The invention relates to a cathode composition usable in a lithium-ion battery, to a process for the preparation of this composition, to such a cathode and to a lithium-ion battery incorporating this cathode.

The composition comprises an active material which comprises an alloy of lithium nickel cobalt aluminum oxides, an electrically conductive filler and a polymeric binder, and it is such that said polymeric binder comprises at least one modified polymer (Id2) which is the product of a thermal oxidation reaction of a starting polymer and which incorporates oxygenated groups comprising CO groups, the composition being capable of being obtained by the molten route and without evaporation of solvent by being the product of said thermal oxidation reaction applied to a precursor mixture comprising said active material, said electrically conductive filler, said starting polymer and a sacrificial polymer phase.

Disclosed is an electrode active material that has a large charge discharge capacity, a high initial efficiency, as well as excellent cycle characteristics and rate characteristics and is favorably used in a non-aqueous electrolyte secondary battery. An organo sulfur-based electrode active material contains sodium and potassium in a total amount of 100 ppm by mass to 1000 ppm by mass; an electrode for use in a secondary battery, the electrode containing the organo sulfur-based electrode active material as an electrode active material; and a non-aqueous electrolyte secondary battery including the electrode. Preferably, the organo sulfur-based electrode active material further contains iron in an amount of 1 ppm by mass to 20 ppm by mass. Preferably, the organo sulfur-based electrode active material is sulfur-modified polyacrylonitrile, and the amount of sulfur in the organo sulfur-based electrode active material is 25 mass % to 60 mass %.

Improved anodes and cells are provided, which enable fast charging rates with enhanced safety due to much reduced probability of metallization of lithium on the anode, preventing dendrite growth and related risks of fire or explosion. Anodes and/or electrolytes have buffering zones for partly reducing and gradually introducing lithium ions into the anode for lithiation, to prevent lithium ion accumulation at the anode electrolyte interface and consequent metallization and dendrite growth. Various anode active materials and combinations, modifications through nanoparticles and a range of coatings which implement the improved anodes are provided.

Improved anodes and cells are provided, which enable fast charging rates with enhanced safety due to much reduced probability of metallization of lithium on the anode, preventing dendrite growth and related risks of fire or explosion. Anodes and/or electrolytes have buffering zones for partly reducing and gradually introducing lithium ions into the anode for lithiation, to prevent lithium ion accumulation at the anode electrolyte interface and consequent metallization and dendrite growth. Various anode active materials and combinations, modifications through nanoparticles and a range of coatings which implement the improved anodes are provided.

An interfacial additive layer for decreasing the interfacial resistance/impedance of a silicon based electrode-containing device such as, for example, an energy storage device or a micro-resistor, is disclosed. The interfacial additive layer, which is composed of a molten lithium containing salt, is formed between a silicon based electrode and a solid polymer electrolyte layer of the device. The presence of such an interfacial additive layer increases the ion and electron mobile dependent performances at the silicon based electrode interface due to significant decrease in the resistance/impedance that is observed at the respective interface as well as the impedance observed in the bulk of the device.

An interfacial additive layer for decreasing the interfacial resistance/impedance of a silicon based electrode-containing device such as, for example, an energy storage device or a micro-resistor, is disclosed. The interfacial additive layer, which is composed of a molten lithium containing salt, is formed between a silicon based electrode and a solid polymer electrolyte layer of the device. The presence of such an interfacial additive layer increases the ion and electron mobile dependent performances at the silicon based electrode interface due to significant decrease in the resistance/impedance that is observed at the respective interface as well as the impedance observed in the bulk of the device.

A negative electrode for a lithium-metal secondary battery and a lithium-metal secondary battery including the same are provided which have an excellent life characteristic and have less irregular resin phases formed on the surface the negative electrode. The negative electrode includes a polymer layer arranged in a lattice structure having vacant spaces, so that the specific surface area of the negative electrode can be increased, a uniform current density distribution can thereby be achieved, the negative electrode has excellent life characteristics, and the formation of irregular resin phases can be suppressed.

A negative electrode for a lithium-metal secondary battery and a lithium-metal secondary battery including the same are provided which have an excellent life characteristic and have less irregular resin phases formed on the surface the negative electrode. The negative electrode includes a polymer layer arranged in a lattice structure having vacant spaces, so that the specific surface area of the negative electrode can be increased, a uniform current density distribution can thereby be achieved, the negative electrode has excellent life characteristics, and the formation of irregular resin phases can be suppressed.

An embodiment of the present disclosure provides an ion battery electrode material that significantly improves scan rate, capacity exhibiting, safety, and energy density compared to conventional ion batteries by manufacturing bulk POM in a layered structure in which bulk POM is uniformly distributed in several nanometers on the surface of rGO/PPy, and a method for synthesizing ion battery electrode materials.

An embodiment of the present disclosure provides an ion battery electrode material that significantly improves scan rate, capacity exhibiting, safety, and energy density compared to conventional ion batteries by manufacturing bulk POM in a layered structure in which bulk POM is uniformly distributed in several nanometers on the surface of rGO/PPy, and a method for synthesizing ion battery electrode materials.