Lithium ion batteries, methods of making the same, and equipment for making the same are provided. In one or more embodiments, an integrated processing system operable to form a pre-lithiated electrode includes a reel-to-reel system operable to transport a continuous sheet of material through processing chambers and a pre-lithiation module defining a processing region and is adapted to process the continuous sheet of material. The pre-lithiation module contains a lithium metal target operable to contact and supplying lithium to the continuous sheet of material, a press coupled with the lithium metal target and operable to move the lithium metal target into contact with the continuous sheet of material, one or more ultrasonic transducers positioned in the processing region and operable to apply ultrasonic energy to the lithium metal target, and one or more heat sources positioned in the processing region and operable to heat the lithium metal target.

Described herein are low or no-cobalt materials useful as electrode active materials in a cathode for lithium or lithium-ion batteries. For example, compositions of matter are described herein, such as electrode active materials that can be incorporated into an electrode, such as a cathode. The disclosed electrode active materials exhibit high specific energy and voltage, and can also exhibit high rate capability and/or long operational lifetime.

A solid-state battery in which a decrease in the capacity retention rate is suppressed, and a method for producing the solid-state battery are provided. A solid-state battery comprising an anode layer, a cathode layer and a solid electrolyte layer, wherein the anode layer contains an interface forming agent, and the interface forming agent contains at least one kind of elements selected from metal elements and semi-metal elements, which can become cations which conduct the solid electrolyte contained in the solid electrolyte layer, which are not involved in an electrode reaction, which have lower ionic conductivity than ions involved in the electrode reaction, and which have ionic radii of 1.34 Å or less, and wherein the solid electrolyte layer has dendritic structure in at least one of an interface with the cathode layer and an interface with the anode layer.

A battery electrode composition is provided that comprises a composite material comprising one or more nanocomposites. The nanocomposites may each comprise a planar substrate backbone having a curved geometrical structure, and an active material forming a continuous or substantially continuous film at least partially encasing the substrate backbone. To form an electrode from the electrode composition, a plurality of electrically-interconnected nanocomposites of this type may be aggregated into one or more three-dimensional agglomerations, such as substantially spherical or ellipsoidal granules.

Provided is a lithium ion battery with a positive electrode having a positive electrode mixture layer that contains a positive electrode active material, and a negative electrode having a negative electrode mixture layer that contains a negative electrode active material, the lithium ion battery being charged and discharged by the movement of lithium ions between the positive electrode and the negative electrode. The negative electrode mixture layer contains a negative electrode active material represented by general formula M.sub.3Me.sub.2X.sub.7 (in the formula, M includes at least one of La and Ca; Me includes at least one of Mn, Ni, Fe, and Co; and X includes at least one of Ge, Si, Sn, and Al), and a binding agent that contains cyano groups, the ratio of the binding agent in the negative electrode mixture layer being 0.5-7.0 mass% (inclusive).

A three-dimensional metallic foam is fabricated with an active oxide material for use as an anode for lithium batteries. The porous metal foam, which can be fabricated by a freeze-casting process, is used as the anode current collector of the lithium battery. The porous metal foam can be heat-treated to form an active oxide material to form on the surface of the metal foam. The oxide material acts as the three-dimensional active material that reacts with lithium ions during charging and discharging.

An embodiment is directed to a solid state electrolyte-comprising Li or Li-ion battery cell, comprising an anode electrode, a cathode electrode with an areal capacity loading that exceeds around 3.5 mAh/cm.sup.2, an ionically conductive separator layer that electrically separates the anode and cathode electrodes, and one or more solid electrolytes ionically coupling the anode and the cathode, wherein at least one of the one or more solid electrolytes or at least one solid electrolyte precursor of the one or more solid electrolytes is infiltrated into the solid state Li or Li-ion battery cell as a liquid.

A carbon-metal/alloy composite material includes a composition represented by (1-a)Sn.sub.1-xM.sup.1.sub.x+aM.sup.2+cC, wherein: M.sup.1 includes one or more transition metals, metals, or metalloids; M.sup.2 includes one or more transition metals, metals, or metalloids; x is 0≦x≦1; a is 0≦a≦1; and c is 0<c≦99. A method of forming the carbon-metal/alloy composite material includes the steps of dissolving one or more precursor materials in a solvent to form a solution; adding an organic carbon forming precursor to the solution to form a mixture; heating the mixture in an autoclave reactor for a prescribed period of time; separating solids formed from the mixture after the heating; washing the separated solids with a washing solvent; and heating the washed solids under a non-oxidizing atmosphere to form the carbon-metal/alloy composite material.

A porous carbon-metal/alloy composite material includes a composition represented by (1−a)Sn.sub.1-xM.sup.1.sub.x+aM.sup.2+cC, wherein: M.sup.1 includes one or more transition metals, metals, or metalloids; M.sup.2 includes one or more transition metals, metals, or metalloids; x is 0≦x≦1; a is 0≦a≦1; and c is 0<c≦99. A method of forming the porous carbon-metal/alloy composite material includes the steps of dissolving one or more metal salts and a metal salt of polysaccharide to form a mixture; subjecting the mixture to heat treatment under an inert atmosphere to form carbon-metal/alloy composite material and metal salt by-product; and washing the formed carbon-metal/alloy composite material and the metal salt by-product with washing solvent to remove the metal salt by-product and obtain the porous carbon-metal/alloy composite material.

Disclosed is an all-solid-state battery having a uniformly deposited or grown lithium layer, thereby having excellent durability.