A method and system for creating low corrosion passivation layer on an anode in a metal-air cell comprise asserting high negative potential and low drawn current density on the cell after its operational parameters have stabilized after the cell has been powered-on. As a result the H2 evolution rate momentarily raises and then drops sharply, thereby causing the creation of a passivation layer on the face of the anode.

A method and system for creating low corrosion passivation layer on an anode in a metal-air cell comprise asserting high negative potential and low drawn current density on the cell after its operational parameters have stabilized after the cell has been powered-on. As a result the H2 evolution rate momentarily raises and then drops sharply, thereby causing the creation of a passivation layer on the face of the anode.

Provided are a negative active material and a lithium battery including the negative active material. The negative active material includes a non-carbonaceous core allowing doping or undoping of lithium ion; and a double coating layer formed on at least one portion of a surface of the non-carbonaceous core and including a first coating layer including a metal and a second coating layer including a metal oxide or a metal nitride.

Provided is a method of producing a multivalent metal-ion battery comprising an anode, a cathode, and an electrolyte in ionic contact with the anode and the cathode to support reversible deposition and dissolution of a multivalent metal, selected from Ni, Zn, Be, Mg, Ca, Ba, La, Ti, Ta, Zr, Nb, Mn, V, Co, Fe, Cd, Cr, Ga, In, or a combination thereof, at the anode, wherein the anode contains the multivalent metal or its alloy as an anode active material and the cathode comprises a cathode active layer of graphitic carbon particles or fibers that are coated with a protective material. Such a metal-ion battery delivers a high energy density, high power density, and long cycle life.

Provided is a method of producing a multivalent metal-ion battery comprising an anode, a cathode, and an electrolyte in ionic contact with the anode and the cathode to support reversible deposition and dissolution of a multivalent metal, selected from Ni, Zn, Be, Mg, Ca, Ba, La, Ti, Ta, Zr, Nb, Mn, V, Co, Fe, Cd, Cr, Ga, In, or a combination thereof, at the anode, wherein the anode contains the multivalent metal or its alloy as an anode active material and the cathode comprises a cathode active layer of graphitic carbon particles or fibers that are coated with a protective material. Such a metal-ion battery delivers a high energy density, high power density, and long cycle life.

An electrochemical device includes a positive electrode, a negative electrode, a separator, and an electrolyte, where the electrolyte contains a nitrile compound and transition metal ions, and satisfies 5≤A/B≤30000, where based on a molar mass of the electrolyte, a molar percentage of a cyano group in the electrolyte is A %, and based on a weight of the electrolyte, a weight percentage of the transition metal ions in the electrolyte is B %. The electrochemical device ensures that the cyano group and the transition metal ions in the electrolyte satisfy a specified relationship, to reduce leaching of the transition metal ions from a positive electrode active material and stabilize structural distortion of the positive electrode active material in a charge and discharge process, thereby improving high-temperature cycle performance and floating charge performance of the electrochemical device.

A negative electrode of a lithium ion electrochemical cell, the negative electrode including an active electrode material that includes a first component and a second component. The first component may include graphene, silicon, or a combination thereof. The second component may include silicon. The active electrode material may include particles in which the second component is encapsulated by the first component. The negative electrode may have an internal porosity of between 40 to 60 percent.

A battery electrode composition is provided that comprises a composite material comprising one or more nanocomposites. The nanocomposites may each comprise a planar substrate backbone having a curved geometrical structure, and an active material forming a continuous or substantially continuous film at least partially encasing the substrate backbone. To form an electrode from the electrode composition, a plurality of electrically-interconnected nanocomposites of this type may be aggregated into one or more three-dimensional agglomerations, such as substantially spherical or ellipsoidal granules.

A battery electrode composition is provided that comprises a composite material comprising one or more nanocomposites. The nanocomposites may each comprise a planar substrate backbone having a curved geometrical structure, and an active material forming a continuous or substantially continuous film at least partially encasing the substrate backbone. To form an electrode from the electrode composition, a plurality of electrically-interconnected nanocomposites of this type may be aggregated into one or more three-dimensional agglomerations, such as substantially spherical or ellipsoidal granules.

Li-ion batteries are provided that include a cathode, an anode comprising active particles, an electrolyte ionically coupling the anode and the cathode, a separator electrically separating the anode and the cathode, and at least one hydrofluoric acid neutralizing agent incorporated into the anode or the separator. Li-ion batteries are also provided that include a cathode, an anode comprising active particles, an electrolyte ionically coupling the anode and the cathode, and a separator electrically separating the anode and the cathode, where the electrolyte may be formed from a mixture of an imide salt and at least one salt selected from the group consisting of LiPF.sub.6, LiBF.sub.4, and LiClO.sub.4. Li-ion battery anodes are also provided that include an active material core and a protective coating at least partially encasing the active material core, where the protective coating comprises a material that is resistant to hydrofluoric acid permeation.