A process is provided comprising submerging a substrate in an electrochemical deposit bath having at least a metal salt and saccharin. In embodiments, the film is further treated with anodization, and in other cases chemical vapor deposition. Films are also provided formed by the disclosed processes. The films are nanoporous on at least a portion of a surface of the films. Also disclosed are electronic devices having the films disclosed, including lithium-ion batteries, storage devices, supercapacitors, electrodes, semiconductors, fuel cells, and/or combinations thereof.

An object of the present invention is to provide a lithium-ion secondary battery having a large charge and discharge capacity and excellent cycle characteristics irrespective of kind and shape of a current collector. The lithium-ion secondary battery comprises an electrode comprising a primer layer for protecting a current collector and a crosslinking agent layer comprising a compound being capable of crosslinking an aqueous binder contained in the primer layer, the both layers being disposed between a current collector and an active material layer comprising a sulfur-based active material.

An ultra-fast charging, high-capacity composite material for use with anodes in lithium-ion batteries including a phosphorene layer on a carbon-based negative electrode material. The carbon-based negative electrode material may be activated carbon, graphene, carbon nanotubes, or combinations thereof. The phosphorene layer includes a base layer of black phosphorus upon which is deposited activated carbon having a disclosed range of particle size and surface area. In a second embodiment, the negative electrode material is a composite of activated carbon and black carbon and includes a negative electrode current collector of copper foil. A slurry is made from a carbon-based conductive agent and a binder, and applied to both sides of the copper foil, then heated and compacted with a rolling machine. The anodes thus produced are used in making lithium-ion batteries, capacitors, etc.

The present disclosure relates to a stretchable electrode, a method for preparing the same and a stretchable battery including the stretchable electrode. The stretchable electrode of the present disclosure, which is prepared by crosslinking a hydroxyl-functionalized fluorine-based polymer binder physically using a ketone-based solvent or chemically with a crosslinking agent, has superior stretchability, has improved interfacial adhesivity to an active material through Fenton's oxidation, exhibits improved stability under various mechanical deformations of the electrode such as stretching, etc. and can uniformly maintain the electrical conductivity, battery capacity and charge-discharge performance of the electrode.

In addition, the stretchable battery of the present disclosure, which includes the stretchable electrode, a stretchable current collector, a stretchable separator and a stretchable encapsulant, has improved stretchability and superior battery stability under various deformations due to high degree of freedom of structures and materials. In addition, the stretchable battery of the present disclosure can be prepared as a fiber battery by printing an electrode and a current collector sequentially on both sides of a stretchable fabric, which can be worn, e.g., around sleeves due to superior stretchability and high structural degree of freedom and retains high battery performance and mechanical stability even under mechanical deformation. Therefore, it can be applied to a mobile display for a health monitoring system or a smartwatch.

A system and method for implementing and manufacturing a hierarchy system for use with a TMCCC-containing electrically-conductive structure (e.g., an electrode) as well as methods for use and manufacturing of such structures and electrochemical cells including these devices. Structures and methods include a coordination complex having L.sub.xM.sub.yN.sub.zTi.sub.a1V.sub.a2Cr.sub.a3Mn.sub.a4Fe.sub.a5Co.sub.a6Ni.sub.a7Cu.sub.a8Zn.sub.a9Ca.sub.a10Mg.sub.a11[R(CN).sub.6].sub.b (H.sub.2O).sub.c. The method includes binding electrochemically active material to produce a hierarchical structure, the hierarchical structure having a plurality of primary crystallites having a size D1, the plurality of these primary crystallites agglomerated into a set of agglomerates each agglomerate having a size D2>D1.

An electrode material, its manufacturing method, and its use as a cathode material in batteries are provided. The electrode material comprises a plurality of nanoparticles, each having a diameter of approximately 100-400 nm and comprising a core and a shell encapsulating the core. The shell comprises carbon and nitrogen, respectively having a mass fraction of approximately 70-90% and approximately 5-20% relative to a total mass of the shell. The core comprises sulfur, having a mass fraction of approximately 40-97% relative to a total mass of the core. The core has a mass fraction of approximately 50-90% relative to a total mass of each nanoparticle. The electrode material can be used in a cathode of a Li—S battery, which has a good energy storage capacity, a high electrochemical stability, and a low capacity decay.

A positive electrode active material includes a lithium-transition metal composite phosphate including a first crystalline phase having a composition represented by Formula 1 and having an olivine structure, and a second crystalline phase having a composition represented by Formula 2 and having a pyrophosphate-containing structure, wherein the second crystalline phase is in an amount of greater than 0 mole percent and not greater than 50 mole percent with respect to a total number of moles of the first crystalline phase and the second crystalline phase, a positive electrode, a secondary battery:

Li.sub.xM1.sub.yPO.sub.4   Formula 1

Li.sub.aM2.sub.b(P.sub.2O.sub.7).sub.4   Formula 2 In Formulas 1 and 2, 0.9≤x≤1.1, 0.9≤y≤1.1, 5.5≤a≤6.5, and 4.8≤b≤5.2, and M1 and M2 are each independently an element from Groups 3 to 11 in the 4th period of the Periodic Table of the Elements, or a combination thereof.

An immobilized selenium body, made from carbon and selenium and optionally sulfur, makes selenium more stable, requiring a higher temperature or an increase in kinetic energy for selenium to escape from the immobilized selenium body and enter a gas system, as compared to selenium alone Immobilized selenium localized in a carbon skeleton can be utilized in a rechargeable battery Immobilization of the selenium can impart compression stress on both the carbon skeleton and the selenium. Such compression stress enhances the electrical conductivity in the carbon skeleton and among the selenium particles and creates an interface for electrons to be delivered and or harvested in use of the battery. A rechargeable battery made from immobilized selenium can be charged or discharged at a faster rate over conventional batteries and can demonstrate excellent cycling stability.

An immobilized selenium body, made from carbon and selenium and optionally sulfur, makes selenium more stable, requiring a higher temperature or an increase in kinetic energy for selenium to escape from the immobilized selenium body and enter a gas system, as compared to selenium alone Immobilized selenium localized in a carbon skeleton can be utilized in a rechargeable battery Immobilization of the selenium can impart compression stress on both the carbon skeleton and the selenium. Such compression stress enhances the electrical conductivity in the carbon skeleton and among the selenium particles and creates an interface for electrons to be delivered and or harvested in use of the battery. A rechargeable battery made from immobilized selenium can be charged or discharged at a faster rate over conventional batteries and can demonstrate excellent cycling stability.

A composite material includes vanadium lithium phosphate, and a conductive carbon. an amount of the conductive carbon is 2.5 mass % or more and 7.5 mass % or less.