There is provided a sealed battery having excellent corrosion resistance and sealing performance. The sealed battery 1 includes a battery jacket can 2 having a bottom and being in a cylindrical or polyhedral shape. The battery jacket can 2 also serves as a collector of one of the electrodes. The battery jacket can 2 has an opening pointing upwards and accommodates active parts (3, 4, 5 and 20). The opening is sealed by a sealing part 10 that includes a flat metal sealing plate 6, a gasket 9 made of an insulator, and a terminal part 7 of the other electrode. In the sealing part, the terminal part is attached to the sealing plate 6 using the gasket 9. The sealing plate has a planar shape that matches a shape of the opening of the battery jacket can. The sealing plate is in a saucer shape whose edge section is bent upwards. An upper end of the edge section of the sealing plate is laser-welded to an upper end of the battery jacket can while the sealing plate being inserted inside the opening of the battery jacket can. The battery jacket can is made of ferritic stainless steel to which Tin (Sn) is added.

A negative electrode for a lithium metal battery, the negative electrode including: a lithium metal electrode comprising lithium metal or a lithium metal alloy; and a protective layer on at least a portion of the lithium metal electrode, wherein the protective layer has a Young's modulus of about 10.sup.6 Pascals or greater, wherein the protective layer includes at least one first particle, wherein the first particle includes an organic particle, an inorganic particle, an organic-inorganic particle, or a combination thereof, and wherein the first particle has a particle size of greater than 1 micrometer to about 100 micrometers, and a crosslinked material comprising a polymerizable oligomer, which is disposed between first particles of the at least one first particle.

Process for the preparation of electrodes from a porous material making it possible to obtain electrodes that are useful in electrochemical systems and that have at least one of the following properties: a high capacity in mAh/gram, a high capacity in mAh/liter, a good capacity for cycling, a low rate of self-discharge, and a good environmental tolerance.

A rechargeable electrochemical battery cell with a housing, a positive electrode, a negative electrode and an electrolyte which contains SO.sub.2 and a conducting salt of the active metal of the cell, whereby at least one of the electrodes contains a binder chosen from the group: Binder A, which consists of a polymer, which is made of monomeric structural units of a conjugated carboxylic acid or of the alkali salt, earth alkali salt or ammonium salt of this conjugated carboxylic acid or a combination thereof or binder B which consists of a polymer based on monomeric styrene structural units or butadiene structural units or a mixture of binder A and B.

A rechargeable electrochemical battery cell with a housing, a positive electrode, a negative electrode and an electrolyte which contains SO.sub.2 and a conducting salt of the active metal of the cell, whereby at least one of the electrodes contains a binder chosen from the group: Binder A, which consists of a polymer, which is made of monomeric structural units of a conjugated carboxylic acid or of the alkali salt, earth alkali salt or ammonium salt of this conjugated carboxylic acid or a combination thereof or binder B which consists of a polymer based on monomeric styrene structural units or butadiene structural units or a mixture of binder A and B.

The lithium metal secondary battery includes a negative electrode active material layer containing lithium metal, a positive electrode active material layer, and a separator disposed between the negative electrode active material layer and the positive electrode active material layer. The separator is porous and contains ion conducting inorganic oxide, and an electrolyte is present in the separator and in the positive electrode active material layer.

Articles and methods including additives in electrochemical cells, are generally provided. As described herein, such electrochemical cells may comprise an anode, a cathode, an electrolyte, and optionally a separator. In some embodiments, at least one of the anode, the cathode, the electrolyte, and/or the optional separator may comprise an additive and/or additive precursor. For instance, in some cases, the electrochemical cell comprises an electrolyte and an additive and/or additive precursor that is soluble with and/or is present in the electrolyte. In some embodiments, the additive precursor comprises a disulfide bond. In certain embodiments, the additive is a carbon disulfide salt. In some cases, the electrolyte may comprise a nitrate.

The invention relates to an improved lithium-air battery. The battery includes a negative electrode and a positive electrode separated by an electrolyte, wherein the negative electrode consists of a film of metal material selected from among lithium and lithium alloys, the positive electrode includes a film of a porous carbon material on a current collector, and the electrolyte is a solution of lithium salts in a solvent. The battery is characterized in that the surface of the negative electrode opposite the electrolyte has a passivation layer containing Li.sub.2S, Li.sub.2S.sub.2O.sub.4, Li.sub.2O, and Li.sub.2CO.sub.3, the passivation layer being richer in sulfur compound on the surface thereof that is in contact with the electrolyte. The battery is obtained by means of a method consisting of producing the positive electrode, the electrolyte, and a film of the metal material for forming the negative electrode, and assembling the positive electrode, the electrolyte, and the film of metal material. The method is characterized in that it includes a step of subjecting the film of metal material to a gaseous atmosphere containing SO.sub.2, before or after the assembly thereof with the positive electrode and the electrolyte.

A negative electrode for a lithium electrochemical generator, wherein it comprises, as active material, a lithium and calcium alloy, wherein the calcium is present in the alloy to the extent of 2% to 34% of atomic.

A functionalized lithium anode for batteries, which is obtainable according to a specific process using diazonium salts. The embodiments also relate to the use of that lithium anode in cells, to a cell including that lithium anode, to the use of that cell in an electronic device, and to an electronic device including that cell.