A silicon-based negative electrode active material, a method for preparing the silicon-based negative electrode active material, and a secondary battery including a negative electrode that includes the silicon-based negative electrode active material. The silicon-based negative electrode active material includes a silicate. The silicate contains an alkaline earth metal element, and the silicon-based negative electrode active material contains both the element K and the element Fe.

A positive electrode active material for a lithium secondary battery, which can improve the performance of the battery by mixing various carbons with positive electrode active material and applying it, and a preparation method thereof and a lithium secondary battery including the same. The positive electrode active material for the lithium secondary battery includes two or more types of active material composites in which sulfur is supported on the carbon materials contained therein, wherein the carbon materials contained in any one of the two or more types of active material composites differ in at least one of the average particle size and shape from the carbon materials contained in another type of active material composites.

A positive electrode active material for a lithium secondary battery, which can improve the performance of the battery by mixing various carbons with positive electrode active material and applying it, and a preparation method thereof and a lithium secondary battery including the same. The positive electrode active material for the lithium secondary battery includes two or more types of active material composites in which sulfur is supported on the carbon materials contained therein, wherein the carbon materials contained in any one of the two or more types of active material composites differ in at least one of the average particle size and shape from the carbon materials contained in another type of active material composites.

A method of making an electrode includes the step of mixing active material particles, radiation curable resin precursors, and electrically conductive particles to create an electrode precursor mixture. The electrode precursor mixture is electrostatically sprayed onto a current collector to provide an electrode preform. The electrode preform is heated and calendered to melt the resin precursor such that the resin precursor surrounds the active particles and electrically conductive particles. Radiation is applied to the electrode preform sufficient to cure the radiation curable resin precursors into resin.

A method of making an electrode includes the step of mixing active material particles, radiation curable resin precursors, and electrically conductive particles to create an electrode precursor mixture. The electrode precursor mixture is electrostatically sprayed onto a current collector to provide an electrode preform. The electrode preform is heated and calendered to melt the resin precursor such that the resin precursor surrounds the active particles and electrically conductive particles. Radiation is applied to the electrode preform sufficient to cure the radiation curable resin precursors into resin.

A method of preparing a slurry composition for a secondary battery positive electrode includes preparing a positive electrode active material pre-dispersion by mixing a lithium iron phosphate-based positive electrode active material, a dispersant, and a solvent, and preparing a slurry for a positive electrode by further mixing a conductive agent, a binder, and an additional solvent with the positive electrode active material pre-dispersion is provided. A positive electrode for a secondary battery which is prepared by using the same method, and a lithium secondary battery including the positive electrode are also provided.

A composite sulfide electrode and a manufacturing method therefor are disclosed. A method for manufacturing a composite sulfide electrode comprises the steps of: preparing a mixed solution of polyacrylonitrile (PAN) and a metallic oxide; stirring the prepared mixed solution; electrospinning the stirred mixed solution to prepare a wire-type precursor bearing a metallic oxide in PAN; drying the prepared wire-type precursor; mixing the dried wire-type precursor and a sulfur powder; and injecting a gas to the mixture of the wire-type precursor and the sulfur powder to sulfurize the wire-type precursor.

A composite sulfide electrode and a manufacturing method therefor are disclosed. A method for manufacturing a composite sulfide electrode comprises the steps of: preparing a mixed solution of polyacrylonitrile (PAN) and a metallic oxide; stirring the prepared mixed solution; electrospinning the stirred mixed solution to prepare a wire-type precursor bearing a metallic oxide in PAN; drying the prepared wire-type precursor; mixing the dried wire-type precursor and a sulfur powder; and injecting a gas to the mixture of the wire-type precursor and the sulfur powder to sulfurize the wire-type precursor.

A method of electroplating (or electrodeposition) carbon to coat anode and cathode active materials used in Li-ion batteries (LIBs) for improving their cycle life. The electroplating of the carbon coating from the carbon source is ultrafast, preferably taking less than 10 seconds. The carbon source can be comprised of an acetonitrile, methanol, ethanol, acetonitrile, nitromethane, nitroethane or N,N-dimethylformamide (DMF) solution. The protective carbon coating may be used also in gas sensors, biological cell sensors, supercapacitors, catalysts for fuel cells and metal air batteries, nano and optoelectronic devices, filtration devices, structural components, and energy storage devices.

A lithium-sulfur accumulator comprising at least one electrochemical cell comprising a positive electrode comprising, as active material, at least one sulfur-containing material, a negative electrode and an electrolyte conducting lithium ions disposed between the negative electrode and the positive electrode, wherein the negative electrode comprises, as active material, a lithium and calcium alloy, wherein the calcium is present in the alloy to the extent of 2% to 34% atomic.