The epsilon polymorph of vanadyl phosphate, ε-VOPO.sub.4, made from the solvothermally synthesized H.sub.2VOPO.sub.4, is a high density cathode material for lithium-ion batteries optimized to reversibly intercalate two Li-ions to reach the full theoretical capacity at least 50 cycles with a coulombic efficiency of 98%. This material adopts a stable 3D tunnel structure and can extract two Li-ions per vanadium ion, giving a theoretical capacity of 305 mAh/g, with an upper charge/discharge plateau at around 4.0 V, and one lower at around 2.5 V.

An electrode structure for a secondary battery includes a potential sheath capable of suppressing a side reaction between an electrode and an electrolyte through electric potential control. The electrode structure for the secondary battery uses the electric potential control so that an unstable SEI layer, which causes decrease in cycle characteristic and capacity of an anode material, occurs only on the surface of a potential sheath without occurring on the surface of the anode active material, thereby being capable of completely solving the problems of the existing nanostructured electrode. A method for manufacturing an electrode for a secondary battery includes the steps of: (a) preparing a template form; (b) coating a graphene on the template foam; (c) removing the template foam to form a graphene foam, wherein the template foam partially remains on an internal surface of the graphene foam; and (d) growing a nanowire by using the template foam remaining on the internal surface of the graphene foam as a seed.

An electrode structure for a secondary battery includes a potential sheath capable of suppressing a side reaction between an electrode and an electrolyte through electric potential control. The electrode structure for the secondary battery uses the electric potential control so that an unstable SEI layer, which causes decrease in cycle characteristic and capacity of an anode material, occurs only on the surface of a potential sheath without occurring on the surface of the anode active material, thereby being capable of completely solving the problems of the existing nanostructured electrode. A method for manufacturing an electrode for a secondary battery includes the steps of: (a) preparing a template form; (b) coating a graphene on the template foam; (c) removing the template foam to form a graphene foam, wherein the template foam partially remains on an internal surface of the graphene foam; and (d) growing a nanowire by using the template foam remaining on the internal surface of the graphene foam as a seed.

A positive electrode for a lithium-sulfur battery and a lithium-sulfur battery including the same, and in particular, a positive electrode for a lithium-sulfur battery including an active material, a conductive material, a binder and an additive, wherein the additive includes an organic acid lithium salt, the organic acid lithium salt including a dicarboxyl group. By including a dicarboxyl group-including organic acid lithium salt as the additive, the positive electrode for the lithium-sulfur battery is capable of enhancing capacity and lifetime properties of the lithium-sulfur battery through enhancing lithium ion migration properties.

A positive electrode for a lithium-sulfur battery and a lithium-sulfur battery including the same, and in particular, a positive electrode for a lithium-sulfur battery including an active material, a conductive material, a binder and an additive, wherein the additive includes an organic acid lithium salt, the organic acid lithium salt including a dicarboxyl group. By including a dicarboxyl group-including organic acid lithium salt as the additive, the positive electrode for the lithium-sulfur battery is capable of enhancing capacity and lifetime properties of the lithium-sulfur battery through enhancing lithium ion migration properties.

A silicon-based negative electrode material containing a silicate skeleton, a negative electrode plate and a lithium battery. The silicon-based negative electrode material comprises a modified silicon monoxide material having a dispersedly distributed silicate material inside same. The general formula of the modified silicon monoxide material is MxSiOy, with 1<x<6, 3<y<6, element M comprising one or more of Mg, Ni, Cu, Zn, Al, Na, Ca, K, Li, Fe and Co, and the grain size being 0.5-100 nm. In the modified silicon monoxide material, the content of the silicate material is 5-60% of the total mass of the modified silicon monoxide material. The dispersedly distributed silicate material forms a skeleton structure of the silicon-based negative electrode material, does not undergo a physicochemical reaction along with the lithium removal and lithium intercalation of the silicon-based negative electrode material in the cycle process, and maintains the original structure thereof after multiple cycles.

The present technology relates to self-standing electrodes, their use in electrochemical cells, and their production processes using a water-based filtration process. For example, the self-standing electrodes may be used in lithium-ion batteries (LIBs). Particularly, the self-standing electrodes comprise a first electronically conductive material serving as a current collector, the surface of the first electronically conductive material being grafted with a hydrophilic group, a binder comprising cellulose fibres, an electrochemically active material, and optionally a second electronically conductive material. A process for the preparation of the self-standing electrodes is also described.

The present technology relates to self-standing electrodes, their use in electrochemical cells, and their production processes using a water-based filtration process. For example, the self-standing electrodes may be used in lithium-ion batteries (LIBs). Particularly, the self-standing electrodes comprise a first electronically conductive material serving as a current collector, the surface of the first electronically conductive material being grafted with a hydrophilic group, a binder comprising cellulose fibres, an electrochemically active material, and optionally a second electronically conductive material. A process for the preparation of the self-standing electrodes is also described.

Presented here are nanocomposites and electrochemical storage systems (e.g., rechargeable batteries and supercapacitors), which are resistant to thermal runaway and are safe, reliable, and stable electrode materials for electrochemical storage systems (e.g., rechargeable batteries and supercapacitors) operated at high temperature and high pressure, and methods of making the same.

Presented here are nanocomposites and electrochemical storage systems (e.g., rechargeable batteries and supercapacitors), which are resistant to thermal runaway and are safe, reliable, and stable electrode materials for electrochemical storage systems (e.g., rechargeable batteries and supercapacitors) operated at high temperature and high pressure, and methods of making the same.