A negative electrode composition includes a silicon containing material and a crosslinked polymer containing coating surrounding at least a portion of the silicon containing material. The crosslinked polymer containing coating comprises a (co)polymer derived from polymerization of one or more vinylic monomers comprising a carboxyl or carboxylate group.

A method for the preparation of an electrode comprising a substrate made of an aluminium based material, vertically aligned carbon nanotubes and an electrically conductive polymer matrix, the method comprising the following successive steps: (a) synthesising, on a substrate made of an aluminium based material, a carpet of vertically aligned carbon nanotubes according to the technique of CVD (Chemical Vapour Deposition) at a temperature less than or equal to 650 C.; (b) electrochemically depositing the polymer matrix on the carbon nanotubes from an electrolyte solution including at least one precursor monomer of the matrix, at least one ionic liquid and at least one protic or aprotic solvent. Further disclosed is the prepared electrode and a device for storing and returning electricity such as a supercapacitor comprising the electrode.

This application describes an electrode material comprising an indigoid compound, i.e. indigo blue or a derivative thereof, for instance, together with particles of an electrochemically active material dispersed in a binder. Processes for the preparation of the electrode material and electrodes containing the material, as well as to the electrochemical cells and their use are also contemplated.

The present disclosure provides a composite material comprising an electrically conductive polymer, such as poly(3,4-ethylenedioxythiophene) (PEDOT) and an ionically conductive polymer, such as poly(ethylene oxide) (PEO). This composite forms a dual conductor for three-dimensional electrodes in electrochemical applications including lithium ion batteries.

An electrochemical device includes a positive electrode, a negative electrode, and a separator disposed between the positive electrode and the negative electrode. The positive electrode includes a positive current collector, a carbon layer, and an active layer. The carbon layer is disposed on the positive current collector and includes a conductive carbon material. The active layer is disposed on the carbon layer and includes a conductive polymer. The carbon layer includes a polyolefin resin. The positive current collector preferably includes aluminum.

An electrochemical device includes a positive electrode, a negative electrode, and a separator disposed between the positive electrode and the negative electrode. The positive electrode includes a positive current collector, a carbon layer, and an active layer. The carbon layer is disposed on the positive current collector and includes a conductive carbon material. The active layer is disposed on the carbon layer and includes a conductive polymer. The carbon layer includes a polyolefin resin. The positive current collector preferably includes aluminum.

An improved rechargeable battery may utilize materials that are entirely solid-state. The battery may utilize at least one organic active material for an electrode. The battery may utilize a cathode that comprises quinone(s). An electrolyte of the battery may be an ion-conducting inorganic compound. An anode of the battery may comprise an alkali metal. Further, a carbonyl group of the quinone(s) of the cathode may be reduced into a phenolate and coordinated to an alkali metal ion during discharge and vice versa during charging.

A negative electrode composition includes a silicon containing material and a crosslinked polymer containing coating surrounding at least a portion of the silicon containing material. The crosslinked polymer containing coating comprises a (co)polymer derived from polymerization of one or more vinylic monomers comprising a carboxyl or carboxylate group.

A negative electrode composition includes a silicon containing material and a crosslinked polymer containing coating surrounding at least a portion of the silicon containing material. The crosslinked polymer containing coating comprises a (co)polymer derived from polymerization of one or more vinylic monomers comprising a carboxyl or carboxylate group.

A positive electrode for electrochemical device includes a positive current collector and a positive electrode material layer supported on the positive current collector. The positive electrode material layer includes a positive electrode active material. The positive electrode active material includes an inner core portion containing polyaniline and a surface layer portion containing poly(3,4-ethylenedioxythiophene) and polythiophene. The inner core portion is fibrous or grain-aggregate, and the surface layer portion covers at least a part of the inner core portion. Furthermore, an electrochemical device includes the above-described positive electrode, a negative electrode including a negative electrode material layer that occludes and releases a lithium ion, and a nonaqueous electrolytic solution having lithium ion conductivity.