A secondary battery includes: a positive electrode current collector; a negative electrode current collector; an electrolyte layer disposed between the positive electrode current collector and the negative electrode current collector; a positive electrode electrolytic solution filling part partitioned by the positive electrode current collector and the electrolyte layer; and a negative electrode electrolytic solution filling part partitioned by the negative electrode current collector and the electrolyte layer. The negative electrode electrolytic solution filling part includes a conductive member having a mesh structure and disposed so as to bring the negative electrode current collector and the electrolyte layer into conduction; a negative electrode active material retained in the conductive member; an electrolyte salt; and a non-aqueous solvent dissolving the electrolyte salt. The negative electrode active material contains at least one selected from the group consisting of silicon, tin, and aluminum, as a constituent element.

A secondary battery includes: a positive electrode current collector; a negative electrode current collector; an electrolyte layer disposed between the positive electrode current collector and the negative electrode current collector; a positive electrode electrolytic solution filling part partitioned by the positive electrode current collector and the electrolyte layer; and a negative electrode electrolytic solution filling part partitioned by the negative electrode current collector and the electrolyte layer. The negative electrode electrolytic solution filling part includes a conductive member having a mesh structure and disposed so as to bring the negative electrode current collector and the electrolyte layer into conduction; a negative electrode active material retained in the conductive member; an electrolyte salt; and a non-aqueous solvent dissolving the electrolyte salt. The negative electrode active material contains at least one selected from the group consisting of silicon, tin, and aluminum, as a constituent element.

Presented are electrochemical devices with copper-free electrodes, methods for making/using such devices, and lithium alloy-based electrode tabs and current collectors for rechargeable lithium-class battery cells. A method of manufacturing copper-free electrodes includes feeding an aluminum workpiece, such as a strip of aluminum sheet metal, into a masking device. The masking device then applies a series of dielectric masks, such as strips of epoxy resin or dielectric tape, onto discrete areas of the workpiece to form a masked aluminum workpiece with masked areas interleaved with unmasked areas. The masked workpiece is then fed into an electrolytic anodizing solution, such as sulfuric acid, to form an anodized aluminum workpiece with anodized surface sections on the unmasked areas interleaved with un-anodized surface sections underneath the dielectric masks of the masked areas. The dielectric masks are removed to reveal the un-anodized surface sections, and the anodized aluminum workpiece is segmented into multiple copper-free electrodes.

A lithium battery includes a solid cathode and a solid electrolyte (SSE), wherein a structurally continuous block of material comprises the solid cathode and the SSE. The structurally continuous solid block of material has a first chemical composition in the solid cathode and a second chemical composition, different from the first chemical composition, in the SSE. The SSE overlies the solid cathode, without any physical separation or interface therebetween. A method for fabricating a lithium battery includes placing a first layer of particles of an electrolyte material of a first composition on top of a second layer of particles of a cathode material of a second composition, forming a stack; and compressing and heating the stack of first and second layers to form a continuous solid material. The formed material has a solid electrolyte (SSE) characterized by the first composition and a solid cathode characterized by the second composition.

Systems and methods for aromatic macrocyclic compounds (Phthalocyanines) as cathode additives for inhibition of transition metal dissolution and stable solid electrolyte interphase formation may include an anode, an electrolyte, and a cathode, where the cathode comprises an active material and a phthalocyanine additive, the additive being coordinated with different metal cationic center and functional groups. The active material may comprise one or more of: nickel cobalt aluminum oxide, nickel cobalt manganese oxide, lithium iron phosphate, lithium cobalt oxide, and lithium manganese oxide, Ni-rich layered oxides LiNi.sub.1−xM.sub.xO.sub.2 where M=Co, Mn, or Al, Li-rich xLi.sub.2MnO.sub.3(1−x)LiNi.sub.aCo.sub.bMn.sub.cO.sub.2, Li-rich layered oxides LiNi.sub.1+xM.sub.1−O.sub.2 where M=Co, Mn, or Ni, and spinel oxides LiNi.sub.0.5Mn.sub.1.5O.sub.4. The phthalocyanine additive may include one or more of: cobalt hexadecafluoro phthalocyanine (Co-Pc-F), dilithium phthalocyanine (Li-Pc), cobalt(II) phthalocyanine, nickel(II) phthalocyanine-tetrasulfonic acid tetrasodium salt, titanium(IV) phthalocyanine dichloride, manganese(II) phthalocyanine, zinc phthalocyanine, aluminum phthalocyanine chloride, Iron(II) phthalocyanine, and silicon phthalocyanine dichloride.

A main object of the present disclosure is to provide an anode material that is used in a fluoride ion battery and can prevent the decrease in operating voltage while inhibiting occurrence of short circuit. The present disclosure achieves the object by providing an anode material to be used in a fluoride ion battery, the anode material comprising a Mg material containing a Mg element, and a fluoride ion conductive material containing at least one kind of metal element excluding a Mg element, and a F element.

A battery electrode composition is provided that comprises a composite material comprising one or more nanocomposites. The nanocomposites may each comprise a planar substrate backbone having a curved geometrical structure, and an active material forming a continuous or substantially continuous film at least partially encasing the substrate backbone. To form an electrode from the electrode composition, a plurality of electrically-interconnected nanocomposites of this type may be aggregated into one or more three-dimensional agglomerations, such as substantially spherical or ellipsoidal granules.

A battery electrode composition is provided that comprises a composite material comprising one or more nanocomposites. The nanocomposites may each comprise a planar substrate backbone having a curved geometrical structure, and an active material forming a continuous or substantially continuous film at least partially encasing the substrate backbone. To form an electrode from the electrode composition, a plurality of electrically-interconnected nanocomposites of this type may be aggregated into one or more three-dimensional agglomerations, such as substantially spherical or ellipsoidal granules.

Provided is a positive electrode active material for a lithium ion secondary battery having favorable cycle characteristics and high capacity. A covering layer containing aluminum and a covering layer containing magnesium are provided on a superficial portion of the positive electrode active material. The covering layer containing magnesium exists in a region closer to a particle surface than the covering layer containing aluminum is. The covering layer containing aluminum can be formed by a sol-gel method using an aluminum alkoxide. The covering layer containing magnesium can be formed as follows: magnesium and fluorine are mixed as a starting material and then subjected to heating after the sol-gel step, so that magnesium is segregated.

The present invention relates to an electric energy storage device, in particular a battery, at least comprising: —an anode comprising a divalent metal selected from magnesium, calcium, beryllium and zinc or a combination thereof or an alloy comprising at least one of these metals; —a cathode comprising elemental sulphur, or a sulphur-containing organosilane compound, or a mixture of sulphur-containing organosilane compounds, or a mixture of sulphur and sulphur-containing organosilane compounds grafted on the surface of the cathode; and—an electrolyte placed between the anode and the cathode; wherein the cathode comprises a current collector surface that has been at least partly modified by grafting the sulphur-containing organosilane compound or a mixture of sulphur-containing organosilane compounds thereon.