A cathode electrode material and a lithium sulfur battery are disclosed. The cathode electrode material includes the cathode binder. The cathode binder includes a polymer obtained by polymerizing a dianhydride monomer with a diamine monomer. At least one of the dianhydride monomer and the diamine monomer includes a silicon-containing monomer. The lithium sulfur battery includes an anode electrode, an electrolyte, and the cathode electrode, the cathode electrode includes a sulfur containing cathode active material, a conducting agent, and the cathode binder.

An active material is provided. The active material comprises a porous carbon having a plurality of pores forming a three-dimensional network structure and a conductive polymer, and at least a part of the plurality of pores contains the conductive polymer.

The present invention relates an electro-active polymeric ionic liquid including imidazolium-based molecules, said imidazolium-based molecule comprising each at least: one imidazolium moiety associated with a negatively-charged counter-ion, and one reducible group selected from: Formula (IV), an anthraquinone derivative of formula (IV): with R.sub.1 representing a hydrogen atom or a C.sub.1-C.sub.6-alkyl group, a viologen group, and a metallocene reducible group such as a cobaltocene group.

Set forth herein are electrochemical cells which include a negative electrode current collector, a lithium metal negative electrode, an oxide electrolyte membrane, a bonding agent layer, a positive electrode, and a positive electrode current collector. The bonding agent layer advantageously lowers the interfacial impedance of the oxide electrolyte at least at the positive electrode interface and also optionally acts as an adhesive between the solid electrolyte separator and the positive electrode interface. Also set forth herein are methods of making these bonding agent layers including, but not limited to, methods of preparing and depositing precursor solutions which form these bonding agent layers. Set forth herein, additionally, are methods of using these electrochemical cells.

Set forth herein are electrochemical cells which include a negative electrode current collector, a lithium metal negative electrode, an oxide electrolyte membrane, a bonding agent layer, a positive electrode, and a positive electrode current collector. The bonding agent layer advantageously lowers the interfacial impedance of the oxide electrolyte at least at the positive electrode interface and also optionally acts as an adhesive between the solid electrolyte separator and the positive electrode interface. Also set forth herein are methods of making these bonding agent layers including, but not limited to, methods of preparing and depositing precursor solutions which form these bonding agent layers. Set forth herein, additionally, are methods of using these electrochemical cells.

Provided is a composite layer of graphene sheets and anode particles being dispersed in a conducting polymer network for a lithium battery anode (negative electrode), the layer comprising a mixture of a conducting polymer network, multiple graphene sheets, and multiple particles of an anode active material, wherein the anode particles have a diameter or thickness from 0.5 nm to 20 ?m and occupy from 30% to 98% by weight, the graphene sheets occupy from 0.01% to 25% by weight, and the conducting polymer network occupies from 1% to 30% by weight based on the total mixture weight and wherein the graphene sheets and the conducting polymer network together form dual conducting pathways for both electrons and lithium ions.

Provided is a composite layer of graphene sheets and anode particles being dispersed in a conducting polymer network for a lithium battery anode (negative electrode), the layer comprising a mixture of a conducting polymer network, multiple graphene sheets, and multiple particles of an anode active material, wherein the anode particles have a diameter or thickness from 0.5 nm to 20 ?m and occupy from 30% to 98% by weight, the graphene sheets occupy from 0.01% to 25% by weight, and the conducting polymer network occupies from 1% to 30% by weight based on the total mixture weight and wherein the graphene sheets and the conducting polymer network together form dual conducting pathways for both electrons and lithium ions.

Methods of making a cathode active material, including steps of: a) mixing a conductive polymer, a nitrogen containing polymer or a combination of a conductive polymer and a nitrogen-containing polymer with sulfur in the presence of a solvent to form a mixture, using a weight ratio of the conductive polymer and/or nitrogen containing polymer to the sulfur of from about 1:2 to about 1:8; and b) heating the mixture to a temperature of from about 250#C to about 400#C under a pressure of from about 0.05 bar to about 2.0 bar to form the cathode active material. A cathode active material formed by the method and cells and batteries employing the cathode active material.

The present invention concerns the use, as an active electrode material, of compounds comprising at least one entity of formula (I): in which the phenyl group is substituted with one to four identical or different substituent(s) R, chosen from a hydrogen atom, a halogen atom chosen from fluorine, chlorine, bromine or iodine, a C(S)SC+ group, an OC+ group, an SC+ group, C+ being an alkali cation chosen from Li+, Na+ and K+, a (C1-C12) alkyl radical, a (C2-C12) alkenyl radical, a (C6-C14) aryl or heteroaryl radical; or two vicinal substituents R that can, if appropriate, be linked to each other to together form a 3- to 7-membered ring optionally including another heteroatom chosen from N, O or S; in the base or salt form; and the tautomeric forms of same. It also concerns an electrode material, an electrode and a lithium, sodium or potassium secondary battery, obtained from these compounds.

The present invention concerns the use, as an active electrode material, of compounds comprising at least one entity of formula (I): in which the phenyl group is substituted with one to four identical or different substituent(s) R, chosen from a hydrogen atom, a halogen atom chosen from fluorine, chlorine, bromine or iodine, a C(S)SC+ group, an OC+ group, an SC+ group, C+ being an alkali cation chosen from Li+, Na+ and K+, a (C1-C12) alkyl radical, a (C2-C12) alkenyl radical, a (C6-C14) aryl or heteroaryl radical; or two vicinal substituents R that can, if appropriate, be linked to each other to together form a 3- to 7-membered ring optionally including another heteroatom chosen from N, O or S; in the base or salt form; and the tautomeric forms of same. It also concerns an electrode material, an electrode and a lithium, sodium or potassium secondary battery, obtained from these compounds.