A system for forming a particle layer on a substrate may include at least one sprayer and at least two masks configured to selectively mask a substrate in a first region and second region of the substrate. The at least one sprayer may be configured to spray particles at the substrate, where the at least two masks maintain the first region and second region substantially free of the deposited material. A heater may be employed to heat the substrate as the particles are sprayed by the at least one sprayer onto the substrate.

The present disclosure is directed to methods of securing battery tab structures to binderless, collectorless self-standing electrodes, comprising electrode active material and carbon nanotubes and no foil-based collector, and the resulting battery-tab secured electrodes. Such methods and the resulting battery tab-secured electrodes may facilitate the use of such composites in battery and power applications.

A method of preparing a lithium-ion battery electrode, S1, preparing a carbon nanotube raw material; S2, providing an electrode active material and a solvent; S3, mixing the carbon nanotube raw material and the electrode active material with the solvent to form a mixture, and stirring the mixture to form an electrode mixture; and S4, spraying the electrode mixture on a substrate to form an electrode layer, and removing the substrate and drying the electrode layer to form the lithium-ion battery electrode.

Disclosed is a process for producing graphene-semiconductor nanowire hybrid material, comprising: (A) preparing a catalyst metal-coated mixture mass, which includes mixing graphene sheets with micron or sub-micron scaled semiconductor particles to form a mixture and depositing a nano-scaled catalytic metal onto surfaces of the graphene sheets and/or semiconductor particles; and (B) exposing the catalyst metal-coated mixture mass to a high temperature environment (preferably from 100° C. to 2,500° C.) for a period of time sufficient to enable a catalytic metal-catalyzed growth of multiple semiconductor nanowires using the semiconductor particles as a feed material to form the graphene-semiconductor nanowire hybrid material composition. An optional etching or separating procedure may be conducted to remove catalytic metal or graphene from the semiconductor nanowires.

A disclosed film electrode includes an electrode base, and an active material layer formed on the electrode base, and a resin layer adhering to at least one of a peripheral portion of the active material layer and a surface of the active material layer in a direction extending along a plane of the electrode base.

The invention relates to a method for producing an electrode powder mixture for a battery cell. A powdered active material is provided with a powdered first polymer binder by means of electrostatic coating. The invention also relates to a method for producing an electrode of a battery cell.

A small diameter roll is provided on the upstream side of a heating and sucking roll, an electrode slurry is applied by using a slot nozzle on the small diameter roll or an OFF roll, and an electrode is formed by instantaneously evaporating a solvent by the heating and sucking roll.

A positive electrode active material for a nonaqueous electrolyte secondary battery includes a lithium-nickel-cobalt-zinc composite oxide powder that contains lithium (Li); nickel (Ni); cobalt (Co); element M, which is at least one element selected from the group consisting of manganese (Mn), vanadium (V), magnesium (Mg), molybdenum (Mo), niobium (Nb), silicon (Si), titanium (Ti), and aluminum (Al); and zinc (Zn). A molar element ratio (Li:Ni:Co:M) of the lithium-nickel-cobalt-zinc composite oxide powder satisfies Li:Ni:Co:M=z:(1-x-y):x:y (where 0.95≤z≤1.10, 0.05≤x≤0.35, and 0≤y≤0.10); a zinc content with respect to Li, Ni, Co, the element M, and oxygen in the lithium-nickel-cobalt-zinc composite oxide powder is greater than or equal to 0.01 mass % and less than or equal to 1.5 mass %; and at least a part of a surface of the lithium-nickel-cobalt-zinc composite oxide powder includes a zinc solid-solved region where zinc is solid-solved.

One variation of a battery unit includes: a series of anode collectors; a set of anode electrodes including anode material arranged on both side of the anode collectors; a set of anode interconnects interposed between and electrically coupling adjacent anode collectors and folded to locate the anode collectors in a boustrophedonic anode stack; a series of cathode collectors; a set of cathode electrodes including cathode material arranged on both side of the cathode collectors; a set of cathode interconnects interposed between and electrically coupling adjacent cathode collectors and folded to locate the cathode collectors in a boustrophedonic cathode stack with cathode collectors interdigitated between anode collectors in the boustrophedonic anode stack; and a set of separators arranged between the anode and cathode electrodes and transporting solvated ions between the anode and cathode electrodes.

A gradient multilayer structure for lithium batteries, a method for manufacturing thereof, and a lithium batteries comprise gradient multilayer structures. The multilayer structure has a porosity gradient with respect to adjacent layers of the multilayer structure or a solid-state ionic conductive material gradient with respect to adjacent layers of the multilayer structure.