An electrochemical cell for a secondary battery, preferably for use in an electric vehicle, is provided. The cell includes a solid metallic anode, which is deposited over a suitable current collector substrate during the cell charging process. Several variations of compatible electrolyte are disclosed, along with suitable cathode materials for building the complete cell.

Provided herein are energy storage devices. In some cases, the energy storage devices are capable of being transported on a vehicle and storing a large amount of energy. An energy storage device is provided comprising at least one liquid metal electrode, an energy storage capacity of at least about 1 MWh and a response time less than or equal to about 100 milliseconds (ms).

A depositing arrangement for evaporation of a material is disclosed herein. The depositing arrangement has an alkali metal or alkaline earth metal for deposition of the material on a substrate. The deposition arrangement has a first chamber configured for liquefying the material; a valve being in fluid communication with the first chamber, and being downstream of the first chamber, wherein the valve is configured for control of the flow rate of the liquefied material through the valve. The deposition arrangement has an evaporation zone being in fluid communication with the valve, and being downstream of the valve, wherein the evaporation zone is configured for vaporizing the liquefied material; a heating unit to heat the material to higher temperatures before providing the liquid material in the evaporation zone; and one or more outlets for directing the vaporized material towards the substrate.

Presented are new, earth-abundant lithium superionic conductors, Li.sub.3Y(PS.sub.4).sub.2 and Li.sub.5PS.sub.4Cl.sub.2, that emerged from a comprehensive screening of the Li—P—S and Li-M-P—S chemical spaces. Both candidates are derived from the relatively unexplored quaternary silver thiophosphates. One key enabler of this discovery is the development of a first-of-its-kind high-throughput first principles screening approach that can exclude candidates unlikely to satisfy the stringent Li.sup.+ conductivity requirements using a minimum of computational resources. Both candidates are predicted to be synthesizable, and are electronically insulating. Systems and methods according to present principles enable new, all-solid-state rechargeable lithium-ion batteries.

The system comprises an electrode treatment unit; a temperature control treatment device (20a) connected in series to the electrode treatment unit, the temperature control treatment device (20a) comprising a temperature control vacuum treatment device (201) or a temperature control inert treatment device (202); and a lift-off unit connected in series to the temperature control treatment device (20a). Or the system comprises an atmosphere box (20b), the interior of the atmosphere box (20b) being vacuum, or an inert atmosphere and/or a protective atmosphere; and the electrode treatment unit provided inside the atmosphere box (20b), the temperature control box (9) connected in series to the electrode treatment unit, and the lift-off unit connected in series to the temperature control box (9). The electrode treatment unit comprises a first metal source unwinding shaft (1); a metal electrode unwinding shaft (2) to be supplemented and a compression roller device.

The electrolyte according to the present disclosure is an electrolyte that conducts alkali metal ions and is used for producing an energy storage device. The electrolyte includes an organic crystal layer including a layered structure, the layered structure including an organic skeletal layer including aromatic dicarboxylic acid anions having an aromatic ring structure and an alkali metal element layer including an alkali metal element to which oxygen included in carboxylic acid anions of the organic skeletal layer are coordinated to form a skeleton, and an organic solvent charged in the organic crystal layer.

In an embodiment, the present disclosure pertains to an electrolyte composition including a plurality of ether-based solvents and at least one sodium-based salt. The plurality of ether-based solvents include at least one acyclic ether and at least one cyclic ether. In a further embodiment, the present disclosure pertains to an energy storage device that includes an electrolyte composition of the present disclosure. In another embodiment, the present disclosure pertains to a method of making the electrolyte compositions of the present disclosure. Such methods generally include one or more of the following steps of mixing a plurality of ether-based solvents and at least one sodium-based salt, and forming the electrolyte composition.

Batteries are described that include a cathode material, and anode material, and a polymeric material that separates the cathode material from the anode material. The polymeric material has hydroxide ion conductivity of at least about 50 mS/cm, and a diffusion ration of hydroxide ions to at least one type of metal ion of at least about 10:1. Also described are methods of making a battery that include forming a layer of polymeric material between a first electrode and second electrode of the battery. In additional methods, the polymeric material is coated on at least one of the electrodes of the battery. In further methods, the polymeric material is admixed with at least one of the electrode materials to make a composite electrode material that is incorporated into the electrode.

A disclosed battery may include an anode, a polymeric network disposed over one or more exposed surfaces of the anode, a cathode positioned opposite to the anode, an electrolyte at least partially dispersed throughout the cathode, and a separator. The anode may include an alkali metal that can release alkali ions during operational discharge-charge cycling of the battery. The polymeric network may include carbonaceous materials grafted with fluorinated polymer chains cross-linked with each other. The fluorinated polymer chains may produce an alkali-metal containing fluoride in response to operational cycling of the battery. Formation of the alkali-metal containing fluoride may suppress alkali metal dendrite formation from the anode such that lithium is consumed to form lithium fluoride rather than forming lithium-containing dendritic structures. The separator may be positioned between the anode and the cathode.

An object is to provide a non-aqueous electrolyte secondary battery negative electrode that can suppress a deterioration in durability and improve energy density, and a non-aqueous electrolyte secondary battery including the same. A non-aqueous electrolyte secondary battery negative electrode, comprising: a collector formed of a porous metal body, and a negative electrode material disposed in pores of the porous metal body, wherein the negative electrode material comprises a negative electrode active material formed of a silicon-based material, a skeleton-forming agent comprising a silicate having a siloxane bond, a conductivity aid, and a binder.