A prussian blue analog having a core-shell structure, which has a core and a cladding layer that dads the core, wherein

the chemical formula of the core is the following Formula 1,

Na.sub.xP[R(CN).sub.6].sub.δ.zH.sub.2O and the chemical formula of the cladding layer is the following Formula 2, A.sub.yL[M(CN).sub.6].sub.α.wH.sub.2O is described. The prussian blue analog has good storage stability, and thus can greatly reduce the manufacturing cost at the subsequent battery cell level. A method for preparing the prussian blue analog having a core-shell structure, as well as a sodium-ion secondary battery, a battery module, a battery pack and a powered device comprising the same are described.

A prussian blue analog having a core-shell structure, which has a core and a cladding layer that dads the core, wherein

the chemical formula of the core is the following Formula 1,

Na.sub.xP[R(CN).sub.6].sub.δ.zH.sub.2O and the chemical formula of the cladding layer is the following Formula 2, A.sub.yL[M(CN).sub.6].sub.α.wH.sub.2O is described. The prussian blue analog has good storage stability, and thus can greatly reduce the manufacturing cost at the subsequent battery cell level. A method for preparing the prussian blue analog having a core-shell structure, as well as a sodium-ion secondary battery, a battery module, a battery pack and a powered device comprising the same are described.

A lithium-sulfur battery cathode including conductive porous carbon particles vacuum infused with sulfur and a conductive collector substrate to which the sulfur infused porous carbon particles are deposited. The sulfur infused carbon particles are encapsulated by an encapsulation polymer, the encapsulation polymer having ionic conductivity, electronic conductivity, polysulfide affinity, or combinations thereof. A lithium-sulfur battery including the lithium-sulfur battery cathode, a lithium anode and an electrolyte disposed between the sulfur cathode and the lithium anode is also provided. Methods of producing the sulfur cathode for use in a lithium-sulfur battery by a hybrid vacuum-and-melt method are also provided.

A method of forming a sulfur-based cathode material includes: 1) providing a sulfur-based nanostructure; 2) coating the nanostructure with an encapsulating material to form a shell surrounding the nanostructure; and 3) removing a portion of the nanostructure through the shell to form a void within the shell, with a remaining portion of the nanostructure disposed within the shell.

A method of forming a crystalline cathode layer of a solid-state battery on a substrate, the method including generating a plasma remote from one or more sputter targets for forming the cathode layer, generating sputtered material from the target or targets using the plasma, and depositing the sputtered material on the substrate, thereby forming the crystalline cathode layer.

A method of forming a crystalline cathode layer of a solid-state battery on a substrate, the method including generating a plasma remote from one or more sputter targets for forming the cathode layer, generating sputtered material from the target or targets using the plasma, and depositing the sputtered material on the substrate, thereby forming the crystalline cathode layer.

A preparation method of fluorocarbon-coated VSe.sub.2 composite (VSe.sub.2@CF) anode electrode material, including: weighting and dissolving an acetylacetone oxovanadium (VO(acac).sub.2) and a selenium dioxide in a solvent to prepare a first solution with a concentration of 0.5-2 mol/L, and stirring the first solution for 0.5 h to obtain a dark green solution; adding the dark green solution with an organic acid to obtain a second solution; transferring the second solution to a polytetrafluoroethylene-lined high-pressure hydrothermal reactor, and holding at a heat insulation temperature for 15-30 h to obtain a third solution; after the third solution is cooled, suction filtering the cooled third solution, and washing the filtered third solution repeatedly to obtain a precipitate; drying the precipitate to obtain a black powder; co-mixing a citric acid solution with the black powder, stirring, ball milling, and drying; and heating up, holding, and finally cooling naturally to room temperature under inert atmosphere.

Covalent organic frameworks (COFs) usually crystallize as insoluble powders and their processing for suitable devices has been thought to be limited. Here, it is demonstrated that COFs can be mechanically pressed into shaped objects having anisotropic ordering with preferred orientation between the hk0 and 00/ crystallographic planes. Pellets prepared from bulk COF powders impregnated with LiClO.sub.4 displayed room temperature conductivity up to 0.26 mS cm.sup.−1 and stability up to 10.0 V (vs. Li.sup.+/Li.sup.0). This outcome portends use of COFs as solid-state electrolytes in batteries.

Covalent organic frameworks (COFs) usually crystallize as insoluble powders and their processing for suitable devices has been thought to be limited. Here, it is demonstrated that COFs can be mechanically pressed into shaped objects having anisotropic ordering with preferred orientation between the hk0 and 00/ crystallographic planes. Pellets prepared from bulk COF powders impregnated with LiClO.sub.4 displayed room temperature conductivity up to 0.26 mS cm.sup.−1 and stability up to 10.0 V (vs. Li.sup.+/Li.sup.0). This outcome portends use of COFs as solid-state electrolytes in batteries.

The present invention relates to a double slit coating die, and an electrode active material coating apparatus comprising same, the double slit coating die comprising first to fourth blocks which are positioned sequentially adjacent to each other, and having a structure in which the positions of the first and second blocks can move in a direction tilted at an angle θ with respect to the interface between the second and third blocks. The present invention has the effects of preventing slip surfaces between blocks constituting the die from spreading apart, and reducing offset in a coating process.