An aspect of the present disclosure is a system that includes a first deposition system that includes a first cylinder having a first outer surface configured to hold a first substrate, a first spray nozzle configured to receive at least a first fluid, and a first fiber nozzle configured to receive at least a second fluid, where the first spray nozzle is configured to operate at a first voltage, the first fiber nozzle is configured to operate at a second voltage, the first cylinder is configured to be electrically connected to ground, the first spray nozzle is configured to apply onto the substrate a first plurality of at least one of particles or droplets from the first fluid, the first fiber nozzle is configured to apply onto the substrate a first fiber from the second fluid, and the first plurality of particles or droplets and the first fiber combine to form a first composite layer on the substrate.

An all-solid secondary battery, including: a cathode; an anode; and a solid electrolyte layer disposed between the cathode and the anode, wherein the anode comprises an anode current collector; a first anode active material layer in contact with the anode current collector and comprising a first metal; a second anode active material layer disposed between the first anode active material layer and the solid electrolyte layer and comprising a carbon-containing active material; and a contact layer between the second anode active material layer and the solid electrolyte layer, and disposed such that the contact layer prevents contact between the second anode active material layer and the solid electrolyte layer, wherein the contact layer comprises a second metal, and has a thickness less than a thickness of the first anode active material layer.

Methods, systems, and compositions for the solution-phase deposition of thin films comprising one or more artificial solid-electrolyte interphase (SEI) layers. The thin films can be coated onto the surface of porous components of electrochemical devices, such as solid-state electrolytes employed in rechargeable batteries. The methods and systems provided herein involve exposing the component to be coated to different liquid reagents in sequential processing steps, with optional intervening rinsing and drying steps. Processing may occur in a single reaction chamber or multiple reaction chambers.

An energy storage device includes a nano-structured cathode. The cathode includes a conductive substrate, an underframe and an active layer. The underframe includes structures such as nano-filaments and/or aerogel. The active layer optionally includes a catalyst disposed within the active layer, the catalyst being configured to catalyze the dissociation of cathode active material.

A method of fabricating a flexible battery comprises forming a first substrate on a first release liner, forming at least one current collector layer on each of the first and second substrate, forming an anode side of the battery by forming an anode on the current collector of the first substrate, forming a cathode side of the battery by forming a cathode on the current collector of the second substrate, depositing electrolyte on one or both of the anode and cathode, adhering and sealing the anode side and cathode side together such that the anode and cathode face one another with the electrolyte In between, and removing the flexible battery from the release liners. The battery may be a primary battery or a secondary battery. The method may be implemented using a roll-to-roll process.

A sulfide solid electrolyte that can suppress the generation of hydrogen sulfide gas while maintaining the lithium ion conductivity; and an electrode composite material, a slurry and a battery, in each of which the sulfide solid electrolyte is used, are provided. The sulfide solid electrolyte contains lithium (Li), phosphorus (P) and sulfur (S) elements; at least one halogen (X) element; and at least one metal (M) element having a first ionization energy of more than 520.2 KJ/mol and less than 1007.3 KJ/mol, wherein, in an X-ray diffraction pattern measured with CuKα1 radiation, peaks are present at positions of 2θ=25.19°±1.00° and 29.62°±1.00°.

Methods for making solid-state laminate electrode assemblies include methods of forming a solid electrolyte interphase (SEI) by ion implanting nitrogen and/or phosphorous into the glass surface by ion implantation.

A sulfide solid electrolyte is provided having peak A at 2θ=20.7°±0.5° in an X-ray diffraction pattern obtained by performing X-ray diffraction measurement using CuKα1 radiation. It is preferable that the sulfide solid electrolyte has peak B at 2θ=25.4°±1.0° in the X-ray diffraction pattern obtained by performing X-ray diffraction measurement using CuKα1 radiation. It is also preferable that the value of the ratio of I.sub.A to I.sub.B, I.sub.A/I.sub.B, is more than 0 and 0.7 or less, where I.sub.A is the intensity of peak A and I.sub.B is the intensity of peak B. It is also preferable that the sulfide solid electrolyte has peak C at 2θ=22.0°±0.5° in the X-ray diffraction pattern obtained by performing X-ray diffraction measurement using CuKα1 radiation.

A solid-state battery comprising: a positive current collector; a negative current collector; a solid state electrolyte layer between the positive current collector and the negative current collector; and at least one of a catholyte gradient composite cathode structure between the positive current collector and the solid state electrolyte layer and an anolyte gradient composite anode structure between the negative current collector and the solid state electrolyte layer.

A battery plate having a substrate with opposing surfaces and one or more nonplanar structures and one or more active materials disposed on at least one of the opposing surfaces; wherein the battery plate includes one or more of: i) one or more projections disposed within but do not extend beyond the active material; ii) one or more projections which project beyond the active material and substantially free of the active material or dust formed from the active material; and/or iii) a frame about the periphery of the substrate which projects beyond the active material and is substantially free of the active material or dust formed from the active material; and wherein the battery plate is adapted to form part of one or more electrochemical cells in a battery assembly.