Disclosed is an electrode active material that has a large charge discharge capacity, a high initial efficiency, as well as excellent cycle characteristics and rate characteristics and is favorably used in a non-aqueous electrolyte secondary battery. An organo sulfur-based electrode active material contains sodium and potassium in a total amount of 100 ppm by mass to 1000 ppm by mass; an electrode for use in a secondary battery, the electrode containing the organo sulfur-based electrode active material as an electrode active material; and a non-aqueous electrolyte secondary battery including the electrode. Preferably, the organo sulfur-based electrode active material further contains iron in an amount of 1 ppm by mass to 20 ppm by mass. Preferably, the organo sulfur-based electrode active material is sulfur-modified polyacrylonitrile, and the amount of sulfur in the organo sulfur-based electrode active material is 25 mass % to 60 mass %.

Set forth herein are electrochemical cells which include a negative electrode current collector, a lithium metal negative electrode, an oxide electrolyte membrane, a bonding agent layer, a positive electrode, and a positive electrode current collector. The bonding agent layer advantageously lowers the interfacial impedance of the oxide electrolyte at least at the positive electrode interface and also optionally acts as an adhesive between the solid electrolyte separator and the positive electrode interface. Also set forth herein are methods of making these bonding agent layers including, but not limited to, methods of preparing and depositing precursor solutions which form these bonding agent layers. Set forth herein, additionally, are methods of using these electrochemical cells.

Set forth herein are electrochemical cells which include a negative electrode current collector, a lithium metal negative electrode, an oxide electrolyte membrane, a bonding agent layer, a positive electrode, and a positive electrode current collector. The bonding agent layer advantageously lowers the interfacial impedance of the oxide electrolyte at least at the positive electrode interface and also optionally acts as an adhesive between the solid electrolyte separator and the positive electrode interface. Also set forth herein are methods of making these bonding agent layers including, but not limited to, methods of preparing and depositing precursor solutions which form these bonding agent layers. Set forth herein, additionally, are methods of using these electrochemical cells.

A battery, having polyvalent aluminum metal as the electrochemically active anode material and also including a solid ionically conducting polymer material.

A battery, having polyvalent aluminum metal as the electrochemically active anode material and also including a solid ionically conducting polymer material.

Provided is a composite solid electrolyte membrane for an all-solid-state secondary battery, including: a phase transformation layer containing a plasticizer and a lithium salt; a porous polymer sheet layer; and a solid polymer electrolyte layer, wherein the phase transformation layer, the porous polymer sheet layer and the solid polymer electrolyte layer are stacked successively, and the phase transformation layer is disposed in such a manner that it faces a negative electrode when manufacturing an electrode assembly. An all-solid-state secondary battery including the composite solid electrolyte membrane is also provided. The composite solid electrolyte membrane for an all-solid-state secondary battery reduces the interfacial resistance with an electrode, increases ion conductivity, and improves the safety of a battery.

Provided is a composite solid electrolyte membrane for an all-solid-state secondary battery, including: a phase transformation layer containing a plasticizer and a lithium salt; a porous polymer sheet layer; and a solid polymer electrolyte layer, wherein the phase transformation layer, the porous polymer sheet layer and the solid polymer electrolyte layer are stacked successively, and the phase transformation layer is disposed in such a manner that it faces a negative electrode when manufacturing an electrode assembly. An all-solid-state secondary battery including the composite solid electrolyte membrane is also provided. The composite solid electrolyte membrane for an all-solid-state secondary battery reduces the interfacial resistance with an electrode, increases ion conductivity, and improves the safety of a battery.

A process can be used to produce a charge storage unit, especially a secondary battery, the electrodes of which contain an organic redox-active polymer, and which includes a polymeric solid electrolyte. The solid electrolyte is obtained by polymerizing from mixtures of acrylates with methacrylates in the presence of at least one ionic liquid, which imparts advantageous properties to the charge storage unit.

There is provided a composite comprising a) a short chain sulfur; and b) a carbon-supported conductive polymer such as polyacrylonitrile, wherein sulfur atoms of said short chain sulfur are covalently linked to the conductive polymer of said carbon-supported conductive polymer via a C—S bond. A method of preparing said composite comprising polymerizing a plurality of monomers in the presence of a carbon scaffold, mixing elemental sulfur and heating the mixture to obtain said composite is also disclosed. An electrochemical cell comprising said composite as cathode, a sodium anode and a liquid electrolyte such as sodium trifluoromethanesulfonate dissolved in a mixture of solvents is disclosed.

The present invention provides an electrode for a non-aqueous electrolyte secondary battery, including: a current collector; and an electrode active material mixture layer containing an organosulfur electrode active material, a conductive assistant, and a binder, wherein the electrode active material mixture layer contains 0.01 mass % to 0.4 mass % of the binder with respect to a total mass of the electrode active material mixture layer, and wherein the electrode active material mixture layer is formed on the current collector.