An electrode for a secondary battery is disclosed herein. In some embodiments, an electrode for a secondary battery includes an electrode current collector; and an active material layer disposed on the electrode current collector, wherein the active material layer is prepared by coating an electrode slurry onto the electrode current collector, wherein the electrode slurry is an aqueous solution containing an anode active material, a conductive material, a surfactant and a binder is coated onto the electrode current collector, and wherein the binder comprises a water-soluble polymer.

High energy density and long cycle life all solid-state electrolyte lithium-ion batteries use ceramic-polymer composite anodes which include a polymer matrix with ceramic nanoparticles, silicon-based anode active materials, conducting agents, lithium salts and plasticizer distributed in the matrix. The silicon-based anode active material are anode active particles formed by high energy milling a mixture of silicon, graphite, and metallic and/or non-metallic oxides. A polymer coating is applied to the particles. The networking structure of the electrolyte establishes an effective lithium-ion transport pathway in the electrode and strengthens the contact between the electrode layer and solid-state electrolyte resulting in higher lithium-ion battery cell cycling stability and long battery life.

A lithium electrode and a lithium secondary battery including the same. The lithium electrode has a surface oxide layer with a controlled thickness and surface roughness. The lithium electrode may be used as a negative electrode of a lithium secondary battery, for example, a lithium-sulfur secondary battery. A lithium-sulfur battery including the lithium electrode has an enhanced lifetime due to suppression of side reactions with polysulfide.

The present invention relates to an anode active material for lithium secondary battery and a lithium secondary battery comprising the same. The anode active material for lithium secondary batteries comprises two kinds of crystalline carbon, with the peak intensity ratio of 3R(101) face to 2H(100) face I.sub.3R(101)/I.sub.2H(100) ranging from 0.55 to 0.7 in an X-ray diffraction pattern.

An all-solid lithium secondary battery, including: a cathode including a cathode active material layer, a solid electrolyte layer; and an anode including an anode active material layer, which forms an alloy or a compound with lithium, wherein the cathode, the solid electrolyte is between the cathode and the anode, wherein the anode active material layer includes about 33 weight percent to about 95 weight percent of an amorphous carbon with respect to the total mass of an anode active material in the anode active material layer, and a ratio of the initial charge capacity of the cathode active material layer to the initial charge capacity of the anode active material layer satisfies 0.01<b/a<0.5, wherein a is the initial charge capacity of the cathode active material layer, and b is the initial charge capacity of the anode active material layer.

In an aspect, a Li-ion cell may comprise a densified electrode exhibiting an areal capacity loading of more than about 4 mAh/cm.sup.2. For example, the densified electrode may a first electrode part arranged on a current collector and a second electrode part on top of the first electrode part, the second electrode part of the at least one densified electrode having a higher porosity than the first electrode part of the at least one densified electrode. In some designs, the densified electrode may be fabricated by densifying electrode layers via a pressure roller while maintaining a contacting part of the pressure roller at a temperature that is less than a temperature of the second electrode part. In some designs, the applied pressure is a time-varying (e.g., frequency modulated) pressure. In some designs, a drying time for a slurry to produce the densified electrode may range from around 1-120 seconds.

Rechargeable lithium battery includes a negative electrode including a negative active material layer and a negative electrode functional layer disposed on the negative active material layer; a positive electrode including a positive active material; an electrolyte solution, wherein the negative electrode functional layer includes flake-shaped polyethylene particles, the electrolyte solution includes a lithium salt and a non-aqueous organic solvent, and the non-aqueous organic solvent includes about 60 volume % to about 80 volume % of a propionate-based solvent and about 20 volume % to about 40 volume % of a carbonate-based solvent.

Composites of silicon and various porous scaffold materials, such as carbon material comprising micro-, meso- and/or macropores, and methods for manufacturing the same are provided. The compositions find utility in various applications, including electrical energy storage electrodes and devices comprising the same.

A negative electrode active material for a lead storage battery or a Pb/C battery according to an embodiment includes a porous carbon material having a plurality of pores and a lead nanoparticle formed in the pores. The material may be capable of controlling the crystal size of lead sulfate produced at a negative electrode during discharging of a lead storage battery and a Pb/C battery.

An energy storage device according to an aspect of the present invention includes: a positive electrode including a positive active material layer; a negative electrode; and a nonaqueous electrolyte, the positive active material layer includes boron and aluminum, and a maximum voltage width that is a difference between a charge upper limit voltage and a discharge lower limit voltage under normal usage is 1.1 V or less.