A preparation method of a three-dimensional nanosized porous metal oxide electrode material of lithium ion battery, which soaks a dried polymer colloidal crystal microsphere template in a metal salt solution as a precursor solution for a period of time, and obtains a precursor template complex after filtration and drying; heats the precursor template complex to a certain temperature at a low heating rate and keeps the temperature, and then obtains the three-dimensional nanosized porous metal oxide electrode material of lithium ion battery after cooling to room temperature. A metal oxide electrode material is manufactured, with the three-dimensional nanosized porous metal oxide electrode material thereby improving the ionic conductivity of the negative electrode material of lithium ion battery, and shortens the diffusion path of the lithium ions during an electrochemical reaction process, and improves the rate discharge performance of lithium ion battery greatly.

A sulfur particle containing a core of elemental sulfur having homogeneously dispersed particles of a conductive carbon and branched polyethyleneimine; and a coating of branched polyethyleneimine (bPEI) encapsulating the core is provided. In the sulfur particle the dispersed particles of conductive carbon are associated with the bPEI. A cathode having an active material containing the sulfur particles and a sulfur loading of 1.0 mg S/cm.sup.2 to 10 mg/cm.sup.2 and a battery containing the cathode are also provided.

There is provided molybdenum oxide for an active material of an electricity storage device having excellent rate characteristics and structural stability. A turbostratic material 1 has a turbostratic structure composed of a plurality of nanosheets 2, where the nanosheets have the composition MoO.sub.2.

An antimony based anode material for a rechargeable battery includes nanoparticles of composition SbM.sub.xO.sub.y, where M is an element selected from the group consisting of Sn, Ni, Cu, In, Al, Ge, Pb, Bi, Fe, Co, and Ga, with 0x<2 and 0y2.5+2x. The nanoparticles form a substantially monodisperse ensemble with an average size not exceeding a value of 30 nm and by a size deviation not exceeding 15%. A method for preparing the antimony based anode material is carried out in situ in a non-aqueous solvent and starts by reacting an antimony salt and an organometallic amide reactant and oleylamine.

A cobalt oxide for a lithium secondary battery, a method of preparing the cobalt oxide; a lithium cobalt oxide for a lithium secondary battery formed from the cobalt oxide; and a lithium secondary battery having a positive electrode including the lithium cobalt oxide, the cobalt oxide having a tap density of about 2.8 g/cc to about 3.0 g/cc, and an intensity ratio of about 0.8 to about 1.2 of a second peak at 2 of about 31.31 to a first peak at 2 of about 191 in X-ray diffraction spectra, as analyzed by X-ray diffraction.

A composite material including a conducting material and an alkali metal sulfide formed integrally on the surface of the conducting material.

A method is provided for forming a metal battery electrode with a pyrolyzed coating. The method provides a metallorganic compound of metal (Me) and materials such as carbon (C), sulfur (S), nitrogen (N), oxygen (O), and combinations of the above-listed materials, expressed as Me.sub.XC.sub.YN.sub.ZS.sub.XXO.sub.YY, where Me is a metal such as tin (Sn), antimony (Sb), or lead (Pb), or a metal alloy. The method heats the metallorganic compound, and as a result of the heating, decomposes materials in the metallorganic compound. In one aspect, decomposing the materials in the metallorganic compound includes forming a chemical reaction between the Me particles and the materials. An electrode is formed of Me particles coated by the materials. In another aspect, the Me particles coated with a material such as a carbide, a nitride, a sulfide, or combinations of the above-listed materials.

A hybrid particle having a core of a hybrid composite comprising at least two elements selected from the group consisting of sulfur, selenium and tellurium and a coating of at least one self-assembling polymeric layer encapsulating the core is provided. A method for preparing the hybrid particle includes mixing an aqueous solution of a polymer with an aqueous solution of a soluble precursor of at least two elements selected from the group consisting of sulfur, selenium and tellurium to form a mixture and adding an acid to the mixture to obtain the hybrid particle. A cathode having an active material of the hybrid particles and a battery containing the cathode are also provided.

Provided is a cathode active material for a non-aqueous electrolyte secondary battery that has a uniform particle size and high packing density, and that is capable of increased battery capacity and improved coulomb efficiency. When producing a nickel composite hydroxide that is a precursor to the cathode active material by supplying an aqueous solution that includes at least a nickel salt, a neutralizing agent and a complexing agent into a reaction vessel while stirring and performing a crystallization reaction, a nickel composite hydroxide slurry is obtained while controlling the ratio of the average particle size per volume of secondary particles of nickel composite hydroxide that is generated inside the reaction vessel with respect to the average particle size per volume of secondary particles of nickel composite hydroxide that is finally obtained so as to be 0.2 to 0.6, after which, while keeping the amount of slurry constant and continuously removing only the liquid component, the crystallization reaction is continued until the average particle size per volume of secondary particles of the nickel composite hydroxide becomes 8.0 m to 50.0 m.

An antimony based anode material for a rechargeable battery includes nanoparticles of composition SbM.sub.xO.sub.y, where M is an element selected from the group consisting of Sn, Ni, Cu, In, Al, Ge, Pb, Bi, Fe, Co, and Ga, with 0x<2 and 0y2.5+2x. The nanoparticles form a substantially monodisperse ensemble with an average size not exceeding a value of 30 nm and by a size deviation not exceeding 15%. A method for preparing the antimony based anode material is carried out in situ in a non-aqueous solvent and starts by reacting an antimony salt and an organometallic amide reactant and oleylamine.