An anode material having 0.8≤0.06×(Dv50).sup.2−2.5×Dv50+Dv99≤12 (1); and 1.2≤0.2×Dv50−0.006×(Dv50).sup.2+BET≤5 (2), where Dv50 represents a value in the volume-based particle size distribution of the anode material that is greater than the particle size of 50% of the particles, Dv99 represents a value in the volume-based particle size distribution of the anode material that is greater than the particle size of 99% of the particles, and BET is a specific surface area of the anode material, wherein Dv50 and Dv99 are expressed in μm and BET is expressed in m.sup.2/g. The anode material is capable of significantly improving the rate performance of electrochemical devices.

Provided are a precursor solution, and a modified layer and a lithium-based battery prepared by using the same. The modified layer is formed on the negative electrode, the positive electrode and/or the separator of the lithium-based battery by using the precursor solution through photo-polymerization reaction or thermal curing. The lithium-based battery comprising the modified layer effectively promotes the charge and discharge capability, cycling life, and safety. The modified layer can be applied to a roll-to-roll process. The formation of lithium dendrites in the lithium-based battery comprising the modified layer is significantly suppressed or reduced during the charge-discharge cycles. The shuttle effect is effectively suppressed or reduced in lithium sulfur batteries and lithium iodine batteries. All the above effects are beneficial to increasing the product value of lithium ion batteries, lithium metal batteries, anode-free lithium batteries, lithium sulfur batteries, and lithium iodine batteries.

Provided is a lithium ion battery, comprising a positive electrode containing a positive electrode material layer, a negative electrode and a non-aqueous electrolyte, the layer comprises a positive electrode active material, the material comprises Li.sub.xNi.sub.yCo.sub.zM.sub.1-y-zO.sub.2, M is at least one element selected from Mn and Al, the material is doped or coated with an element E, which is selected from one or more of Ba, Zn, Ti, Mg, Zr, W, Y, Si, Sn, B, Co, and P, a potential range of the positive electrode active material with respect to lithium metal is ≥4.25V; the non-aqueous electrolyte comprises a solvent, an electrolyte salt and an additive, the additive comprises a compound represented by structural formula 1:

##STR00001## the lithium ion battery meets the following requirements:

0.1≤(H/T)×M/1000≤10; and

80≤H≤150,0.005≤T≤0.8,0.05≤M≤3.

The lithium ion battery provided by the application has a lower battery impedance and excellent high-temperature cycle performance.

A nano-silicon-graphite composite negative electrode material with carbon coating and aluminum metaphosphate composite modification layer on surface and its preparation method are disclosed, which is mainly prepared from following components by mass percentage: 4-10 wt. % of aluminum metaphosphate, 10 wt. % of asphalt cracking carbon, 15 wt. % of spherical nano-silicon powder, and 71-65 wt. % of graphite powder. A nano-silicon powder is added to deionized water for ultrasonic dispersion to obtain a uniform dispersion, then graphite powder is added to mix uniformly, and then waterborne asphalt is added. After stirring and mixing evenly, spray drying is carried out, and the dried powder is compounded with metaphosphate for mechanical fusion. Finally, the same is transferred into vacuum furnace for high-temperature carbonization to obtain the product. The composite modification layer existing on the surface can well inhibit the corrosion of the nano-silicon material by electrolytes, alleviate volume expansion, improve electrical conductivity, and increase cycle life.

The adhesion between metal foil serving as a current collector and a negative electrode active material is increased to enable long-term reliability. An electrode active material layer (including a negative electrode active material or a positive electrode active material) is formed over a base, a metal film is formed over the electrode active material layer by sputtering, and then the base and the electrode active material layer are separated at the interface therebetween; thus, an electrode is formed. The electrode active material particles in contact with the metal film are bonded by being covered with the metal film formed by the sputtering. The electrode active material is used for at least one of a pair of electrodes (a negative electrode or a positive electrode) in a lithium-ion secondary battery.

Electrolyte materials for use in electrochemical cells, electrochemical cells comprising the same, and methods of making such materials and cells, are generally described. In some embodiments, the materials, processes, and uses described herein relate to electrochemical cells comprising sulfur and lithium such as, for example, lithium sulfur batteries.

Composite carbon particles including a porous carbon material and a silicon component, the composite carbon particle having an average aspect ratio of 1.25 or less, and a ratio (I.sub.Si/I.sub.G) of a peak intensity (I.sub.Si) in the vicinity of 470 cm.sup.−1 to a peak intensity (I.sub.G) in the vicinity of 1580 cm.sup.−1 as measured by Raman spectroscopy of 0.30 or less, wherein the porous carbon material satisfies V.sub.1/V.sub.0>0.80 and V.sub.2/V.sub.0<0.10, when a total pore volume at a maximum value of a relative pressure P/P.sub.0 is defined as V.sub.0 and P.sub.0 is a saturated vapor pressure, a cumulative pore volume at a relative pressure P/P.sub.0=0.1 is defined as V.sub.1, a cumulative pore volume at a relative pressure P/P.sub.0=10.sup.−7 is defined as V.sub.2 in a nitrogen adsorption test, and has a BET specific surface area of 800 m.sup.2/g or more.

A negative active material for a rechargeable lithium battery and a rechargeable lithium battery including the same are disclosed, and the negative active material includes a primary particle of a crystalline carbon-based material and secondary particle that is an assembly of the primary particles, wherein a ratio of an average particle diameter (D50) of the secondary particle relative to an average particle diameter (D50) of the primary particle (average particle diameter (D50) of the secondary particle/average particle diameter (D50) of the primary particle) ranges from about 1.5 to about 5 and an aspect ratio of the primary particle ranges from about 1 to about 7.

An electrode material manufacturing method is a method for manufacturing an electrode material (50) of an all-solid-state battery, and the method includes: the step of preparing a coated active substance to prepare a coated active substance (10) containing a positive electrode active substance 11 and a coating layer (12) of an oxide-based solid-electrolyte that covers at least a portion of a surface thereof; the step of first compositing to manufacture a first composite material (20) by covering at least a portion of a surface of the solid electrolyte (21) with a conductive auxiliary agent (22); the step of second compositing to manufacture a second composite material (40) by covering a surface of the coated active substance (10) with the first composite material (20); and the step of mixing the second composite material (40), the conductive auxiliary agent (22), and the solid electrolyte (21) to manufacture an electrode material (50).

Articles and methods related to electrochemical cells and/or electrochemical cell components (such as electrodes) comprising species comprising a conjugated, negatively-charged ring comprising a nitrogen atom and/or reaction products of such species are generally provided. The electrochemical cell may comprise an electrode (e.g., a cathode) comprising a protective layer comprising a species comprising a conjugated, negatively-charged ring comprising a nitrogen atom and/or a reaction product thereof.