A method for producing an electrode comprising a porous garnet-type ion-conducting oxide sintered body with high ion conductivity, the electrode, and an electrode-electrolyte layer assembly comprising the electrode and an electrolyte layer comprising a dense garnet-type ion-conducting oxide sintered body with high ion conductivity. Disclosed is a method for producing an electrode, the method comprising: preparing crystal particles of a garnet-type ion-conducting oxide; preparing a lithium-containing flux; preparing the electrode active material; preparing an electrolyte material by mixing the crystal particles of the garnet-type ion-conducting oxide and the flux; and sintering the electrolyte material and the electrode active material by heating at a temperature of 650° C. or less, wherein a number average particle diameter of the flux is larger than a number average particle diameter of the crystal particles of the garnet-type ion-conducting oxide.

The epsilon polymorph of vanadyl phosphate, ε-VOPO.sub.4, made from the solvothermally synthesized H.sub.2VOPO.sub.4, is a high density cathode material for lithium-ion batteries optimized to reversibly intercalate two Li-ions to reach the full theoretical capacity at least 50 cycles with a coulombic efficiency of 98%. This material adopts a stable 3D tunnel structure and can extract two Li-ions per vanadium ion, giving a theoretical capacity of 305 mAh/g, with an upper charge/discharge plateau at around 4.0 V, and one lower at around 2.5 V.

The epsilon polymorph of vanadyl phosphate, ε-VOPO.sub.4, made from the solvothermally synthesized H.sub.2VOPO.sub.4, is a high density cathode material for lithium-ion batteries optimized to reversibly intercalate two Li-ions to reach the full theoretical capacity at least 50 cycles with a coulombic efficiency of 98%. This material adopts a stable 3D tunnel structure and can extract two Li-ions per vanadium ion, giving a theoretical capacity of 305 mAh/g, with an upper charge/discharge plateau at around 4.0 V, and one lower at around 2.5 V.

A method of producing a positive electrode material for lithium-ion secondary batteries, which includes a pyrolyzed carbon coating, the method including a heat treatment step of thermally decomposing an organic compound using a rotary kiln to form a pyrolyzed carbon coating, wherein the organic compound is a carbon source that forms the pyrolyzed carbon coating of a positive electrode material.

A system and method for a rechargeable electrical device includes an anode, a cathode, an electrolyte located between the anode and the cathode, and a housing retaining the anode, cathode and electrode, wherein the cathode comprises a molybdenum sulphide compound.

In one aspect, a method of producing a sulfur-infused carbonaceous material as a cathode material for use in a Li—S battery is described, including providing a carbonaceous material; mixing elemental sulfur with the carbonaceous material; and heating the mixed sulfur and the carbonaceous material at a temperature from about 445° C. to about 1000° C. for a period of time and under a pressure greater than 1 atm to generate a sulfur vapor to infuse the carbonaceous material to result in a sulfur-infused carbonaceous material. In another aspect, a reactor for producing a sulfur-infused carbonaceous material as a cathode material for use in a Li—S battery is described, including a reactor body capable of withstanding a pressure from about 1 atm to about 150 atm; and an inner sulfur-resistant layer at the inner surface of the reactor, wherein the inner layer is inert to sulfur vapor at a temperature from about 450° C. to about 1000° C.

In one aspect, a method of producing a sulfur-infused carbonaceous material as a cathode material for use in a Li—S battery is described, including providing a carbonaceous material; mixing elemental sulfur with the carbonaceous material; and heating the mixed sulfur and the carbonaceous material at a temperature from about 445° C. to about 1000° C. for a period of time and under a pressure greater than 1 atm to generate a sulfur vapor to infuse the carbonaceous material to result in a sulfur-infused carbonaceous material. In another aspect, a reactor for producing a sulfur-infused carbonaceous material as a cathode material for use in a Li—S battery is described, including a reactor body capable of withstanding a pressure from about 1 atm to about 150 atm; and an inner sulfur-resistant layer at the inner surface of the reactor, wherein the inner layer is inert to sulfur vapor at a temperature from about 450° C. to about 1000° C.

A method for producing at least one electrochemical cell of a solid-state battery, comprising a mixed-conducting anode, a mixed-conducting cathode, and an interposed electrolyte, is characterized in that a mixed-conducting anode and a mixed-conducting cathode are initially produced or provided. The surface of at least one of the two electrodes is modified by way of an additional method step in such a way that the electronic conductivity perpendicular to the cell is reduced to less than 10.sup.−8 S/cm in a layer of the electrode near the surface. The anode and cathode are then assembled to form a solid-state battery in such a way that the surface-modified layer of at least one electrode is disposed as an electrolyte layer between the anode and cathode, and the mixed-conducting electrodes are thereby electronically separated.

Provided is a method for manufacturing a base material powder having a carbon nanocoating layer, the method including adding a polycyclic aromatic hydrocarbon to a base material powder, heating the mixture to a temperature that is higher than or equal to the boiling point of the polycyclic aromatic hydrocarbon and is lower than or equal to the relevant boiling point temperature +300° C., and that is higher than or equal to the thermal decomposition temperature of the polycyclic aromatic hydrocarbon, and thereby coating the surface of the base material powder with a layer of carbon having a thickness of 0.1 nm to 10 nm. According to the method, when a source of carbon that covers a base material powder is appropriately selected, the base material powder having the carbon nanocoating layer can be provided, which does not have a possibility of causing inconveniences in the applications of a final manufactured product of the base material powder and exhibits satisfactory productivity of the base material powder, and from which a modified final manufactured product is obtained.

The present disclosure relates to a lithium sulfur battery comprising a negative electrode and a positive electrode disposed opposite to each other, a separator positioned between the negative electrode and the positive electrode, and a gel polymer electrolyte positioned between the separator and the positive electrode, wherein the gel polymer electrolyte comprises LiNO.sub.3.

The present disclosure relates to a lithium sulfur battery preventing degeneration caused by a shuttle effect, and the lithium sulfur battery comprises a gel polymer electrolyte configured to inhibit a transfer of a polysulfide-based material to a negative electrode so as to prevent a loss of the polysulfide formed on a positive electrode surface during charge and discharge reactions, whereby, lifespan characteristics of the lithium sulfur battery are capable of being enhanced.