The present disclosure relates to a method of making carbon nanotube supported self-standing electrodes embedded in a polymer based battery packaging material. The present disclosure further relates to a method of continuously making carbon nanotube supported self-standing electrodes embedded in a polymer based battery packaging material. The resulting self-standing electrodes may be used in a wearable and flexible battery.

The present disclosure relates to a method of making carbon nanotube supported self-standing electrodes embedded in a polymer based battery packaging material. The present disclosure further relates to a method of continuously making carbon nanotube supported self-standing electrodes embedded in a polymer based battery packaging material. The resulting self-standing electrodes may be used in a wearable and flexible battery.

An electrode is capable of achieving both the safety of a corresponding electrochemical device and at least one of the output or the capacity retention rate. The electrode contains an electrode composite material layer, an insulating layer, and an electrode substrate. The electrode composite material layer and the insulating layer are sequentially formed on the electrode substrate, and the electrode composite material layer is coated by the insulating layer. An average value of the coverage percentage of the electrode composite material layer by the insulating layer in the electrode is 90% or more.

An energy storage device according to one aspect of the present invention is an energy storage device including a negative electrode having a negative electrode substrate and a negative active material layer stacked on the negative electrode substrate directly or via another layer, and a nonaqueous electrolyte solution, in which the negative active material layer contains graphite and a solvent-based binder, and the negative active material layer is not subjected to pressing.

An energy storage device according to one aspect of the present invention is an energy storage device including a negative electrode having a negative electrode substrate and a negative active material layer stacked on the negative electrode substrate directly or via another layer, and a nonaqueous electrolyte solution, in which the negative active material layer contains graphite and a solvent-based binder, and the negative active material layer is not subjected to pressing.

A method for manufacturing a negative electrode, including the steps of preparing a negative electrode slurry including low-expansion natural graphite, a binder polymer, a conductive material and a dispersion medium; applying the negative electrode slurry to at least one surface of a negative electrode current collector, drying the coated negative electrode slurry, to form a preliminary negative electrode having a preliminary negative electrode active material layer; and pressing the preliminary negative electrode to obtain the negative electrode having a finished negative electrode active material layer. A difference between the specific surface area of the preliminary negative electrode active material layer before pressing and that of the finished negative electrode active material layer after pressing is 0.5 m.sup.2/g to 1.0 m.sup.2/g. A negative electrode obtained by the method and a secondary battery including the negative electrode are also disclosed.

A method for manufacturing a negative electrode, including the steps of preparing a negative electrode slurry including low-expansion natural graphite, a binder polymer, a conductive material and a dispersion medium; applying the negative electrode slurry to at least one surface of a negative electrode current collector, drying the coated negative electrode slurry, to form a preliminary negative electrode having a preliminary negative electrode active material layer; and pressing the preliminary negative electrode to obtain the negative electrode having a finished negative electrode active material layer. A difference between the specific surface area of the preliminary negative electrode active material layer before pressing and that of the finished negative electrode active material layer after pressing is 0.5 m.sup.2/g to 1.0 m.sup.2/g. A negative electrode obtained by the method and a secondary battery including the negative electrode are also disclosed.

An immobilized selenium body, made from carbon and selenium and optionally sulfur, makes selenium more stable, requiring a higher temperature or an increase in kinetic energy for selenium to escape from the immobilized selenium body and enter a gas system, as compared to selenium alone Immobilized selenium localized in a carbon skeleton can be utilized in a rechargeable battery Immobilization of the selenium can impart compression stress on both the carbon skeleton and the selenium. Such compression stress enhances the electrical conductivity in the carbon skeleton and among the selenium particles and creates an interface for electrons to be delivered and or harvested in use of the battery. A rechargeable battery made from immobilized selenium can be charged or discharged at a faster rate over conventional batteries and can demonstrate excellent cycling stability.

An immobilized selenium body, made from carbon and selenium and optionally sulfur, makes selenium more stable, requiring a higher temperature or an increase in kinetic energy for selenium to escape from the immobilized selenium body and enter a gas system, as compared to selenium alone Immobilized selenium localized in a carbon skeleton can be utilized in a rechargeable battery Immobilization of the selenium can impart compression stress on both the carbon skeleton and the selenium. Such compression stress enhances the electrical conductivity in the carbon skeleton and among the selenium particles and creates an interface for electrons to be delivered and or harvested in use of the battery. A rechargeable battery made from immobilized selenium can be charged or discharged at a faster rate over conventional batteries and can demonstrate excellent cycling stability.

Lithium ion batteries, methods of making the same, and equipment for making the same are provided. In one implementation, a method of fabricating a pre-lithiated electrode is provided. The method comprises disposing a lithium metal target comprising a layer of lithium metal adjacent to a surface of a prefabricated electrode. The method further comprises heating at least one of the lithium metal target and the prefabricated electrode to a temperature less than or equal to 180 degrees Celsius. The method further comprises compressing the lithium metal target and the prefabricated electrode together while applying ultrasound to the lithium metal target to transfer a quantity of lithium from the lithium metal target to the prefabricated electrode.