Briefly, a carbon working electrode is described that has a plastic substrate of polyethylene, polypropylene, polystyrene, polyvinyl chloride, or polylactic acid, and may be formed into an elongated wire. The carbon material coats the plastic substrate, and may be, for example, graphene, diamagnetic graphite, pyrolytic graphite, pyrolytic carbon, carbon black, carbon paste, or carbon ink, which is aqueously dispersed in an elastomeric material such as polyurethane, silicone, acrylates or acrylics. Optionally, selected additives may be added to the carbon compound prior to it being layered onto the plastic substrate. These additives may, for example, improve electrical conductivity or sensitivity, or act as a catalyst for target analyte molecules.

A positive electrode includes: a carbonaceous core; a coating layer including an electrolyte-philic organic compound on the carbonaceous core; a lithium salt; and an electrolyte, wherein the organic compound includes an imide functional group.

A positive electrode includes: a carbonaceous core; a coating layer including an electrolyte-philic organic compound on the carbonaceous core; a lithium salt; and an electrolyte, wherein the organic compound includes an imide functional group.

An electrode material useful as a dry in place deposit comprising at least one metal chelating polymer; an active material capable of reversibly intercalating lithium ions; a plurality of electrical conductor particles; a binder polymer. The electrode material is formed into a slurry using a non-aqueous solvent. The metal chelating polymer may be a reaction product of a polyphenolic polymer; an aldehyde, a ketone, or mixtures thereof; and an amine. The electrode material slurry is deposited on a current collector and dried to form a positive electrode in a secondary lithium ion battery. The deposited electrode material has high flexibility, adhesion to the current collector, resistance to electrolyte damage, and low electrical resistance. The electrode material forms a superior positive electrode at a relatively low additional cost and with no increase in process complexity.

A negative electrode for a lithium-metal secondary battery and a lithium-metal secondary battery including the same are provided which have an excellent life characteristic and have less irregular resin phases formed on the surface the negative electrode. The negative electrode includes a polymer layer arranged in a lattice structure having vacant spaces, so that the specific surface area of the negative electrode can be increased, a uniform current density distribution can thereby be achieved, the negative electrode has excellent life characteristics, and the formation of irregular resin phases can be suppressed.

A method of producing a powder mass for a lithium battery, comprising: (a) mixing graphene sheets and a sulfonated elastomer or its precursor in a liquid medium or solvent to form a suspension; (b) dispersing a plurality of particles of an anode active material in the suspension to form a slurry; and (c) dispensing the slurry and removing the solvent and/or polymerizing or curing the precursor to form the powder mass comprising multiple particulates, wherein at least one of the particulates is composed of one or a plurality of the particles encapsulated by a thin layer of a sulfonated elastomer/graphene composite having a thickness from 1 nm to 10 m, a fully recoverable tensile strain from 2% to 500%, a lithium ion conductivity from 10.sup.7 S/cm to 510.sup.2 S/cm and an electrical conductivity from 10.sup.7 S/cm to 100 S/cm.

A method of producing a powder mass for a lithium battery, comprising: (a) mixing graphene sheets and a sulfonated elastomer or its precursor in a liquid medium or solvent to form a suspension; (b) dispersing a plurality of particles of an anode active material in the suspension to form a slurry; and (c) dispensing the slurry and removing the solvent and/or polymerizing or curing the precursor to form the powder mass comprising multiple particulates, wherein at least one of the particulates is composed of one or a plurality of the particles encapsulated by a thin layer of a sulfonated elastomer/graphene composite having a thickness from 1 nm to 10 m, a fully recoverable tensile strain from 2% to 500%, a lithium ion conductivity from 10.sup.7 S/cm to 510.sup.2 S/cm and an electrical conductivity from 10.sup.7 S/cm to 100 S/cm.

Provided is a cathode for a sodium/sulfur (NaS) battery. The cathode includes polysodium-sulfide polyacrylonitrile (Na.sub.xS-PAN, 3?x) obtained by reaction with a large amount of sodium, and is a high-capacity electrode manufactured via sodiation to inject sodium.

A negative electrode includes a metal substrate and a polymeric single-ion conductor coating formed on a surface of the metal substrate. The metal substrate is selected from the group consisting of lithium, sodium, and zinc. The polymeric single-ion conductor coating is formed of i) a metal salt of a sulfonated tetrafluoroethylene-based fluoropolymer copolymer or ii) a polymeric metal salt having an initial polymeric backbone and pendent metal salt groups attached to the initial polymeric backbone.

A negative electrode includes a metal substrate and a polymeric single-ion conductor coating formed on a surface of the metal substrate. The metal substrate is selected from the group consisting of lithium, sodium, and zinc. The polymeric single-ion conductor coating is formed of i) a metal salt of a sulfonated tetrafluoroethylene-based fluoropolymer copolymer or ii) a polymeric metal salt having an initial polymeric backbone and pendent metal salt groups attached to the initial polymeric backbone.