfaces, in water treatment technology, in membranes, and in electronics on paper and food Such methods include fabrication of LIG in controlled atmospheres, such that, for example, superhydrophobic and superhydrophilic LIG surfaces can be obtained. Such methods further include fabricating laser-induced graphene by multiple lasing of carbon precursors. Such methods further include direct 3D printing of graphene materials from carbon precurors. Application of such LIG include oil/water separation, liquid or gas separations using polymer membranes, anti-icing, microsupercapacitors, supercapacitors, water splitting catalysts, sensors, and flexible electronics.

Provided is a process for producing an electrolyte-impregnated laminar graphene structure for use as a supercapacitor electrode. The process comprises (a) preparing a graphene dispersion having multiple isolated graphene sheets dispersed in an electrolyte; and (b) subjecting the graphene dispersion to a forced assembly procedure, forcing the multiple graphene sheets to assemble into an electrolyte-impregnated laminar graphene structure, wherein the multiple graphene sheets are alternately spaced by thin electrolyte layers, less than 5 nm in thickness, and the graphene sheets are substantially aligned along a desired direction, and wherein the laminar structure has a physical density from 0.5 to 1.7 g/cm.sup.3 and a specific surface area from 50 to 3,300 m.sup.2/g, when measured in a dried state of the laminar structure with the electrolyte removed. This process leads to a supercapacitor having a large electrode thickness, high active mass loading, high tap density, and exceptional energy density.

The present invention provides an electrode material for an electrochemical capacitor having high surface utilization efficiency, composed of a porous carbon material capable of further contributing to higher electrostatic capacitance of the electrochemical capacitor and to development of high rate characteristics; the porous carbon material having a co-continuous structural portion in which a carbon skeleton and voids form respective continuous structures, the co-continuous structural portion having a structural period of 0.002 μm to 20 μm.

The present patent application discloses a method of producing nano-porous carbon, comprising mixing furfuryl alcohol or its fast-polymerizing derivatives with an aluminum-based solid polymerization catalyst, heating the mixture until a solid catalyst-carbon matrix forms, heating again under inert atmosphere and etching the powder to remove the matrix to produce a network of pores in the nano-porous carbon. The application further provides a method for making of fabricating tailor-made nano-porous carbon electrodes.

A negative electrode material for a power storage device contains a single-phase porous carbon material capable of electrochemically occluding and releasing lithium ions, the single-phase porous carbon material has a BET specific surface area of not less than 100 m.sup.2/g, and a cumulative volume of pores having a pore diameter of 2 nm to 50 nm in a pore diameter distribution of the single-phase porous carbon material is not less than 25% of a total pore volume.

A method of fabricating a highly activated, highly porous, highly electrically conductive net-shaped monolithic electrode for use in an electrical energy storage device including an ultracapacitor, pseudo-capacitor, battery, or in an electricity producing device such as a fuel-cell or in a gas producing device, such as a hydrogen generator or an oxygen generator.

A capacitor electrode including a first carbon, and at least one of a second carbon and a metal porous body. The first carbon includes a graphene, and the second carbon includes short carbon fibers having an average length of 10 μm or less and/or carbon particles having an average diameter of 0.1 μm or less. The graphene is layered via the second carbon.

A method is described to make a metal-containing non-amorphous hard-carbon composite material that is synthesized from furan-ring containing compounds. The metals described in the process include lithium and transition metals, including transition metal oxides like lithium titanates. The non-amorphous hard-carbon component of the metal-containing non-amorphous hard-carbon composite material is characterized by a d.sub.002 peak—in the X-ray diffraction patterns—that corresponds to an interlayer spacing of >3.6 Å, along with a prominent D-band peak in the Raman spectra. These metal-containing hard-carbon composites are used for constructing electrodes for Li-ion batteries and Li-ion capacitors.

A carbonaceous material may have a high capacitance per volume as well as a high durability, and/or may have a BET specific surface area is 1,500 to 1,900 m.sup.2/g, an average pore size is 1.84 to 2.05 nm at a nitrogen relative pressure P/P.sub.0 of 0.93 in a nitrogen adsorption isotherm measured at 77.4 K, a ratio of pore volume having a pore size of 3 nm or smaller, determined by the BJH method, is 65 to 90% relative to total pore volume calculated based on a nitrogen adsorption amount at a relative pressure P/P.sub.0 of 0.93 in the nitrogen adsorption isotherm, and a ratio of pore volume having a pore size of 1 to 2 nm, determined by the MP method, is 10 to 20% relative to total pore volume calculated based on the nitrogen adsorption amount at a relative pressure P/P.sub.0 of 0.93 in the nitrogen adsorption isotherm.