Provided is a process for producing a graphene-based supercapacitor electrode from a supply of coke or coal powder, comprising: (a) exposing this powder to a supercritical fluid for a period of time in a pressure vessel to enable penetration of the supercritical fluid into internal structure of the coke or coal; wherein the powder is selected from petroleum coke, coal-derived coke, meso-phase coke, synthetic coke, leonardite, anthracite, lignite coal, bituminous coal, or natural coal mineral powder, or a combination thereof; (b) rapidly depressurizing the supercritical fluid at a fluid release rate sufficient for effecting exfoliation and separation of the coke or coal powder to produce isolated graphene sheets, which are dispersed in a liquid medium to produce a graphene suspension; and (c) shaping and drying the graphene suspension to form the supercapacitor electrode having a specific surface area greater than 200 m.sup.2/g.

Apparatuses and methods for forming an electrode film mixture are described. An apparatus for forming an electrode film mixture can have a first source including a solution comprising a polymer, for example, polytetrafluoroethylene and a critical or supercritical fluid, for example, supercritical carbon dioxide, a second source including a second component of the electrode film mixture, a mixer configured to receive the solution and the second component and to form a slurry comprising the solution and the second component. The apparatus can include a decompressor configured to receive the slurry and decompress the slurry to vaporize the critical or supercritical fluid and precipitate dry polymer.

Apparatuses and methods for forming an electrode film mixture are described. An apparatus for forming an electrode film mixture can have a first source including a solution comprising a polymer, for example, polytetrafluoroethylene and a critical or supercritical fluid, for example, supercritical carbon dioxide, a second source including a second component of the electrode film mixture, a mixer configured to receive the solution and the second component and to form a slurry comprising the solution and the second component. The apparatus can include a decompressor configured to receive the slurry and decompress the slurry to vaporize the critical or supercritical fluid and precipitate dry polymer.

PDC resins are mixed with various sources of carbon to form electrodes through pyrolysis of the mixture of PDC resins and coal dust derived materials with or without other sources of carbon, substrates and the like. For example, a PDC resin-coal dust mixture produces a material for use as an anode in lithium ion batteries and supercapacitors when pyrolyzed to form a porous, electrically conductive ceramic composite.

PDC resins are mixed with various sources of carbon to form electrodes through pyrolysis of the mixture of PDC resins and coal dust derived materials with or without other sources of carbon, substrates and the like. For example, a PDC resin-coal dust mixture produces a material for use as an anode in lithium ion batteries and supercapacitors when pyrolyzed to form a porous, electrically conductive ceramic composite.

The present application is directed to methods for preparation of carbon materials. The carbon materials comprise enhanced electrochemical properties and find utility in any number of electrical devices, for example, as electrode material in ultracapacitors or batteries.

The present application is directed to methods for preparation of carbon materials. The carbon materials comprise enhanced electrochemical properties and find utility in any number of electrical devices, for example, as electrode material in ultracapacitors or batteries.

The present application is directed to methods for preparation of carbon materials. The carbon materials comprise enhanced electrochemical properties and find utility in any number of electrical devices, for example, as electrode material in ultracapacitors or batteries.

The present application is directed to methods for preparation of carbon materials. The carbon materials comprise enhanced electrochemical properties and find utility in any number of electrical devices, for example, as electrode material in ultracapacitors or batteries.

Laser-induced graphene (LIG) and laser-induced graphene scrolls (LIGS) materials and, more particularly to LIGS, methods of making LIGS (such as from polyimide (PI)), laser-induced removal of LIG and LIGS, and 3D printing of LIG and LIGS using a laminated object manufacturing (LOM) process.